• Title/Summary/Keyword: Chemical test

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Evaluation on the Properties of Modified-sulfur Concrete as a Basic Study for Development of Anti-corrosive Concrete (내부식성 콘크리트 개발을 위한 기초연구로서 개질유황 혼합 콘크리트의 물성 평가)

  • Park, Sang-Soon;Na, Ok-Jung
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.28-37
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    • 2016
  • Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

An Experimental Study on the Effect of Accelerator and Chemical Admixture Type for the Durability of Shotcrete (급결제 및 혼화제 종류가 숏크리트 내구성에 미치는 영향에 관한 연구)

  • 백신원;권소진;이영수;김의성;신용석
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.109-113
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    • 2003
  • Concrete and shotcrete should withstand the conditions for which they have been designed, without deterioration, over a period of years. But connote and shotcrete are being deteriorated according to aging by internal and external causes. Recently, many studies on the durability of concrete have been conducted But the durability of shotcrete is rarely studied. So, in this study, chloride ion penetration test freeze and thaw test neutralization test were conducted to examine the durability characteristics of shotcrete with several accelerator and chemical admixture types. These results indicate that shotcrete with allah free accelerator and with superplasticizer are durable. Therefore, the present study provides a fm base to make high performance shotcrete.

NIR PREDICTIONS OF INDIRECT RESPONSES

  • Claridge, Rovert-Burling;Ross Clarke
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.3103-3103
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    • 2001
  • NIR has been extensively used to predict directly measurable properties of materials that are important to the appropriate industries. Commonly, NIR is used to perform fast, routine tests to improve control response as against the response time for the (normally chemical) base test. This paper discusses the use of NIR to measure indirect properties of materials. In these cases, the pure chemical or physical tests are either unable measure the appropriate parameters (eg GMO modification) or there are mitigating effects that are not properly addressed by the base tests. In particular, we looked at the digestible portion of amino acids within meat and bone meal. This is the desired response measurement by end-users of the product (intensive livestock producers) but is currently unable to be offered as a measurement by producers. The base test method is by controlled feeding trials. These are somewhat cumbersome, taking 2-3 months, involving several sets of animals, and considerable expense. A shortened test (feed trial based) would be of little use, as the precision blows out over short period feeding trials. For example, a rat ileal digestibility test requires around 2 months, and costs some $USD1000. This is clearly impractical test for a producer involved in continuous production, with a 1-2 day turn around. While the amino acid abundance is accessible chemically, the uptake of amino acids into usable material by mammalian species is not simply related to the measured abundance within the material. There are many co-related material properties that might help or hinder uptake, some chemical based (eg protein damage), some indirect (eg palatability), some physiological (intestinal tract response vs speed of throughput). We discuss the approaches taken to provide a suitable reference data set, and present the derived prediction and validation relationships.

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Experimental Test Time Reduction Method for Step Responses Using the Time-Optimal Control Technique (시간최적제어 기법을 이용한 계단응답 실험시간 단축 방법)

  • Lee, Jietae
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.190-196
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    • 2020
  • The step to obtain a process dynamic model through process experiments is very important because it needs times and expenditures. Step response method is one of the standard methods to have long been used for understanding process dynamics, obtaining dynamical models and designing control systems. For the step response, it is usually required to measure process output for a step input change in the open-loop manner. Its disadvantage criticized is the long open-loop operation. For this, a method based on the time-optimal control technique to minimize the test time for obtaining the step response has been recently presented. However, the method requires iterative computations for the minimization of test times. Here, a method where iterative computations are not required is proposed. Simulation results are presented to show that test times to obtain step responses are reduced considerably and an autotuning method based on the proposed method is compared with the relay feedback autotuning method accepted widely for the autotuning of controllers.

Petrographic Study(ASTM C 295) on the KEDO Concrete Aggregates (콘크리트용 KEDO 골재의 암석기재시험 (ASTM C295))

  • Jeong, Ji-Gon;Kim, Kyung-Su;Lee, Chol-Woo
    • The Journal of Engineering Geology
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    • v.17 no.4
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    • pp.589-599
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    • 2007
  • For the preliminary judgement on the chemical stability of concrete aggregates mixed with cement paste, ASTM C 295 method can be applied prior to the long-term chemical test methods. By using this standard test method, the petrographic study on the appropriateness of natural KEDO aggregates for concrete was carried out. With the natural gravel and sand aggregates, the polarized microscope, stereoscopic microscope, and X-ray diffractometer were used for examination. The result shows the 23% of gravel aggregates and 5.1% of sand aggregates are chemically unstable. To select the favorable KEDO concrete aggregates, it is required to exclude the highly metamorphosed rocks, acidic volcanic rocks, highly foliated rocks, and expansive rocks identified from mortar-bar test. Further chemical test and mortar-bar test method integrated with this study is recommended for the suitability assessment of natural KEDO concrete aggregates.

Life Expectancy Estimation of the Propellants KM10 using High Temperature Acceleration Aging Tests and Stockpile Analysis Test (고온가속노화시험법과 저장분석시험법을 이용한 추진제 KM10의 기대수명 평가)

  • Cho, Ki-Hong;Kim, Eui Yong
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.695-699
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    • 2010
  • The propellant KM10, a single propellant manufactured from nitrocellulose, was known to cause natural degradation phenomena at long term storage. In this study, the self-life was estimated using high temperature acceleration aging tests and stockpile analysis test. For the life expectancy estimation, Arrhenius equation and Berthelot equation were used in the high temperature acceleration tests, and the first order regression was used in the Stockpile analysis test. The self-life of propellant KM10 using the Arrhenius equation and Berthelot equation showed significantly different results as 43.73, 16.53 years in the high temperature acceleration test, and it showed 42.94 years in the Stockpile analysis test. The value of self-life predicted by Arrhenius equation was reasonable when compared with the result of E. R. Bixon.

