• Title/Summary/Keyword: Chemistry Experiment

Search Result 1,237, Processing Time 0.028 seconds

Optimization red emission of SrMoO4: Eu3+ via hydro-thermal co-precipitation synthesis using orthogonal experiment

  • Tan, Yongjun;Luo, Xuedan;Mao, Mingfu;Shu, Dehua;Shan, Wenfei;Li, Guizhi;Guo, Dongcai
    • Current Applied Physics
    • /
    • v.18 no.11
    • /
    • pp.1403-1409
    • /
    • 2018
  • In the present study, the $SrMoO_4:Eu^{3+}$ phosphors has been synthesized through hydro-thermal co-precipitation method, and single factor and orthogonal experiment method was adopted to find optimal synthesis condition. It is interesting to note that hydro-thermal temperature is a prominent effect on the luminescent intensity of $SrMoO_4:Eu^{3+}$ red phosphor, followed by co-precipitation temperature, calcining time, and the doping amount of $Eu^{3+}$. The optimal synthesis conditions were obtained: hydro-thermal temperature is $145^{\circ}C$, co-precipitation temperature is $35^{\circ}C$, the calcining time is 2.5 h, and the doping amount of activator $Eu^{3+}$ is 25%. Subsequently, the crystalline particle size, phase composition and morphology of the synthesized phosphors were evaluated by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The results show that these phosphors possess a scheelite-type tetragonal structure, and the particle size is about $0.2{\mu}m$. Spectroscopic investigations of the synthesized phosphors are carried out with the help of photo-luminescence excitation and emission analysis. The studies reveal that $SrMoO_4:Eu^{3+}$ phosphor efficiently convert radiation of 394 nm-592 and 616 nm for red light, and the luminescence intensity of $SrMoO_4:Eu^{3+}$ phosphors is improved. $SrMoO_4:Eu^{3+}$ phosphors may be a potential application for enhancing the efficiency of white LEDs.

Flavonoids of Gomphocarpus sinaicus and Evaluation of Some Pharmacological Activities

  • Batran, Seham A. El;Abdel-Azim, Nahla S.;Abdel-Shafeek, Khaled A.;Shahat, Abd-Elatty A.;El-Missiry, Moustafa M.
    • Natural Product Sciences
    • /
    • v.11 no.4
    • /
    • pp.233-239
    • /
    • 2005
  • The aerial parts of Gomphocarpus sinaicus Boiss. yielded four flavonoids that were identified as isorhamnetin 3-O-rhamnoglucoside (1), luteolin-7-O-glucoside-3-O-rhamnoside (2), rutin (3) and rutin-7-O-rhamnoside (4). All of the isolated flavonoids were identified by spectroscopic methods (UV, FAB-MS, $^1H-NMR\;&\;^{13}C-NMR$) and in comparison with the literature data. The isolated flavonoids 1, 2 and 4 are reported here for the first time from Gomphocarpus sinaicus Boiss. Three sets of experiments were carried out using the defatted alcoholic extract of Gomphocarpus sinaicus Boiss: the $1^{st}$ experiment indicated that the $LD_{50}$ was 49.82 mg/100 g b.wt. of intraperitoneally (i.p.) injected mice. The toxic signs were recorded within the first 24 hr post-injection. The $2^{nd}$ experiment revealed that the extract of the plant exhibited significant anti-inflammatory effects in normal rats. The $3^{rd}$ experiment was found that the tested doses of the extract in diabetic rats induced a significant decrease in serum glucose, AST, ALT, triglycerides, cholesterol and LDL, while HDL caused a significant increase.

