Browse > Article

Catalytic Oxidation of Toluene by Manganese Oxide: (II) Support and Precursor Effect  

Cheon Tae-Jin (Department of Environmental Science and Engineering, Keimyung University)
Choi Sung-Woo (Department of Environmental Science and Engineering, Keimyung University)
Lee Chang-Soep (Department of Chemistry, Keimyung University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.21, no.3, 2005 , pp. 277-284 More about this Journal
Abstract
Catalytic oxidation of toluene in low concentrations was investigated over various supports. As the manganese oxides loading was increased, the conversion of toluene increased at a lower temperature. The 18.2 $wt\%$ $Mn/\gamma-Al_2O_3$ appeared to be the most active catalyst. Among the supports, $\gamma-Al_2O_3$ was more active than $TiO_2$ and $SiO_2$. Manganese oxide catalysts prepared from manganese nitrate precursor were better for complete oxidation of toluene than those prepared from manganese sulfate and chloride precursor because sulfate from manganese sulfate and chloride from chloride manganese remained even after the calcination by XRD (X-Ray Diffraction) analyses.
Keywords
Various supports; XRD;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Kim, S.C. (2002) The catalytic oxidation of aromatic hydrocarbons over supported metal oxide, J. Hazardous Materials, 91, 285-299   DOI   PUBMED   ScienceOn
2 Liu, Y., M. Luo, Z. Wei, Q. Xin, P. Ying, and C. Li (2001) Catalytic oxidation of chlorobenzene on supported manganese oxide catalysts, Applied Catalysis B: Environ., 29, 61-67   DOI   ScienceOn
3 Noordally, E., J.R. Richmond, and S.F. Tahir (1993) Destruction of Volatile Organic Compounds by catalytic oxidation, Catalysis Today, 17, 359-366   DOI   ScienceOn
4 Silva, A.M.T., R.R.N. Marques, and R.M. Quinta-Ferreira (2004) Catalysts based in cerium oxide for wet oxidation of acrylie acid in the prevention of environmental risks, Applied Catalysis B : Environ., 47, 269-279   DOI   ScienceOn
5 Stobbe, E.R., B.A. deBoer, and J.W. Geus (1999) The reduction and oxidation behaviour of manganese oxides, Catalysis Today, 47, 161 -167   DOI   ScienceOn
6 Tsou, J., L. Pinard, P. Magnoux, J.L. Figueiredo, and M. Guisnet (2003) Catalytic oxidation of volitale organic compounds (VOCs): Oxidation of o-xylene over Pt/HBEA catalysts, Applied Catalysis B: Environ, 46, 371 -379   DOI   ScienceOn
7 Rudy, E.N. and L.A. Carrol (1993) Select the best VOC control stratergy, chemical engineering progress, 89, 28-35
8 Ferreira, R.S.G., P.G.P. de Oliveira, and F.B. Noronha (2001) The effect of the nature of vanadium species on benzene total oxidation, Applied Catalysis B: Envicon. 29(4), 275-283   DOI   ScienceOn
9 Wu, X., L. Xu, and D. Weng (2004) The thermal stability and catalytic performance of Ce-Zr promoted $Rh-Pd/{\gamma}-AI_2O_3$ automotive catalysts, Applied Surface Science, 221,375-383   DOI   ScienceOn
10 Jeong, J.Y., K. Sekiguchi, W. Lee, and K. Sakamoto (2004) Photodegradation of gaseous volatile organic compounds (VOCs) using $TiO_2$ photoirradiated by an ozone-producing UV lamp : decomposition characteristics, identification of by-products and water -soluble organic intermediates, J. Photo & Photo. A : Chem. 169,277-285
