• Title/Summary/Keyword: Cie

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A Study on the Optical and Electrical Properties of the White-light-emitting Organic LED with Two-wavelength using DPVBi/Rubrene Structure (DPVBi/Rubrene 구조를 사용한 2-파장 방식의 백색유기발광소자의 광학적ㆍ전기적 특성에 관한 연구)

  • 오환술;조재영;최성진;강명구;윤석범
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.2
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    • pp.217-222
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    • 2004
  • The white-light-emitting organic LED(OLED) with two-wavelength was fabricated using the DPVBi of blue emitting material and a series of orange color fluorescent dye(Rubrene) by vacuum evaporation processes. The basic structure of white-light-emitting OLED was ITO/NPB(150$\AA$)/DPVBi/Rubrene/BCP(100$\AA$)/Alq$_3$(150$\AA$)/Al(600$\AA$). We analyzed the fabricated device through the changes of the DPVBi and Rubrene layer's thickness. We obtained the white-light-emitting OLED with white color light and the CIE coordinate of the device was (0.29, 0.33) at applied voltage of 13V when the thickness of DPVBi layer was 210$\AA$ and the thickness of Rubrene layer was 180$\AA$. At a current of 100㎃/$\textrm{cm}^2$, the quantum efficiency was 0.35% and at a voltage of 20V, it was 0.405%.

Investigation of the Fundamental Properties on the Color Concrete and the Development of Its Technique manufacturing Formative Article (컬러콘크리트의 기초적 물성검토 및 이를 활용한 조형물 제작기술 개발에 관한 연구)

  • Kim, Jong-Baek;Kim, Jong;Kim, Gi-Cheol;Jeon, Chung-Keun;Yeun, Kyu-Won;Shin, Dong-An
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.125-128
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    • 2007
  • This study investigates the fundamental properties of the color concrete corresponding to the various types and contents of the coloring agent. For the properties of the fresh, the flow is gradually decreased corresponding to increasing of the coloring agent, and it is approached to the target flow on $3{\sim}6%$ of the adding amounts. The air content is increased in accordance with the increase of the coloring agent. For the properties of the hardened concrete, the compressive strength is increased about 9 and 12% in the case that $3{\sim}6%$ of red and yellow coloring agents is mixed. And they are decreased when white and black coloring agents. The chromaticity of red $(a^*)$ and yellow $(b^*)$ is appropriate at 6% of the adding amounts, and luminosity of the white and black is also favorable because of economy at 6%, so the formative article is manufactured successfully to aim in the result of this study.

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Synthesis and Characterization of New Anthracene-Based Blue Host Material

  • So, Ki-Ho;Park, Hyun-Tae;Shin, Sung-Chul;Lee, Sang-Gyeong;Lee, Dong-Hui;Lee, Kyeong-Hoon;Oh, Hyeong-Yun;Kwon, Soon-Ki;Kim, Yun-Hi
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1611-1615
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    • 2009
  • We designed new anthracene-based host material to increase color purity as well as device efficiency. The new blue host, 9,10-bis(2,4-dimethylphenyl)anthracene (BDA), has highly twisted structure and wide band gap due to ortho interaction between anthracene and introduced 2,4-dimethylphenyl substituents. BDA exhibited deep blue fluorescence in solution (${\lambda}_{max}$ = 410 nm) and in solid state (${\lambda}_{max}$ = 429 nm), respectively, with the wide optical band gap (E = 3.12 eV). Blue-light-emitting OLEDs using obtained host and 2% Flu-DPAN as emitter showed 8 cd/A of high efficiency as well as high color purity [CIE coordinates = (0.15, 015)].

