• Title/Summary/Keyword: Circular spectrum

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Experimental Techniques for Surface Science with Synchrotron Radiation

  • Jonhnson, R.L.;Bunk, O.;Falkenberg, G.;Kosuch, R.;Zeysing, J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.17-17
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    • 1998
  • Synchrotron radiation is produced when charged particles moving with relativistic velocities a are accelerated - for example, deflected by the bending magnets which guide the electron or p positrons in circular accelerators or storage rings. By using special focusing magnetic lattices i in the particle accelerators it is possible to make the dimensions of the particle beam very small with a hi맹 charge density which results in a light source with high b디lIiance. Synchrotron light h has important properties which make it ideal for a wide range of investigations in surface s science. The fact that the spectrum of electromagnetic radiation emitted in a bending magnet e extends in a continuum from the 얹r infra red region to hard x-rays means that it is id않I for a v variety of spectroscopic studies. Since there are no convenient lasers, or other really bright l light sources, in the vacuum ultraviolet and soft x-ray re.밍ons the development of synchrotron r radiation has enabled enormous advances to be made in this di펌C비t spectr따 re밍on. P Polarization-dependent measurements, for ex없nple ellipsometry or circular dichroism studies a are possible because the radiation has a well-defined polarization - linear in the plane of orbit w with additional right-circular, or left-circular, components for emission an생es above, or below, t the horizontal, respectively. Since the synchrotron light is emitted from a bunch of charge c circulating in a ring the light is emitted with a well-defined time structure with a short flash of l light every time a bunch passes an exit port. The time structure depends on the size of the ring a and the number and sequence of filling of the bunches. A pulsed light source enables time¬r resolved studies to be performed which provide direct information on the lifetimes and decay m modes of excited states and in addition opens up the possibility of using time of flight t techniques for spectroscopic studies. The fact that synchrotron radiation is produced in a clean u ultrahi야 vacuum environment is of gr않t importance for surce science studies. The current t비rd generation synchrotron light sources provide exceptionally high baliance and stability a and open up possibilities for experiments which would have been inconceivable only a short time ago.

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Interaction of Ruthenium(II)[(1,10-phenanthroline)2benzodipyrido[3,2-a:2',3'-c]-phenazine]2+ with Single Stranded Poly(dA) and Poly(dT): Turning off the Light Switch

  • Lee, Jeong-Mi;Choi, Ji-Yoon;Kim, Jong-Moon;Lee, Sang-Yong;Lee, Hyo-Sun;Kim, Seog-K.;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • v.28 no.6
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    • pp.965-969
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    • 2007
  • The spectral properties, namely the circular dichroism, electric absorption and luminescence properties, of Λ- and Δ-[Ru(II)(1,10-phenanthroline)2benzodipyrido[b:3,2-h:2',3'-j]phenazine]2+ ([Ru(phen)2BDPPZ]2+) in the presence and absence of single stranded poly(dA) and poly(dT) were compared in this work. In the presence of single stranded DNAs, hypochromism in the absorption spectrum and significant changes in the circular dichroism spectrum in the ligand absorption band were apparent, indicating the strong interaction of the [Ru(phen)2BDPPZ]2+ complex with the single stranded DNAs. The luminescence intensity of the Ru(II) complex decreased stoichiometrically with increasing concentrations of the single stranded DNAs. All of these spectral changes were independent of the configuration of the Ru(II) complex and the nature of the DNA bases. Therefore, it is conceivable that both enantiomers of the [Ru(phen)2BDPPZ]2+ complex interact electrostatically with the negatively charged phosphate groups of DNA. However, the spectral properties of [Ru(II)(1,10-phenanthroline)3]2+ were not altered even in the presence of single stranded DNAs. Therefore, the size of the ligand involved in the interaction of the metal complex with the phosphate group of DNA may play an important role, even when the nature of the interaction is electrostatic.

AN EVALUATION OF CHEMICAL DEGRADATION OF LIGHT-CURED RESTORATIVE COMPOSITES (광중합 복합레진의 화학적 분해 평가)