11 Ronald, M.H., R.J. Farrauto, and S.T. Gulati (2002) Catalytic air pollution control; Commercial Technology 2nd Ed., Wiley interscience., 282pp
12 Einaga, H. and S. Futamura (2004) Catalytic oxidation of benzene with ozone over alumina-supported manganese oxides, J. Catalysis, 227, 304-305   DOI   ScienceOn
13 Larrson, P.O., H. Berggren, A. Andersson, and O. Augustsson (1997) Supported metal oxides for catalytic combustion of CO and VOCs emissions: preparation of titania overlayers on a macroporous support, Catalysis Today 35, 137-144   DOI   ScienceOn
14 Centeno, M.A., M. Paulis, M. Montes, and J.A. Odriozola (2002) Catalytic combustion of volatile organic compounds on $Au/CeO_2/AI_2O_3\;and\;Au/Al_2O_3$, catalysts, Applied Catalysis A: General, 234, 65-78   DOI   ScienceOn
15 Chen, A,, H. Xu, Y. Yue, W. Hua, W. Shen, Z. Gao (2003) Support effect in hydrogenation of methyl benzoate over supported manganese oxide catalysts, J. Molecular Catalysis A: Chemistry, 203, 299-306   DOI   ScienceOn
16 Tsou, J., P. Magnoux, M. Guisnet, J.J.M. Orfao, and J.L. Figueiredo (2004) Oscillations in the Catalytic Oxidation of Volatile Organic Compounds, J. Catalysis, 225, 147- 154   DOI   ScienceOn
17 Qi, G. and R.T. Yang (2003) Performance and kinetics study for low-temperature SCR of NO with $NH_3$ over $MnOx-CeO_2 $ atalyst, J. Catalysis, 217,434-441   DOI
18 Tsou, J., P.M.M. Guisnet, J.J.M. Orfao, and J.L. Figueiredo (2004) Catalytic oxdiation of volatile organic compounds: Oxidation of methyl-isobutyl-ketone over Pt/zeolite catalysts, Applied Catalysis B: Environ., 57, 117-123
19 Alvarez-Galvan, M.C., V.A. de la Pena O'Shea, J.L.G. Fierro, and P.L. Arias (2003) Alumina-supported manganese and manganese-palladium oxide catalysts for VOCs combustion, Catalysis Communication, 4, 223-228   DOI   ScienceOn
20 Ferreira, R.S.G., P.G.P. de Oliveira, and F.B. Noronha (2004) Characterization and catalytic activity of $Pd/V_2O_5/AI_2O_3$ catalysts on benzene total oxidation, Applied Catalysis B: Environ., 50, 243-249   DOI   ScienceOn
21 Spivey, J.J. (1987) Complete Catalytic Oxidation of Volatile Organics, Ind. Eng. Chem. Res., 26, 2 165-2180
22 Kundakovic, L.J. and M. Flytzani-Stephanopoulos (1998) Reduction characteristics of copper oxide in cerium and zirconium oxide systems, Applied Catalysis A: General 171, 13 -29   DOI   ScienceOn
23 Robert, J.F., K. Jordan, M. Lampert, C. Hobson, and E.M. Waterman (1995) Thermal decomposition and reformation of PdO catalysts; support effect, Applied Catalysis B: Environ., 6, 263-270   DOI   ScienceOn
24 Liu, Y., Z. Wei, Z. Feng, M. Luo, P. Ying, and C. Li (2001) Oxidative Destruction of Chlorobenzene and o-Dichlorobenzene on a Highly Active Catalyst: $MnOx /TiO_2-Al_2O_3$, J. Catalysis 202, 200-204   DOI   ScienceOn
25 Luo, M.F., X.X. Yuan, and X.M. Zheng (1998) Catalyst characterization and activity of Ag-Mn, Ag-Co and Ag-Ce composite oxides for oxidation of volatile organic compounds, Applied Catalysis A: General 175, 121-129   DOI   ScienceOn
26 Skoglundh, M.L., O . Lowendahl, and J.E. Ottersted (1991) Combinations of platium and palladium on alumina supports as oxidation catalysts, Applied Catalysis, 77, 9-20   DOI   ScienceOn