Optical and Electrical Properties of Thin Film Electroluminescent Devices with SrS:Cu, Ag Phosphor Layer

  • Chang, Ho-Jung;Park, Jun-Seo;Chang, Young-Chul
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.1
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    • pp.29-33
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    • 2002
  • The SrS:Cu, Ag thin film electroluminescient devices were fabricated on $AlTiO_3$/ITO/glass substrates by electron-beam evaporation. The emission spectrum of the device was about 460 nm with $\chi$=0.20, y=0.29 in the CIE color coordinator. It was found that the emission spectrum was saturated to pure blue color when Ag sensitizer was doped in SrS:CuCl phosphors. The luminance of the device was increased by increasing the sulfur pressure. The measured luminance was saturated with 430 cd/$m^2$at the applied voltage of 90 V and the maximum luminance was 580 cd/$m^2$at 110V. The polarization charge and conduction charge of the devices were found to be found to be about $3.5\mu$C/$\textrm{cm}^2$ and $7.4\mu$C/$\textrm{cm}^2$, respectively.

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Highly Efficient Red Phosphorescent OLEDs Based on Ir(III) Complexes with Fluorine-substituted Benzoylphenylpyridine Ligand

  • Kang, Hyun-Ju;Lee, Kum-Hee;Lee, Suk-Jae;Seo, Ji-Hyun;Kim, Young-Kwan;Yoon, Seung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3711-3717
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    • 2010
  • Four orange-red phosphorescent Ir(III) complexes were designed and synthesized based on the benzoylphenylpyridine ligand with a fluorine substituent. Multilayered OLEDs with the device structure, ITO/2-TNATA/NPB/CBP : 8% Ir(III) complexes/BCP/Liq/Al, were fabricated using these complexes as dopant materials. All the devices exhibited orange-red electroluminescence and their electroluminescent properties were quite sensitive to the structural features of the dopants in the emitting layers. Among these, the maximum luminance ($14700\;cd/m^2$ at 14.0 V) was observed in the device containing Ir(III) complex 1 as the dopant. In addition, its luminous, power and quantum efficiency were 11.7 cd/A, 3.88 lm/W and 9.58% at $20\;mA/cm^2$, respectively. The peak wavelength of electroluminescence was 606 nm with CIE coordinates of (0.61, 0.38) at 12.0 V. The device also showed stable color chromaticity with various voltages.

Electroluminescence Characteristics of a New Green-Emitting Phenylphenothiazine Derivative with Phenylbenzimidazole Substituent

  • Ahn, Yeonseon;Jang, Da Eun;Cha, Yong-Bum;Kim, Mansu;Ahn, Kwang-Hyun;Kim, Young Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.107-111
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    • 2013
  • A new green-emitting material with donor-acceptor architecture, 3,7-bis(1'-phenylbenzimidazole-2'-yl)-10-phenylphenothiazine (BBPP) was synthesized and its thermal, optical, and electroluminescent characteristics were investigated. Organic light-emitting diodes (OLEDs) with four different multilayer structures were prepared using BBPP as an emitting layer. The optimized device with the structure of [ITO/2-TNATA (40 nm)/BBPP (30 nm)/TPBi (30 nm)/Alq3 (10 nm)/LiF (1 nm)/Al (100 nm)] exhibited efficient green emission. Enhanced charge carrier balance and electron mobility in the organic layers enabled the device to demonstrate a maximum luminance of 31,300 cd/$m^2$, a luminous efficiency of 6.83 cd/A, and an external quantum efficiency of 1.62% with the CIE 1931 chromaticity coordinates of (0.21, 0.53) at a current density of 100 mA/$cm^2$.

Photoluminescence Characteristic of Gallate-Based Red Emitting Phosphors with High Color Purity (색순도가 우수한 갈륨 산화물계 적색 형광체의 광발광 특성)

  • Kim, Kyoung-Un;Choi, Sung-Ho;Jung, Ha-Kyun;Nahm, Sahn
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.159-162
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    • 2008
  • $Eu^{3+}$-activated $R_3GaO_6$ (R = Y, Gd) phosphors were prepared in a conventional solid-state reaction and their optical properties were investigated. These compounds exhibit strong red emission under light excitation at 254 nm. The emission spectra are dominated by peaks appearing around 610-630 nm that are induced by the electric dipole transition of $^5D_0\;{\rightarrow}\;^7F_2$ of $Eu^{3+}$. In addition, the appropriate CIE (Commission Internationale de l'clairage) chromaticity coordinates, (x = 0.656, y = 0.336) for $Y_3GaO_6$ and (x = 0.655, y = 0.334) for $Gd_3GaO_6$, become closer to the NTSC (National Television System Committee) standard values. With the optimized activator concentrations, the maximum emission brightness is approximately 80% of $Y_2O_3$:$Eu^{3+}$ typical red-emitting phosphor with improved color purity under an excitation condition of 254 nm.