  • Yang, Kuy-Ho;Kim, Hun-Ju;Choi, Nam-Ki
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.3
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    • pp.530-539
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    • 2003
  • The aim of this study was to evaluate the resistance to degradation of four commercial composite resins in an alkaline solution. The brands studied were Charisma, Filtek P 60, Palpique Estelite, and Spectrum. Preweighed discs of each brand were exposed to 0.1N NaOH solution at $60^{\circ}C$. After 2 weeks they were removed, neutralized with HCl, washed with water and dried. Resistance to degradation was evaluated on the basis of following parameters: (a) mass loss(%) - determined from pre-and post-exposed specimen weights; (b) Si loss(ppm) - obtained from ICP-AE analysis of solution exposed to specimens; and (c) degradation depth(${\mu}m$) - measured SEM and CLSM from polished circular sections of exposed specimens. The results were as follows: 1. The sequence of mass loss was in descending order by Palpique Estelite, Filtek P 60, Charisma, and Spectrum. 2. The sequence of the degree of degradation layer depth was in descending order by Filtek P 60, Charisma, Palpique Estelita, and Spectrum. 3. The sequence of the Si loss was in descending order by Chrisma, Spectrum, Palpique Estelite, and Filtek P 60. 4. The correlation coefficient between mass loss and degradation layer depth was relatively high(r=0.704, p<0.05). 5. When observed with SEM, destruction of bonding was observed between resin matrix and filler. 6. When observed with CLSM, degradation layer depth of composite resin surface was observed.

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Decoupled Location Parameter Estimation of 3-D Near-Field Sources in a Uniform Circular Array using the Rank Reduction Algorithm

  • Jung, Tae-Jin;Kwon, Bum-Soo;Lee, Kyun-Kyung
    • The Journal of the Acoustical Society of Korea
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    • v.30 no.3
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    • pp.129-135
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    • 2011
  • An algorithm is presented for estimating the 3-D location (i.e., azimuth angle, elevation angle, and range) of multiple sources with a uniform circular array (UCA) consisting of an even number of sensors. Recently the rank reduction (RARE) algorithm for partly-calibrated sensor arrays was developed. This algorithm is applicable to sensor arrays consisting of several identically oriented and calibrated linear subarrays. Assuming that a UCA consists of M sensors, it can be divided into M/2 identical linear subarrays composed of two facing sensors. Based on the structure of the subarrays, the steering vectors are decomposed into two parts: range-independent 2-D direction-of-arrival (DOA) parameters, and range-relevant 3-D location parameters. Using this property we can estimate range-independent 2-D DOAs by using the RARE algorithm. Once the 2-D DOAs are available, range estimation can be obtained for each source by defining the 1-D MUSIC spectrum. Despite its low computational complexity, the proposed algorithm can provide an estimation performance almost comparable to that of the 3-D MUSIC benchmark estimator.

Effects of Freestream Turbulence Intensity on the Flow Past a Circular Cylinder (원형단면 실린더를 지나는 유동에 대한 자유류 난류강도의 영향)

  • Hwang, Jong-Yeon;Yang, Kyung-Soo;Lee, Sung-Su;Lee ,Joon-Sik;Lee, Sang-San
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.8 s.227
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    • pp.953-960
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    • 2004
  • In this study, the effects of freestream turbulence intensity on laminar-turbulent transition of separated shear layers in the wake of a circular cylinder are investigated using an immersed boundary method and LES. It is shown that the present numerical results without freestream turbulence for Re=3,900 based on bulk mean velocity and the cylinder diameter are in good agreement with other authors' experimental observations and numerical results, verifying our numerical methodology. Then a 'prescribed power spectrum' method is imposed to generate isotropic turbulence at the inlet of the computational domain at each time step. The principal effects of freestream turbulence intensity on flow statistics are investigated for Re=3,900. Statistical study reveals that the Reynolds stresses in the near-wake region gradually increase, and transition occurs further upstream, as the turbulence intensity increases. On the other hand, the bubble size behind the cylinder decreases as the turbulence intensity increases, which indicates that the freestream turbulence helps mean velocity be quickly recovered.

NMR and Circular Dichroism Studies on Human CD99 Transmembrane Domain

  • Kim, Hai-Young;Shin, Joon;Shin, Young-Kee;Park, Seong-Hoe;Lee, Weon-Tae
    • Journal of the Korean Magnetic Resonance Society
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    • v.7 no.1
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    • pp.37-45
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    • 2003
  • Human CD99 is a ubiquitous 32-kDa transmembrane protein encoded by mic2 gene. Recently it has been reported that expression of a splice variant of CD99 transmembrane protein (Type I and Type II) increases invasive ability of human breast cancer cells. To understand structural basis for cellular functions of CD99 Type II, we have initiated studies on hCD99$\^$TMcytoI/ using circular dichroism (CD) and multi-dimensional NMR spectroscopy. CD spectrum of hCD99$\^$TMytoI/ in the presence of 200mM DPC and CHAPS displayed an existence ${\alpha}$-helical conformation, showing that it could form an ${\alpha}$-helix under membrane environments. In addition, we have found that the cytoplasmic domain of CD99 would form symmetric dimmer in the presence of transmembrane domain. Although it has been rarely figured out the correlation between structure and functional mechanism of hCD99$\^$TMcytoI/, the dimerization or oligomerization would play an important role in its biological function.

