• Title/Summary/Keyword: Chloride concentrations

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Experimental Study on Corrosion Rate in Concrete

  • Jang, BongSeok;Oh, ByungHwan
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.34-38
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    • 2004
  • The corrosion of reinforcement is a very important factor on the serviceability and safety of reinforced concrete structures. The corrosion rate influences directly the cover failure time of reinforced concrete structures because the corrosion rate is used to estimate the amount of corrosion and thus expansive pressure due to corrosion. In this study, several series of experiments are performed considering the chloride concentration in artificial pore solution. The potentials are measured according to the applied current density and then corrosion current densities are obtained from the Tafel plot for various chloride concentrations. The measured corrosion rates show good correlation with those of other researchers.

Effect of Zinc Chloride on Commercial Trails of the Bivoltine Silkworm, Bombyx mori L.

  • Hugar, I.I.;Kaliwal, B.B.
    • International Journal of Industrial Entomology and Biomaterials
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    • v.6 no.1
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    • pp.75-79
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    • 2003
  • Oral supplementation of zinc chloride to silkworm larvae in different concentrations (30, 60 and 90 ${\mu}g$/ml) to the fourth and fifth instar resulted in a significant increase in commercial traits, like larval weight, silk gland weight, cocooning percentage in lower concentrartion (30 ${\mu}g$) treated group. The female cocoon weight, shell weight and its ratio were significantly increased in 30 and 60 ${\mu}g$ treated groups, male cocoon weight, and shell weight in 30 ${\mu}g$ treated group and its ratio in 60 and 90 ${\mu}g$ treated groups, filament length, weight and moth emergence percentage in all the treated groups and egg productivity in 90 ${\mu}g$ treated group were increased significantly. The remaining groups did not show any significant changes compared with that of carrier control.

Effect of Allopurinol on Methylmercuric Chloride-Induced Cytotoxicity in $C_6$ Cultured Glioma Cells

  • Oh, Yong-Leol;Son, Byoung-Kwan
    • Biomedical Science Letters
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    • v.12 no.4
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    • pp.451-455
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    • 2006
  • It is demonstrated that inorganic mercury has cytotoxic effect on glial cells. Recently, oxygen radicals is involved in methylmercuric chloride (MMC)-induced cytotoxicity. But, the toxic mechanism of MMC is left unknown. The purpose of this study was to examine the cytotoxicity of MMC on $C_6$ glioma cells. The cytotoxicy was measured by cell viability using XTT assay in $C_6$ glioma cells. Colorimetric assay is regarded as a very sensitive screening method for the determination of the cell viability on various agents. In this study, MMC decreased cell viability according to the dose- and time dependent manners after $C_6$ glioma cells were grown with various concentrations of MMC for 48 hours. In the protective effect of allopurinol on MMC-induced cytotoxicity, allopurinol was effective in the prevention of MMC-induced cytotoxicity in these cultures. These results suggest that MMC has highly cytotoxic effect on $C_6$ glioma cells by the decrease of cell viavility, and free radical scavenger such as allopurinol was effective on organic mercury-induced cytotoxicity in these cultures.

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Laboratory Evaluation of Select Methods of Corrosion Prevention in Reinforced Concrete Bridges

  • Pritzl, Matthew D.;Tabatabai, Habib;Ghorbanpoor, Al
    • International Journal of Concrete Structures and Materials
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    • v.8 no.3
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    • pp.201-212
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    • 2014
  • Sixteen reinforced concrete laboratory specimens were used to evaluate a number of corrosion prevention methods under an accelerated (6 months) testing program. The use of galvanic thermal sprayed zinc, galvanic embedded anodes, a tri-silane sealer, an acrylic coating, and an epoxy/polyurethane coating was evaluated. The specimens received various treatments prior to exposure to accelerated corrosion. The performance of the treatments was evaluated with respect to corrosion currents, chloride ingress, extent of cracking, severity of rust staining, and visual inspection of the reinforcing steel after the conclusion of testing and dissection. Results indicated that the tri-silane sealer, the conjoint use of galvanic thermal sprayed zinc and epoxy/polyurethane coating, the epoxy/polyurethane coating, and acrylic coating performed better than the other methods tested. Higher chloride concentrations were measured in the vicinity of embedded zinc anodes.

