• Title/Summary/Keyword: Chloride penetration analysis

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Durability Evaluation of Cement Concrete Using Ferrosilicon Industrial Byproduct (페로실리콘 산업부산물 활용 시멘트 콘크리트의 내구성능 평가)

  • Chang-Young Kim;Ki Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.89-96
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    • 2023
  • In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO2 content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

Reliability-Based Service Life Estimation of Concrete in Marine Environment (신뢰성이론에 기반한 해양환경 콘크리트의 내구수명 평가)

  • Kim, Ki-Hyun;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.22 no.4
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    • pp.595-603
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    • 2010
  • Monte-Carlo simulation technique is often used in order to predict service life of concrete structure subjected to chloride penetration in marine environment based on probability theory. Monte-Carlo simulation method, however, the method gives different results every time that the simulation is run. On the other hand, moment method, which is frequently used in reliability analysis, needs negligible computational cost compared with simulation technique and gives a constant result for the same problem. Thus, in this study, moment method was applied to the calculation of corrosion-initiation probability. For this purpose, computer programs to calculate failure probabilities are developed using first-order second moment (FOSM) and second-order second moment (SOSM) methods, respectively. From the analysis examples with the developed programs, SOSM was found to give a more accurate result than FOSM does. The sensitivity analysis has shown that the factor affecting the corrosion-initiation probability the most was the cover depth, and the corrosion-initiation probability was influenced more by its coefficient of variation than its mean value.

A Study to Evaluate Performance of Poly-Urethane Polymer Concrete for Long-Span Orthotropic Steel Bridge (장경간 강바닥판 케이블교량에 적용하기 위한 폴리우레탄 폴리머콘크리트의 공용특성 연구)

  • Park, Heeyoung;Lee, Junghun;Kwak, Byeongseok;Choi, Iehyun;Kim, Taewoo
    • International Journal of Highway Engineering
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    • v.15 no.1
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    • pp.1-9
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    • 2013
  • PURPOSES: The purpose of this study is to evaluate physical properties, durability, fatigue resistance, and long-term performance of poly-urethane concrete (PU) which can be possible application of thin layer on long-span orthotropic steel bridge and to check structural stability of bridge structure. METHODS : Various tests of physical properties, such as flexural strength, tensile strength, bond strength and coefficient of thermal expansion tests were conducted for physical property evaluation using two types of poly urethane concrete which have different curing time. Freezing and thawing test, accelerated weathering test and chloride ion penetration test were performed to evaluate the effect of exposed to marine environment. Beam fatigue test and small scale accelerated pavement test were performed to assess the resistance of PU against fatigue damage and long-term performance. Structural analysis were conducted to figure out structural stability of bridge structure and thin bridge deck pavement system. RESULTS: The property tests results showed that similar results were observed overall however the flexural strength of PUa was higher than those of PUb. It was also found that PU materials showed durability at marine environment. Beam fatigue test results showed that the resistances of the PUa against fatigue damage were two times higher than those of the PUb. It was found form small scale accelerated pavement test to evaluate long-term performance that there is no distress observed after 800,000 load applications. Structural analysis to figure out structural stability of bridge structure and thin bridge deck pavement system indicated that bridge structures were needed to increase thickness of steel deck plate or to improve longitudinal rib shape. CONCLUSIONS: It has been known that the use of PU can be positively considered to thin layer on long-span orthotropic steel bridge in terms of properties considered marine environment, resistance of fatigue damage and long-term performance.

Failure Analysis of Welded type 304 in Cooling Water Pipeline of District Heating System (지역난방 냉각수 배관의 용접부 파손 분석)