Roles of Azospirillum spp. Inoculation in Two Consecutive Growth of Maize Plants

  • Choi, Seung-Ju;Gadagi, Ravi;Park, Myung-Su;Yang, Jin-Chul;Sa, Tong-Min
    • Korean Journal of Environmental Agriculture
    • /
    • v.21 no.1
    • /
    • pp.74-79
    • /
    • 2002
  • Two consecutive green house experiments were carried out to examine the effect of Azospirillum spp. inoculation on growth, nitrogen and phosphorus accumulation in maize plants grown in pots. There were eight treatments including an uninoculated control and Azospirillum strains OAD-3, OAD-9, AZ-22, AZ-8, AZ-9, Azospirillum brasilense BR-11001 and Azospirillum lipoferum BR-11080. The inoculated plants showed higher values in each of the following measurements; plant height, total dry mass and nitrogen and phosphorus accumulation in shoot when compared to the uninoculated control plants in two consecutive experiments conducted in the same soil. Among Azospirillum strains, Azospirillum sp. OAD-3 inoculated plants showed higher nitrogen accumulation by 44.5% and 45.1%, total dry mass by 48.6% and 66.9% in two consecutive experiments respectively. The nitrogen concentration in the maize plants was not changed significantly in the first experiment, however it increased significantly in the second experiment due to Azospirillum inoculation. In addition, Azospirillum sp. OAD-9 and A. brasilense BR-11001 also proved to be effective with respect to total dry mass, total nitrogen accumulation and total phosphorus accumulation. The nitrogen concentrations in maize plants were increased in the second experiment due to Azospirillum inoculation.

The difference of metabolic profile between male and female zebrafish

  • Yoon, Dahye;Choi, Jin;Choi, Hyeonsoo;Kim, Suhkmann
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.20 no.1
    • /
    • pp.13-16
    • /
    • 2016
  • Various experiments using zebrafish have been highlighted recently in the scientific community. Because it is possible to conduct practical experiment from various neurological research to area of genetic study or toxicity experiment. However, gender difference effects are nearly not considered. If the gender differences of zebrafish are considered it is possible to obtain more accurate data. In this study, zebrafish which have different genders were compared each other with NMR-based metabolomics. The extracts of male and female zebrafish were measured by 600 MHz NMR spectrometer. Statistical analysis and target profiling were conducted. As a result, muscle related metabolites were observed in male zebrafish and nerve related metabolites were observed in female zebrafish.

Study of Inorganic Photocatalyst Media for Reused Wastewater (폐수 재이용을 위한 무기계 광촉매 담체 연구)

  • Lee, Gyuyoung;Kim, Jungchul;Lim, Jihyun;Lee, Junwoo;Park, Jeongmi;Lee, Seunghun;Nam, Jukyung;Lee, Yong-Woo
    • Journal of Korean Society on Water Environment
    • /
    • v.31 no.1
    • /
    • pp.42-48
    • /
    • 2015
  • This study focused on effective decomposition methods for low concentrated organic compounds from the reuse of industrial wastewater, and confirmed the possibility through photocatalyst media. Photocatalyst immobilized media was developed to carry on this experiment which confirmed the removal possibility of low concentrated organic compounds. Considering the stability and efficiency of photocatalyst immobilization, inorganic support, hollow bead, and $TiO_2$ nano powder were used. As a result of the removal experiment, the removal efficiencies of acetonitrile, ethanol, IPA(Isopropyl alcohol), methanol were above 75% after 15 minutes while those of acetone, acetaldehyde, urea were 10%, 45%, 20%, respectively after 60 minutes. If further studies were made to increase the surface area of the photocatalyst immobilized media, the efficiency of the removal of low concentrated organic compounds can be improved and this solution can also be used in an actual treatment process.

Analysis of Experiments for the Rules of Material Change Unit in 9th Grade Science Textbooks and the Development of Experiments Applying Small-Scale Chemistry (9학년 과학교과서 물질변화에서의 규칙성 단원 실험 분석과 Small-Scale Chemistry를 적용한 실험 개발)

  • Ryu, Ran-Yeong;Kim, Dong-Jin;Hwang, Hyun-Sook;Park, Se-Yeol;Lee, Sang-Kwon;Park, Kuk-Tae
    • Journal of the Korean Chemical Society
    • /
    • v.55 no.3
    • /
    • pp.529-540
    • /
    • 2011
  • The purpose of this study was to analyze experiments for the rules of material change unit in 9th grade science textbooks and develop experiments applying small-scale chemistry (SSC). For this study, experimental methods for the precipitation experiment, water electrolysis experiment, decomposition of hydrogen peroxide experiment presented in the 9 science textbooks were analyzed. Problems and improvements that were needed were extracted by 13 science teachers performing the experiments. Experiments applying SSC were developed based on the improvements needed. Afterwards, 19 pre-service science teachers performed both the developed SSC experiments and the science textbooks' experiments. A questionnaire about merits and demerits of the experiments applying SSC was performed. According to the results of this study, most of the 9th grade science textbooks included the lead iodide precipitation experiment, water electrolysis experiment by Hoffman voltameter, and decomposition of hydrogen peroxide experiment using catalytic manganese dioxide. Improvements were needed on the quantity of reagents, time for performing experiments, and scale of experimental apparatus. Merits of the developed experiments applying SSC which used small amount of reagents were safety, easy waste material disposal, short reaction time, and reproducible experimental results. Demerits of the experiments applying SSC were difficulty in observing, decreased achievement, and lack of skill in handling small-scale apparatus. Therefore, if the experiments developed applying SSC were to be utilized in 9th grade science experiments, it will be possible to use less reagent and be able to teach and carry out reproducible experiments at the same time. Also, the reproducible experiments based on SSC will help students under stand the scientific concepts for the rules of material change unit.

