• Title/Summary/Keyword: Cl$^{[-10]}$ 이온

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Synthesis of all-inorganic halide perovskite nanocrystal and film fabrication for application in highly efficient optoelectronic device (고효율 광전자 소자 응용을 위한 전 무기 할라이드 페로브스카이트 나노결정 합 성 및 필름 제작)

  • Choi, Seung Hee;Kim, Hyun Bin;Yoo, Jung Hyeon;Kwon, Seok Bin;Jeong, Seong Guk;Song, Young Hyun;Yoon, Dae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.3
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    • pp.106-111
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    • 2018
  • Halide perovskite nanocrystals have become attractive for LED applications due to their high color purity and excellent luminescent properties. $CsPbX_3$ (X = I, Br, and Cl) nanocrystals were synthesized by hot-injection method and the emission wavelength was controlled by changing the composition of halide ion. Green- and red-emitting films were fabricated using a polymer binder. The outstanding optical properties of the synthesized nanocrystals and fabricated films were confirmed. The wLED designed by green- and red-emitting perovskite nanocrystal films on blue InGaN LED was characterized.

Effect of cavitation for electrochemical characteristics in seawater for austenitic 304 stainless steel (오스테나이트계 STS 304강의 해수 내 전기화학적 특성에 미치는 캐비테이션의 영향)

  • Kim, Seong-Jong;Lee, Seung-Jun;Chong, Sang-Ok
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.5
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    • pp.484-492
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    • 2013
  • With the industrial acceleration in a lot of countries of the world, the demand for anti-corrosion and anti-abrasion material increases continuously. Particularly, stainless steel with the fine surface and excellent corrosion resistance is widely used in various industrial fields including ship, offshore structures tidal power plant, and etc. In marine environment, however, it is easy to generate by the corrosion damage by $Cl^-$ ion and cavitation damage due to high rotation speed on stainless steel. Therefore, in this research, the cavitation erosion-corrosion test (Hybrid test) was performed for 304 stainless steel specimen used in the high flow rate seawater environment. And the cavitation damage behavior in the corrosive environment was analyzed overall. The high hardness was shown due to the formation of compressive residual stress by the water cavitation peening effect in cavitation condition. However, high current density in the potentiodynamic polarization experiment presented with the breakdown of the passive film caused by physical impact. Therefore, both electrochemical characteristics and mechanical properties must be taken into account to improve the cavitation resistance in seawater.

Gene cloning, tissue distribution, and its characterization of Ca2+-activated Cl- channel activated by ginsenosides in Xenopus laevis oocytes (Xenopus laevis oocytes에서 진세노사이드에 의하여 활성화되는 Ca2+-activated Cl- 이온 통로의 유전자 클로닝, 조직 분포 및 채널 특성)

  • Jeong, Sang-Min;Lee, Jun-Ho;Yoon, In-Soo;Nah, Seung-Yeol
    • Journal of Ginseng Research
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    • v.29 no.4
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    • pp.167-175
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    • 2005
  • The $Ca^{2+}-activated$ chloride channel (CLCA) was activated by ginseng total saponin (GTS) in Xenopus oocytes. The reverse transcription PCR (RT-PCR) method was performed with gene specific primers on oocytes. The gene specific primers were deduced from spleen cDNA in expressed sequence tags (EST) database showing high homology to the mouse CLCA. Full length of cDNA sequence was completed by linkage of several 5' and 3'-half cDNA fragments have been sequenced. We named the full cDNA to oCLCA transiently. The oCLCA gene encodes a protein of 911 amino acids with $48.9\%$ identity overall to that of mouse CLCA (mCLCA4). A predicted oCLCA amino acids sequence shows the molecular weight of 108 kDa and has four or more transmembrane domains, and also the one hydrophobic C­terminal domain. oCLCA gene was expressed ubiquitously in various tissues included oocytes, also interfered in oocytes by siRNA for oCLCA. Here, we suggest that oCLCA is a endogenous chloride channel gene in oocytes. We are studying for the identification of oCLCA gene and further physiological research.