Catalytic Oxidation of Toluene by Manganese Oxide: (II) Support and Precursor Effect (망간 산화물에 의한 톨루엔 촉매 산화 반응: (II) 담체 및 전구물질 영향)

  • Cheon Tae-Jin;Choi Sung-Woo;Lee Chang-Soep
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.3
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    • pp.277-284
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    • 2005
  • Catalytic oxidation of toluene in low concentrations was investigated over various supports. As the manganese oxides loading was increased, the conversion of toluene increased at a lower temperature. The 18.2 $wt\%$ $Mn/\gamma-Al_2O_3$ appeared to be the most active catalyst. Among the supports, $\gamma-Al_2O_3$ was more active than $TiO_2$ and $SiO_2$. Manganese oxide catalysts prepared from manganese nitrate precursor were better for complete oxidation of toluene than those prepared from manganese sulfate and chloride precursor because sulfate from manganese sulfate and chloride from chloride manganese remained even after the calcination by XRD (X-Ray Diffraction) analyses.

Aerosol Size Distribution and Composition at Kosan, Cheju Island : Measurements in April 1998 (제주도 고산에서의 에어로솔 입경분포별 조성: 1998년 4월 측정 연구)

  • 김용표;배귀남;지준호;진현철;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.677-685
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    • 1999
  • Aerosol mass size distributions were measured at Kosan, Cheju Island in April 1998 and their compositions were analyzed. Microorifice Uniform Deposit Impactor(MOUDI) was used to collect aerosols. Sulfate and ammonium ions were predominatly present at fine mode of the aerosols while nitrate, chloride, and metal ions were mostly at coarse mode. Based on the size distribution of nitrate, it is suggested that most nitrate were from gas to particle conversion on coarse particles. Non-sea salt(nss) fraction of sulfate accounted for more than 90% of total sulfate mass concentration. In general, ion concentrations in this study are lower than those measured at the same site from the previous studies. Ion balance and chloride ion levels indicates that there had been anthropogenic chloride emission sources near to the site during the measurements.

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A Study on the Initiation of Pitting Corrosion of Fe-17Cr Alloy Using Micro-Droplet Cell Technique (Micro-droplet cell을 이용한 Fe-17Cr 합금의 공식 발생에 대한 연구)

  • Kim, Jae-Jung;Lee, Jae-Bong
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.809-816
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    • 2008
  • The influences of various parameters such as inclusions, surface roughness, exposed areas and chloride ion concentrations on the initiation of pitting of Fe-17Cr alloy were investigated, using micro-droplet cell technique. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local currents with the potentiodynamic polarization. Micro electrochemical tests were carried out at the inclusions after EDX analysis of inclusion. EDX analysis identified inclusions as Cr-oxides. It was found that some active inclusions among Cr-oxide inclusions acted as initiation sites for pitting corrosion. In addition, the rougher surface and the denser chloride ion concentration offered easier pit initiation sites, causing the more susceptible to pitting corrosion.

Ionic Equilibria in Mixed Solutions of Cuprous and Cupric Chloride (염화 제1구리와 제2구리 혼합용액의 이온평형)

  • Lee, Man Seung;Nicol, M.J.
    • Korean Journal of Metals and Materials
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    • v.46 no.1
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    • pp.20-25
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    • 2008
  • The ionic equilibira in mixed solutions of cuprous and cupric chloride were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. Required thermodynamic constants and interaction parameters were evaluated from the data reported in the literature. The effect of NaCl and CuCl concentrations on the pH and potential of the mixed solutions was explained in terms of the variation in the concentration of solutes and in the activity of hydrogen ion. The calculated pH values of the mixed solutions agreed well with the measured values. However, the calculated values for the potential of the mixed solutions were lower than the measured values, indicating the necessity of considering the complex formation between cuprous and chloride ion, such as $Cu^2Cl{_4}^{2-}$ and $Cu_3Cl{_6}^{3-}$.