Natural Dyeing of Silk Fabrics with Undaria Pinnatifida Extracts (미역 추출물을 이용한 견직물의 천연염색)

  • Kim, Sangyool;Jeon, Soonduk
    • Journal of Fashion Business
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    • v.18 no.5
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    • pp.69-81
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    • 2014
  • Fabric made of 100% silk was dyed with Undaria pinnatifida extracts under different conditions such as varing colorant concentration, temperature, time and dyebath pH. The dye uptake (K/S, value), CIE L*,a*,b* and Munsell values of the dyed samples and mordanted samples were measured. Colorfastness, antibacterial property and UV protection property were also evaluated. As colorants concentration increased, the dye uptake increased progressively and maximum color strength was obtained at 100% V/V. Dye uptake also increased with increasing temperature and time, and the maximum color strength was obtained at $80^{\circ}C$ and 60min. With pre-mordanting, the color of the Al and Fe mordanted silk fabrics was yellow on the Munsell color system, while the Cu mordanted fabric was a greenish color. Al and Fe post-mordanted fabrics had a yellow tone, and the Cu post-mordanted fabric had a yellow greenish tone. The light fastness property of the Cu mordanted silk fabric was relatively good, The effect of Al and Fe mordanting on fastness was insignificant. The antibacterial activity of dyed and unmordanted silk fabric was excellent, whereas fabric dyed and mordanted with Undaria pinnatifida extract demonstrated superior ultraviolet protection.

Preparation and Luminescent Characteristics of Phosphate-Based Phosphors (포페이트계열 형광체의 합성 및 광특성 평가)

  • Noh, Seh-Chul;Kim, You-Hyuk
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.21-26
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    • 2002
  • In order to search new phosphors for plasma display panel(PDP), phosphate hosts which has a host excitation band at around 150nm were prepared and their luminescent properties were investigated. In the preparation of $YPO_4: Eu\; and\; (Y,Gd)PO_4: Eu$ phosphors, the effect of oxide and oxalate starting materials on prepared phosphors were compared in terms of relative emission intensities and particle characteristics. The results showed that oxalate starting materials gave better performance in emission intensities and smaller size and more round shape phosphors which would be more applicable for high resolution display. Additionally, Gd, V, Nb and Ta ions were doped to $YPO_4:Eu$ and the luminescent properties of the resulant solid solutions were investigated to find efficient sensitizer. Among these ions, Gd, V and Nb ions increased the emission intensities of parent phosphor to around 10%. While Nb ion gave the best result in emission intensities, CIE color coordinate were improved by doping V ion into $YPO_4:Eu$ phosphor to give x=0.6523, y=0.3406 compared to commercial sample.

Color Variation Improvement by Introducing Double Emission Layers in WPLEDs

  • Kwon, Soon-Kab;Lee, Yong-Kyun;Park, Tae-Jin;Jeong, Su-Hyeon;Jeon, Woo-Sik;Kwon, Jang-Hyuk;Jang, Jin
    • Journal of Information Display
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    • v.7 no.3
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    • pp.19-22
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    • 2006
  • White polymeric light-emitting devices (WPLEDs) have been fabricated from polyfluorene-based (PFO) blue and MEH-PPV polymer blending systems. A device structure of ITO / PEDOT:PSS / Blending polymer / Blue polymer / LiF / Al was employed. This structure of double emission layers showed significant improvement of white color shift phenomenon. A current efficiency of 4.67 cd/A (3,900 $cd/m^{2}$, 6.4 V) and a brightness value of 17,600 $cd/m^{2}$ at 9.4 V with (0.34, 0.35) CIE coordinates at 5 V and (0.29, 0.29) at 9 V were achieved achieved.