Characteristics of Sapphire Wafers Polishing Depending on Ion Conductivity of Silica Sol (실리카졸의 이온전도도 변화에 따른 사파이어 웨이퍼의 연마 특성)

  • Na, Ho Seong;Cho, Gyeong Sook;Lee, Dong-Hyun;Park, Min-Gyeong;Kim, Dae Sung;Lee, Seung-Ho
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.21-26
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    • 2015
  • CMP(Chemical Mechanical Polishing) Processes have been used to improve the planarization of the wafers in the semiconductor manufacturing industry. Polishing performance of CMP Process is determined by the chemical reaction of the liquid sol containing abrasive, pressure of the head portion and rotational speed of the polishing pad. However, frictional heat generated during the CMP process causes agglomeration of the particles and the liquidity degradation, resulting in a non-uniform of surface roughness and surface scratch. To overcome this chronic problem, herein, we introduced NaCl salt as an additive into silica sol for elimination the generation of frictional heat. The added NaCl reduced the zata potential of silica sol and increased the contact surface of silica particles onto the sapphire wafer, resulting in increase of the removal rate up to 17 %. Additionally, it seems that the silica particles adsorbed on the polishing pad decreased the contact area between the sapphire water and polishing pad, which suppressed the generation of frictional heat.

Purification and Characterization of stu I Endomuclease from Streptomyces Tubercidicus (Streptomyces tubercidicus에 존재하는 stu I endonuclease의 정제와 특징)

  • 김기태;정미영;유욱준
    • Korean Journal of Microbiology
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    • v.25 no.3
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    • pp.180-183
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    • 1987
  • Stu I, type II restriction endonuclease, has been purified to homogeneity from Streptomyces tubercidicus (ATCC 25502), and its catalytic properties have been studied. For the purification of Stu I endonuclease free of nonspecific nucleases, DEAE-Sephadex (A-50), QAE-Sephadex (A-50) and Heparin-agarose column chromatography have been performed after ammonium sulfate fractionation of the crude extract. The enzyme was further purified by gel filtration using Sephadex G-100 column to obtain homogeneous form of protein. The single polypeptide species of Stu I endonuclease has a subunit molecular weight of 34,000 $\pm$ 1,000 daltons as judged by polyacrylamide gel electrophoresis in the presence of sodium dodecyl sulfate. Stu I endonuclease requires $Mg^{2+}$ ion for its activity and is maximally active at neutral pH (7.0-8.0) in the absence of NaCl.

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Separation of Molybdenum and Tungsten from Sulfuric acid Solution by Solvent Extraction with Alamine 336 (황산용액에서 Alamine 336에 의한 용매추출로 몰리브덴과 텅스텐의 분리)

  • Nguyen, Thi Hong;Lee, Man Seung
    • Resources Recycling
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    • v.25 no.1
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    • pp.16-23
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    • 2016
  • The separation behaviour of Mo and W from sulfuric acid solution by solvent extraction with Alamine 336 was investigated as a function of solution pH and extractant concentration. Selective extraction of Mo over W by Alamine 336 was obtained in the pH range of 3-5 with low amine concentration. The mixture of Alamine 336 and acidic extractants improved the separation factor between Mo and W and was in the following order: D2EPHA > PC88A > Decanol > Versatic acid. The stripping efficiency of Mo and W from the loaded mixture of Alamine 336 and D2EHPA was very poor, while complete stripping of Mo and W was possible from the mixture of Alamine 336 and Decanol by using a mixture of $NH_4OH$ and $NH_4Cl$.

Aggregation Behavior of Silver and TiO2 Nanoparticles in Aqueous Environment (수환경 특성에 따른 은과 이산화티탄 나노입자의 응집 특성 연구)

  • Lim, Myunghee;Bae, Sujin;Lee, Yong-Ju;Lee, Sung-Kyu;Hwang, Yu Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.5
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    • pp.571-579
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    • 2013
  • The aggregation behaviors of silver nanoparticles (AgNPs) and titanium dioxide ($TiO_2$) nanoparticles were investigated. Time-resolved dynamic light scattering (DLS) was used to study the initial aggregation of AgNPs and $TiO_2$ over a range of mono (NaCl) and divalent ($CaCl_2$) electrolyte concentrations. The effects of pH, initial concentration of NPs and natural organic matters (NOM) on the aggregation of NPs were also investigated. The aggregation of both nanoparticles showed classical Derjaguin-Landau-Verwey-Overbeek (DLVO) type behavior. Divalent electrolyte was more efficient in destabilize the AgNPs and $TiO_2$ than monovalent electrolyte. The effect of pH on the aggregation of AgNPs was not significant. But the aggregation rate of $TiO_2$ was much higher with increasing pH. Higher NPs concentration leads to faster aggregation. Natural organic matter (NOM) was found to substantially hinder the aggregation of both AgNPs and $TiO_2$. This study found that the aggregation behavior of AgNPs and $TiO_2$ are closely associated with environmental factors such as ionic strength, pH, initial concentration of NPs and NOM.