Inhibitory Effect of the Selected Heavy Metals on the Growth of the Phosphorus Accumulating Microorganism, Acinetobacter sp.

  • Chung, Keun-Yook;Han, Seok-Soon;Kim, Hong-Ki;Choi, Guak-Soon;Kim, In-Su;Lee, Sang-Sung;Woo, Sun-Hee;Lee, Kyung-Ho;Kim, Jai-Joung
    • Korean Journal of Environmental Agriculture
    • /
    • v.25 no.1
    • /
    • pp.40-46
    • /
    • 2006
  • This study was initiated to evaluate the inhibitory effect of selected heavy metals on the growth of Acinetobacter sp. Down as one of the phosphorus accumulating microorganisms (PAO) involved in the enhanced biological phosphorus removal (EBPR) process of the wastewater treatment plant. Acinetobacter sp. was initially selected as a starting model microorganism and was grown under aerobic condition for this experiment. The heavy metals selected and investigated in this study were cadmium (Cd), copper (Cu), mercury (Hg), nickel (Ni), and zinc (Zn). Median $(IC_{50})$ and threshold $(IC_{10})$ inhibitory concentrations for Cd, Cu, Hg, Ni, and Zn were 2.95 and 1.45, 4.92 and 2.53, 0.03 and 0.02, 1.12 and 0.43, 14.84 and 5.46 mg $L^{-1}$, respectively. We demonstrated that most of heavy metals tested in the experiment inhibited the growth of Acinetobacter sp. in the range of predetermined concentrations. Based on the data obtained from the experiment, Hg was the most sensitive to Acinetobacter sp., then Ni, Cd, Cu, and Zn in order.

An Analysis and Improvement of the Experiment of the Acid-Base Neutralization Reaction (산-염기 중화반응 실험의 문제점 분석 및 개선 방안)

  • Jeon, Yeong-Hwa;Hong, Lan-Sun;Kang, Young-Jin;Kang, Seong-Joo
    • Journal of the Korean Chemical Society
    • /
    • v.48 no.2
    • /
    • pp.189-194
    • /
    • 2004
  • The aim of this study is to analyze and improve the experiment of the acid-base neutralization reaction described in science textbooks. The problems in the neutralization reaction of NaOH-HCl solution were following; 1) the decoloration of phenolphthalein solution, 2) the color change of the titrated solution during condensation for the confirmation of the salt crystals, 3) the difficulty for the confirmation of the salt crystals. These problems are explained by the structure change of phenolphthalein and the improved experiment is proposed.

Enzyme and Microbial Activities in Paddy Soil Amended Continuously with Different Fertilizer Systems

  • Gadagi, Ravi;Park, Chang-Young;Im, Geon-Jae;Lee, Dong-Chang;Chung, Jong-Bae;Singvilay, Olayvanh;Sa, Tong-Min
    • Korean Journal of Environmental Agriculture
    • /
    • v.20 no.5
    • /
    • pp.325-329
    • /
    • 2001
  • Soil enzyme and microbial activities are affected by fertilizer and compost applications and can be used as sensitive indicators of ecological stability. Microbial population and soil enzymes viz., dehydrogenase, urease, acid phosphatase and aryl-sulphatase were determined in the long-term fertilizer and compost applied paddy soil. Soil samples were collected from the four treatments (control, compost, NPK and compost+NPK). Long-term NPK+compost application significantly increased activities of urease, dehydrogenase and acid phosphatase than all other treatments. The compost application enhanced activities of urease, dehydrogenase and acid phosphatase than the NPK application. However, arylsulfatase activity was not significantly different between compost and fertilizer application. The highest microbial population was recorded in the NPK+compost treatment. The compost application also resulted in higher microbial population than the NPK application. The above results indicate that ecological stability could be maintained by application of compost alone or with NPK.

  • PDF