  • Jeong, Joon-Cheol;Kim, Woo-Cheol;Kim, Kyung Min;Sohn, Hong-Kyun;Kim, Jung-Gu;Lee, Soo-Yeol;Kim, Heesan
    • Corrosion Science and Technology
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    • v.19 no.6
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    • pp.296-301
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    • 2020
  • Failure analysis on the welded type 304 pipe used for cooling water piping in the district heating primary side was conducted. Inorganic elements and bacteria in the cooling water and in corrosion products were analyzed, and the weldment was inspected by microscopy and a sensitization test. Corrosion damages were observed in the heat-affected zone, on weld defects such as incomplete fusion or excessive penetration caused by improper welding, or/and at the 6 o'clock position along the pipe axial direction. However, the level of concentration of chloride in the cooling water as low as 80 ppm has been reported to be not enough for even a sensitized type 304 steel, meaning that the additional corrosive factor was required for these corrosion damages. The factor leading to these corrosion damages was drawn to be the metabolisms of the types of bacteria, which is proved by the detection of proton, sulfur containing species, biofilms, and both bacteria and corrosion product analyses.

An Experimental Study on the Resistance to Penetration of Harmful Ions in Surface Coatings Material Containing Organic Corrosion inhibitor (유기계 방청제를 혼입한 표면피복재의 유해이온 침투저항에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.157-166
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    • 2017
  • In general, carbonation and chlorine ions are the most harmful causes of deterioration of concrete structures. Recently, a method has been developed to control the corrosion of rebar in concrete containing chloride by impregnating a Surface coating material with a inhibitor. In this study, accelerated carbonation and differential thermogravimetric analysis (TG-DTA) and CASS tests were carried out to evaluate the characteristics of Surface coatings containing Organic Corrosion inhibitors which are excellent in corrosion inhibition and fix degradation causes $CO_2$ and $Cl^-$. As a result of the experiment, TG-DTA analysis and accelerated carbonation showed that $CO_2$ was directly reacted with amine derivative in concrete by the incorporation of Organic Corrosion inhibitor. In other words, $CO_2$ was immobilized and carbonation inhibition effect was confirmed. In addition, in the CASS test, the specimen coated with the Surface coating material containing the Organic Corrosion inhibitor with $Cl^-$ fixing property showed no corrosion until the 28th day and had excellent performance in preventing corrosion of a rebar by the chloride ion.

An Study on the Investigation of Bridge Deck Condition by Analysis of Concrete Core Properties (교량바닥판 콘크리트 코어의 물성분석을 통한 상태조사연구)

  • Suh, Jin-Won;Rhee, Ji-Young;Ku, Bon-Sung;Shin, Jae-In;Shin, Do-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.789-792
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    • 2008
  • Recently, the deteriorations of RC bridge decks on express-way are frequently observed. The major cause of deterioration for the RC concrete bridge decks exposed to de-icing chemiclas would be chloride-induced reinforcement corrosion. Therefore, Waterproofing is necessary for improvement of bridge deck durability and comfortable utility. In this study is to investigate the appearance of deterioration and properties of concrete core from the collect in a bridge deck. The results of this study shows that penetration waterproofing agents shows low infiltration depth and low water-repellent. It appears that the damaging of concrete deck is primarily waterproofing system rather than physical property.

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Evaluation of a New Workplace Protection Factor―Measuring Method for Filtering Facepiece Respirator

  • Sun, Chenchen;Thelen, Christoph;Sanz, Iris Sancho;Wittmann, Andreas
    • Safety and Health at Work
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    • v.11 no.1
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    • pp.61-70
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    • 2020
  • Background: This study aims to assess whether the TSI PortaCount (Model 8020) is a measuring instrument comparable with the flame photometer. This would provide an indication for the suitability of the PortaCount for determining the workplace protection factor for particulate filtering facepiece respirators. Methods: The PortaCount (with and without the N95-CompanionTM) was compared with a stationary flame photometer from Moores (Wallisdown) Ltd (Type 1100), which is a measuring instrument used in the procedure for determining the total inward leakage of the particulate filtering facepiece respirator in the European Standard. Penetration levels of sodium chloride aerosol through sample respirators of two brands (A and B) were determined by the two measuring systems under laboratory conditions. For each brand, thirty-six measurements were conducted. The samples were split into groups according to their protection level, conditioning before testing, and aerosol concentration. The relationship between the gauged data from two measuring systems was determined. In addition, the particle size distribution inside the respirator and outside the respirator was documented. Linear regression analysis was used to calculate the association between the PortaCount (with and without the N95-CompanionTM) and the flame photometer. Results: A linear relationship was found between the raw data scaled with the PortaCount (without N95-CompanionTM) and the data detected by the flame photometer (R2 = 0.9704) under all test conditions. The distribution of particle size was found to be the same inside and outside the respirator in almost all cases. Conclusion: Based on the obtained data, the PortaCount may be applicable for the determination of workplace protection factor.