Growth and Physiological Response of Three Evergreen Shrubs to De-icing Salt(CaCl2) at Different Concentrations in Winter - Focusing on Euonymus japonica, Rhodoendron indicum, and Buxus koreana - (겨울철 염화칼슘(CaCl2) 처리에 따른 가로변 3가지 상록 관목류의 생육 및 생리반응 - 사철나무, 영산홍, 회양목을 중심으로 -)

  • Ju, Jin-Hee;Park, Ji-Yeon;Xu, Hui;Lee, Eun-Yeob;Hyun, Kyoung-Hak;Jung, Jong-Suk;Choi, Eun-Young;Yoon, Yong-Han
    • Journal of the Korean Institute of Landscape Architecture
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    • v.44 no.2
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    • pp.122-129
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    • 2016
  • It is important to know the sensitivity of shrubs to de-icing salt in order to set guidelines for ecological tolerance of evergreen shrubs along roads. Therefore, the aim of this study was to investigate the influence of de-icing salt, calcium chloride($CaCl_2$), on the growth and physiological characteristics of three evergreen shrubs, Euonymus japonica, Rhododendron indicum, and Buxus koreana. Plants were exposed to calcium chloride at different concentrations(weight percentage, 0% as control, 1.0%, 3.0%, and 5.0%) through amended soil maintained from the start of the experiment in October of 2014 until termination in March of 2015. The survival rate, plant height, leaf length, leaf width, leaf shape index, number of leaves, fresh weight, dry weight, dry matter, root/top ratio, chlorophyll contents, fluorescence, photosynthesis, stomatal conduct, and transpiration rate were recorded. Elevated calcium chloride concentrations decreased plant height, leaf length, leaf width, leaf shape index, fresh weight, dry weight, dry matter, and R/T ratio of the three shrubs. Root growth responded more sensitively than the top growth to salinity. However Euonymus japonica was more tolerant to salt stress than Rhododendron indicum and Buxus koreana. Their growths were totally inhibited by $CaCl_2$ above 3.0% and 1.0% concentrations, respectively. Chlorophyll content, fluorescence, photosynthesis, stomatal conduct, and transpiration rate of both Rhododendron indicum and Buxus koreana were reduced sharply, while Euonymus japonica exhibited mild reductions compared to plants grown in control when increasing calcium chloride was used. Especially, the transpiration rates of Rhododendron indicum, and the photosynthesis and stomatal conduct of Buxus koreana were suppressed as the concentrations of calcium chloride increased. Therefore, Euonymus japonica should be considered as an ecologically tolerant species with proven tolerance to de-icing salt.

Experimental Studies on the Preparation of Some $^{99m}Tc$ Instant Labelling Kits (몇가지 $^{99m}Tc$ 즉석표식(卽席標識)킷트 제조(製造)를 위(爲)한 실험연구(實驗硏究))

  • Kim, Jae-Rok;Awh, Ok-Doo;Koo, Hyeon-Sook;Park, Kyung-Bae
    • The Korean Journal of Nuclear Medicine
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    • v.15 no.1
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    • pp.13-20
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    • 1981
  • Using stannous chloride, optimum conditions for $^{99m}Tc$ labelling of some scanning agents such as phytic acid (P A), dimercaptosuccinic acid (DMSA), and calcium diethylenetriaminepentaacetate (Ca-DPTA) were established. Methods of separation and identification of the labelled compounds were practiced by a paper- or thin layer- chromatography. Biodynamic studies of the compounds were also carried out. The results indicate that the molar ratios of the chelating agent and stannous chloride varies only with the concentrations of the chelating agents, and thus the amounts of the stannous chloride per labelling tube were nearly constant $(500\sim600{\mu}g)$ regardless the variation of the molar ratios. It suggests that the given experimental conditions require about $500{\mu}g$ of stannous chloride regardless of the chelating agents. Under alkaline pH, the labelling yields were drastically decreased due to the probable formation of colloidal tin compounds. Biodynamic data showed characteristic patterns with each compound indicating that they are all suitable for the relevant scanning applications.

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