Thermodynamic Study on the Solubilization of p-Halogenated Phenol Derivatives in TTAB Solution (TTAB 수용액에서 p-할로겐화 페놀유도체들의 가용화에 대한 열역학적 연구)

  • Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.20-26
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    • 2014
  • The interaction of p-halogenated phenol derivatives with the micellar system of tetradecyltrimethylammonium bromide (TTAB) was studied by the UV/Vis spectrophotometric method. Effects of substituents, additives, and temperatures on the solubilization of phenol derivatives have been measured. The results show that all the values of ${\Delta}G^o$ and ${\Delta}H^o$ were negative and the values of ${\Delta}S^o$ were positive for all phenol derivatives within the measured temperature range. The calculated thermodynamic parameters depended on the size, the electro-negativity, and the hydrophobic property of halogen substituents. The addition of n-butanol results in the decrement in tthe Ks values and the addition of NaCl caused the increment in the Ks values for all the phenol derivatives. From these changes we can postulate that the solubilization sites of the phenol derivatives in the micelle depend severely on properties of the halogen-substituent.

Taste Characteristics and Functionality of Two Stage Enzyme Hydrolysate from Low-Utilized Longfinned Squid (창오징어 2단 효소분해엑스분의 정미특성 및 기능성)

  • 오광수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.5
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    • pp.782-786
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    • 2001
  • The taste characteristics and functionality of low-utilized small longfinned squid as affected by two stage enzyme hydrolysis were examined. In taste active-components, total free amino acid contents in hot-water and autolytic extract, two stage enzyme hydrolysate (TSEH) of longfinned squid were 2,792.5 mg%, 8,393.8 mg% and 9,186.1 mg%, respectively. The major free amino acids were Pro, Leu, Glu, Tau, Lys, Arg, Phe, Val and Ile. As for quarternary ammonium bases, betaine was the principal component (593.8 mg%) and also contents of TMAO, AMP in longfinned squid TSEH were 234.8% mg% and 51.0 mg%, respectively. The major inorganic ions in TSEH were Na(874.0 mg%), K (398.2 mg%), Cl (1,213.1 mg%) and PO$_4$(995.9 mg%). From the results in sensory tests, TSEH was superior to other extracts on the aspects of taste characteristics such as umami intensity, sweetness, taste harmony and transparency of extract. Also TSEH of longfinned squid revealed very higher Angiotensin-I converting enzyme inhibition ratio (92.1%) than those of hot-water and autolytic extract.

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Development of a Portable and Disposable pH Sensor Based on Titanium Wire with High Electrochemical Sensing Performance (우수한 전기화학적 센싱 성능을 지닌 티타늄 와이어 기반의 휴대 및 일회용 pH 센서 개발)

  • Yoon, Eun Seop;Yoon, Jo Hee;Son, Seon Gyu;Kim, Seo Jin;Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.700-705
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    • 2021
  • A portable and disposable pH sensor based on Ti wire was successfully developed for monitoring hydronium ion concentrations. A sensing electrode was prepared by electrochemically depositing iridium oxide onto a Ti wire, while a reference electrode was fabricated by coating Ag/AgCl ink on a Ti wire. Combining the two electrodes in the pH sensor enabled the collection of open circuit potential signals when the sensor was immersed in solutions of various pH values. The pH sensor exhibited excellent electrochemical sensing performance in terms of sensitivity, response time, repeatability, selectivity, and stability. To demonstrate point-of-measurement applications, the pH sensor was integrated with a wireless electronic module that could communicate with a mobile application. The portable pH sensor accurately measured pH changes in real samples. The results obtained were consistent with those of using a commercial pH meter.