A Comparative Study on Test Methods for Ophthalmic Lens Coatings (안경렌즈 코팅의 평가 방법에 관한 비교 연구)

  • Yu, Dong-Sik;Moon, Byeong-Yeon;Ha, Jin-Wook
    • Journal of Korean Ophthalmic Optics Society
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    • v.11 no.1
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    • pp.7-15
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    • 2006
  • We have surveyed test methods for ophthalmic lens coatings and compared the coating quality of lenses supplied by manufactures. Plastic ophthalmic lenses are produced in increasingly larger volumes. However, their softness have need resistant coatings absolutely essential in most cases. Coating lenses are typically evaluated in physical and chemical properties through random selection from produced lenses. No international standard test methods for ophthalmic lenses exist for issues such as adhesion, abrasion resistance, hardness, chemical and hot water resistance with exception of transmittance. We have learned that there is a great deal of confusion regarding the methods employed in the various tests for ophthalmic coating lenses. For this reason, test methods for ophthalmic lens coatings are needed making all of international or domestic standards available.

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The Minimum Concentration of Organic Solvents Inducing Phytotoxicity and Their Symptoms (유기용매(有機溶媒)의 약해유발(藥害誘發) 농도(濃度)와 그 증상(症狀))

  • Yu, Ju-Hyun;Kim, Jin-Seog;Cho, Kwang-Yun
    • Applied Biological Chemistry
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    • v.32 no.3
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    • pp.255-264
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    • 1989
  • The minimum concentrations of organic solvents inducing phytotoxicity were investigated after spraying or flooding solvent solutions to annual plants. In the foliar treatment of upland test, solvents with high-boiling point or low-polarity induced severe phytotoxicity. Especially, aromatic solvents induced severe phytotoxicity. The most sensitive plant to phytotoxicity was soybean. In the pre-emergence treatment of upland test, the solvents with high-boiling point only induced phytotoxicity at high concentration. The degree of phytotoxicity induced by foliar spray in the condition of paddy field was similiar to that of upland test, but in the pre-emergence test, the former was more severe than the latter. Among 6 treatments, phytotoxicity induced by solvents was most severe in the pre-emergence test under the condition of flooding paddy field. Generally, alcohols induced severe phytotoxicity, especially, ethanol at 0.001%.

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Analysis of the Reinforcement Effect of Aging Reservoir Reinforced by Environmental Soil Stabilizer as Chemical Grouting Material (친환경 지반안정재를 약액주입재로 사용하여 보강한 노후 저수지의 보강효과 분석)

  • Kim, Se-Min;Seo, Se-Gwan;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.20 no.2
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    • pp.1-11
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    • 2021
  • In this study, a study related to laboratory and pilot test were performed to use an environmental soil stabilizer developed to induce a hardening reaction similar to that of Ordinary Portland Cement (OPC) by using industrial by-products of blast furnace slag and the combustion ash of a circulating fluidized bed boiler as the main material. For this, specimens were prepared using liquid A of sodium silicate and silica sol, and liquid B of an environmental soil stabilizer (or OPC), and laboratory tests were performed to analyze the strength and environmental characteristics. And pilot test was performed on the aging reservoir, field permeability test and electrical resistivity survey were performed in the field to analyze the applicability. As a result of the laboratory test, the homo-gel compressive strength of the chemical injection material using the environmental soil stabilizer as liquid B was about 2.88 to 3.23 times greater than that of OPC. In addition, the elution amount of most heavy metals was lower than that of OPC, and the survival rate in the fish, acute toxicity test was 100%. Therefore, when judged based on the results of the laboratory test, it was analyzed to be superior to OPC in terms of strength and environment. In the results of the pilot test in the aging reservoir, when the environmental soil stabilizer was reinforced with liquid B of the chemical injection material, the coefficient of permeability in the aging reservoir decreased to 1/50 level. In addition, as a result of the electrical resistivity survey, it was analyzed that the electrical resistivity inside the aging reservoir increased as time passed, the saturation zone disappeared, and the overall reinforcement.

Material Properties of 400MPa Grade Hot Rolled H-beam(SHN400) for Building Structure (400MPa급 건축구조용 열간압연 H형강(SHN400)의 소재 특성)

  • Kim, Hee-Dong;Choi, Byoung-Jeong;Kim, Sang-Sub;Kim, Chul-Hwan;Oh, Young-Suk
    • Journal of Korean Society of Steel Construction
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    • v.23 no.4
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    • pp.515-522
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    • 2011
  • The purpose of this study was to evaluate the material characteristics of SHN400 steel, which is suitable as a steel material for building structures, using the experimental approach. For this purpose, the chemical composition test, tensile test, macro test, micro test, and charpy notch impact test were conducted with specimens taken from the highest, thickest, and commonly used H-beams for girder or beam members. Each test was conducted under the Korean Standard(KS) test conditions. All the test results satisfied the requirements of KS (KS D 3866) and the steel material for seismic design. The carbon equivalent value (Ceq), which is related to weldability, and the yield ratio, which is related to inelastic behavior, showed especially good results. Thus, SHN400 is definitely suitable as the steel material for building structures.