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Reliability analysis of circular tunnel with consideration of the strength limit state

  • Ghasemi, Seyed Hooman;Nowak, Andrzej S.
    • Geomechanics and Engineering
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    • v.15 no.3
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    • pp.879-888
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    • 2018
  • Probability-based design codes have been developed to sufficiently confirm the safety level of structures. One of the most acceptable probability-based approaches is Load Resistance Factor Design (LRFD), which measures the safety level of the structures in terms of the reliability index. The main contribution of this paper is to calibrate the load and resistance factors of the design code for tunnels. The load and resistance factors are calculated using the available statistical models and probability-based procedures. The major steps include selection of representative structures, consideration of the limit state functions, calculation of reliability for the selected structures, selection of the target reliability index and calculation of load factors and resistance factors. The load and resistance models are reviewed. Statistical models of resistance (load carrying capacity) are summarized for strength limit state in bending, shear and compression. The reliability indices are calculated for several segments of a selected circular tunnel designed according to the tunnel manual report (Tunnel Manual). The novelty of this paper is the selection of the target reliability. In doing so, the uniform spectrum of reliability indices is proposed based on the probability paper. The final recommendation is proposed based on the closeness to the target reliability index.

Experimental investigations on seismic responses of RC circular column piers in curved bridges

  • Jiao, Chiyu;Li, Jianzhong;Wei, Biao;Long, Peiheng;Xu, Yan
    • Earthquakes and Structures
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    • v.17 no.5
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    • pp.435-445
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    • 2019
  • The collapses of curved bridges are mainly caused by the damaged columns, subjected to the combined loadings of axial load, shear force, flexural moment and torsional moment, under earthquakes. However, these combined loadings have not been fully investigated. This paper firstly investigated the mechanical characteristics of the bending-torsion coupling effects, based on the seismic response spectrum analysis of 24 curved bridge models. And then 9 reinforced concrete (RC) and circular column specimens were tested, by changing the bending-tortion ratio (M/T), axial compression ratio, longitudinal reinforcement ratio and spiral reinforcement ratio, respectively. The results show that the bending-torsion coupling effects of piers are more significant, along with the decrease of girder curvature and the increase of pier height. The M/T ratio ranges from 6 to 15 for common cases, and influences the crack distribution, plastic zone and hysteretic curve of piers. And these seismic characteristics are also influenced by the compression ratio, longitudinal reinforcement ratio and spiral reinforcement ratios of piers.

Effects of Exhaust Pipe Curvature on the Exhaust Noise of a Diesel Engine (디이젤 엔진에서 排氣管의 屈曲度가 排氣 騷音에 미치는 影響)

  • 문병수;김옥현;서정윤
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.3
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    • pp.392-398
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    • 1986
  • It is often occurred that exhaust pipe of an internal combustion engine should be bent due to some geometrical constraints. Especially for automobiles most of exhaust pipes of engines have curvature to avoid rear axles. In this paper effects of pipe curvature on the exhaust noise of a diesel engine have been studied experimentally. Experiments were carried out on a 4-cycle, 2164cc diesel engine. Two types of curvature, circular arc and retangle, were tested. Sound pressure level (SPL) and power spectrum of the exhaust noise were measured by inserting bent pipes of different curvature dimensions into the exhaust pipe at various engine operating conditions. The following results were obtained from this study. Among the engine operating conditions the exhaust noise was affected mainly by engine revolution speed. The noise was reduced by the circular arc bent pipe. The effectiveness of an arc bent pipe on the noise reduction was dominated by its arc angle and the maximum noise reduction was obtained by the angle of 180.deg.. But the noise reduction could not be obtained by the rectangular bent pipe, and at high engine speed the noise was rather increased due to turbulence of exhaust gas.

Documentation of Printed Hangul Images of the Selected Area by Finger Movement (손가락 이동에 의해 선택된 영역의 인쇄체 한글 영상 문서화)

  • Beak, Seung-Bok
    • Journal of the Korean Institute of Intelligent Systems
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    • v.12 no.4
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    • pp.306-310
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    • 2002
  • In this paper, we realized a system that converts the Korean alphabet (Hangul) images, which are in any domain that is formed by the finger movement on the Hangul document, to the editable characters and then outputs them to the word editor. The domain of hand is separated from the sphere of document in the pre-process step of image. The centroid point of hand is drawn by the maximum circular movement method. After the system recognizes the hand with the circular pattern vector algorithm, finds out the position of finger by the distance spectrum and then draws out the sphere of selected character image by the finger movement to divide the characters into character units by applying the histogram between the Hangul characters. We standardized the characters of various sizes. We used the circular pattern vector algorithm that grafts on the fuzzy inference to divert the character images of the domain, which user wants, to the editable characters by comparing the characteristic vectors between the standard pattern character and the inputted character and by recognizing the character.