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http://dx.doi.org/10.5012/bkcs.2010.31.12.3711

Highly Efficient Red Phosphorescent OLEDs Based on Ir(III) Complexes with Fluorine-substituted Benzoylphenylpyridine Ligand  

Kang, Hyun-Ju (Department of Chemistry, Sungkyunkwan University)
Lee, Kum-Hee (Department of Chemistry, Sungkyunkwan University)
Lee, Suk-Jae (Department of Information Display, Hongik University)
Seo, Ji-Hyun (Department of Information Display, Hongik University)
Kim, Young-Kwan (Department of Information Display, Hongik University)
Yoon, Seung-Soo (Department of Chemistry, Sungkyunkwan University)
Publication Information
Abstract
Four orange-red phosphorescent Ir(III) complexes were designed and synthesized based on the benzoylphenylpyridine ligand with a fluorine substituent. Multilayered OLEDs with the device structure, ITO/2-TNATA/NPB/CBP : 8% Ir(III) complexes/BCP/Liq/Al, were fabricated using these complexes as dopant materials. All the devices exhibited orange-red electroluminescence and their electroluminescent properties were quite sensitive to the structural features of the dopants in the emitting layers. Among these, the maximum luminance ($14700\;cd/m^2$ at 14.0 V) was observed in the device containing Ir(III) complex 1 as the dopant. In addition, its luminous, power and quantum efficiency were 11.7 cd/A, 3.88 lm/W and 9.58% at $20\;mA/cm^2$, respectively. The peak wavelength of electroluminescence was 606 nm with CIE coordinates of (0.61, 0.38) at 12.0 V. The device also showed stable color chromaticity with various voltages.
Keywords
Fluorine; Phosphorescent OLEDs; Ir(III) complex; 5-Benzoyl-2-phenylpyridine ligand;
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