A Fundamental Study on the Characteristics of Concrete with the Substitution Ratio of the Rapidly Cooled Steel Slag (급냉제강슬래그의 대체율에 따른 콘크리트의 특성에 관한 기초적 연구)

  • Kim, Nam-Wook;Bae, Ju-Seong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.1 s.53
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    • pp.78-87
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    • 2009
  • When the steel slag is utilized to the concrete as the alternative fine aggregate, its use is limited as the concrete aggregate because of expansibility caused by much quantity of free CaO. So, this study is intended to examine the characteristics of the concrete which uses the rapidly cooled steel slag whose content of free CaO is sharply reduced by rapidly cooling the steel slag as the fine aggregate. Accordingly, by comparing and considering the results of the concrete slump loss test with the different substitution ratio and fine aggregate ratio of rapidly cooled steel slag, hydration by XRD and SEM analysis, compressive test by age, a length variation test and rapid chloride ion penetration test, the rapidly cooled steel slag's proper substitution ratio and the fine aggregate ratio was derived.

Experimental Study on the Relationship between Time-Dependent Chloride Diffusion Coefficient and Compressive Strength (시간의존성 염화물 확산계수와 압축강도 상관성에 대한 실험적 연구)

  • Lee, Seung-Hoon;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.24 no.6
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    • pp.715-726
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    • 2012
  • Since strength and diffusion coefficient of concrete, representative concrete properties that in change with age, the time effect must be considered in the analysis of chloride penetration. In this study, an evaluation of correlation between accelerated diffusion coefficient, apparent diffusion coefficient, and compressive strength in high performance concrete with various mineral admixtures such as ground granulated blast furnace slag, fly ash, and silica fume was performed. For this work, thirty mix proportions were prepared. Accelerated diffusion coefficients at the age of 28, 91, 180, and 270 days were evaluated. For apparent diffusion coefficient, submerging test for 6 months was performed. For evaluation of compressive strength with ages, the compressive strength test was carried out at an age of 7, 28, 91, 180 days. The results of accelerated diffusion coefficient, apparent diffusion coefficient, and strength were compared, and the correlation was analyzed considering time dependency. From this study, linear relationship between accelerated diffusion and apparent diffusion coefficient were obtained regardless of concrete age. The linear relations were also observed in strength-accelerated diffusion coefficient and strength-apparent diffusion coefficient regardless of concrete age.

Revision of Repair Materials Performance Requirement for Concrete Structures (콘크리트 구조물 단면복구공사 보수재료 품질기준개선)

  • Lee, Il Keun;Kim, Ki Hwan;Kim, Hong Sam;Yun, Sung Hwan;Kim, Woo Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.1
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    • pp.9-20
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    • 2023
  • For highway concrete structures, the deterioration of the structure is accelerated due to the increase in the use of deicing materials, and sectional repair work is being frequently carried out to restore performance. However, after the repair work, re-damage such as cracks, delamination, and poor bond performance is exhibited in the repaired sectional area. In this study, overseas repair material requirements were first analyzed, and present domestic requirements were improved repair material performance through field surveys of common concrete structures, laboratory experiments, and test construction on a disused concrete bridge. In addition, performancebased quality requirements were presented so that all materials that meet the required performance can be applied, and different test methods for each material were unified into concrete test methods for consistent test results analysis. The considered performance requirements were compression strength, bending strength, and bond strength for structural properties, and length change rate, crack resistance, thermal expansion coefficient, and elasticity coefficient were for dimensional behavior. For resistance to chloride penetration resistance and freeze-thaw resistance were presented as durability. The proposed requirements for concrete repair materials are expected to contribute to the improvement of the quality of concrete sectional repair work in Korea.