• 대한기계학회논문집B
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• 제22권2호
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• pp.173-183
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• 1998

An optimization procedure to find the inlet concentration profile that yields the most uniform deposition rate in a cylindrical CVD chamber has been developed. Assuming that the chemical reaction time is negligibly small, a SIMPLE based finite-volume method is adopted to solve the fully elliptic equations for momentum, temperature, and concentration. The inlet concentration profile is expressed by a linear combination of Chebyshev polynomials and the coefficients of which are determined by the local random search technique. It is shown that the present method is very effective in improving the uniformity of the deposition rate, especially when Re is high and/or the wafer is placed close to the inlet. The optimal profiles have been obtained for various Re, Gr, and geometry combinations.

• Korean Chemical Engineering Research
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• 제58권3호
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• pp.390-395
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• 2020

몇몇 포화를 갖는 공정에서 경제적인 운전점이 포화시작점에 있게 된다. 고전적인 피드백 제어기는 포화시작점에서 동특성이 급박하게 바뀌고 포화가 된 상태에서는 피드백을 위한 정보가 없기 때문에 사용할 수가 없다. 포화점과 동특성이 알려져 있고 바뀌지 않을 때는 모델예측제어 같은 최적화를 기반으로 하는 방법들이 어려움 없이 이 제어 문제를 처리할 수 있다. 그렇지 않으면, 이 포화점과 등특성을 추적하는 적응 방법이 첨가되어야 한다. 여기서는, 이 제어 문제를 해결할 수 있는 매우 간단한 방법들로서, 최근의 slope seeking method와 relay feedback method에 기반한 두가지 제어 방법을 제안한다. 포화현상을 갖는 이차 액위제어 공정에 적용한 모사를 통하여 그 성능을 검사하였다. 모사결과는 제안하는 본 제어 방법들이 포화시작점을 5% 이내로 찾고 유지하는 것을 보여주고 있다.

• 농약과학회지
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• 제11권1호
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• pp.1-7
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• 2007

살균활성을 보이는 천연물인 incrustoporin(1)의 기본골격인 2(5H)-furanone을 포함하는 유도체 2를 microwave를 이용한 Suzuki-Miyaura coupling 반응으로 합성하였고, 또한 furanone의 화학구조에서 산소원자를 탄소원자로 치환한 2-cycloalkenone 유도체 3 및 4를 유사한 방법으로 합성하였다. 합성한 이들 유도체들의 살균활성을 6종의 식물병원균에 대하여 조사한 결과, 벼 도열병 및 토마토 역병에 대하여 다소 방제효과를 나타내었다. 따라서 이들 유도체들은 다양한 구조변화를 통한 살균제 개발에 활용할 수 있을 것으로 생각된다.

• 공업화학
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• 제9권7호
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• pp.1043-1046
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• 1998

국내에서 상수원중의 부유물질 및 용존 유기물질의 제거를 위하여 사용하는 알루미늄계 무기응집제들은 응집처리 과정에서 노인성 치매의 한 원인으로 알려져 있는 알루미늄 이온을 상수원수에 잔류시킬 수 있으며, 상수의 탁도가 일시적으로 매우 높아질 때 효과적인 응집에 한계가 있다. 따라서 이들을 대신한 epichlorohydrine-dimethylamine(EPI-DMA) poly(amine)계 고분자 응집제가 선진국을 중심으로 사용이 되어 왔으며, 우리나라에서도 이것을 도입하기 위한 준비가 필요한 상태에 있다. 본 연구에서는 먼저 EPI-DMA poly(amine)계 고분자 응집제의 국산화를 위해 EPI와 DMA의 조성비를 달리하거나 또는 반응시간, 반응온도 등의 합성조건을 변화시키면서 이들의 합성조건에 대한 최적화 연구를 수행하여 대량생산을 위한 최적합성 조건을 구하였다. 그리고 이 과정에서 조건을 달리하여 얻은 각각의 고분자 응집제들에 대한 점도를 측정하여 합성 방법에 따른 고분자 응집제의 효율을 조사하였으며, EPI, DCP, DCIPA, 그리고 CPDO 등 유해 잔류물의 양을 Gas Chromatography(GC)에 의해 정량하였다.

• Membrane and Water Treatment
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• 제14권4호
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• pp.181-189
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• 2023

The Covid-19 pandemic has increased demand for chlorine-based sanitizing solutions, most of which contain hypochlorous acid (HOCl) as an active agent. Free chlorine (HOCl) in these sanitizers is crucial for their efficacy. Disposable test strips are affordable and convenient tools for determining various qualitative and quantitative parameters. In this study, disposable opto-chemical test strips were developed by physically immobilizing 3,3',5,5'-tetramethylbenzidine (TMB) and o-dianisidine (o-D) reagents on chromatography and filter paper-based test strips for the visualization and detection of free chlorine in the form of HOCl. The reagents undergo a rapid color change upon reaction with chlorine through a redox reaction. The paper-based test strips showed rapid color change within a minute and a low sample volume requirement (1 ml). This portable, disposable paper-based test strip is a simple and cost-effective way to rapidly detect the presence of HOCl sanitizers for home and field applications. Both TMB and o-D successfully detected chlorine. Chromatography paper proved to be the more efficient option among the two papers used as substrates for the reagents (TMB and o-D). It exhibited high retention capacity and high performance in terms of color transformation when reacting with HOCl, even after two months of storage.

• International Journal of Fluid Machinery and Systems
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• 제5권3호
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• pp.134-142
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• 2012

The competition to deliver ultra-low emitting vehicles at a reasonable cost is driving the automotive industry to invest significant manpower and test laboratory resources in the design optimization of increasingly complex exhaust after-treatment systems. Optimization can no longer be based on traditional approaches, which are intensive in hardware use and laboratory testing. The CFD is in high demand for the analysis and design in order to reduce developing cost and time consuming in experiments. This paper describes the development of a comprehensive practical model based on experiments for simulating the performance of automotive three-way catalytic converters, which are employed to reduce engine exhaust emissions. An experiment is conducted to measure species concentrations before and after catalytic converter for different loads on engine. The model simulates the emission system behavior by using an exhaust system heat conservation and catalyst chemical kinetic sub-model. CFD simulation is used to study the performance of automotive catalytic converter. The substrate is modeled as a porous media in FLUENT and the standard k-e model is used for turbulence. The flow pattern is changed from axial to radial by changing the substrate model inside the catalytic converter and the flow distribution and the conversion efficiency of CO, HC and NOx are achieved first, and the predictions are in good agreement with the experimental measurements. It is found that the conversion from axial to radial flow makes the catalytic converter more efficient. These studies help to understand better the performance of the catalytic converter in order to optimize the converter design.

• KSBB Journal
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• 제24권4호
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• pp.361-366
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• 2009

본 연구에서는 반응표면분석법 (RSM)을 따른 고추 대의 묽은 황산을 이용한 자일로즈 분별 공정을 통해 고추대 시료로부터 최적의 자일로즈 수율을 얻을 수 있는 반응조건을 예측할 수 있었다. 실제 실험 결과 최적 반응은 온도 $147^{\circ}C$, 산 농도 2.8% $H_2SO_4$, 반응시간 21 min. 임을 알 수 있었고 최적 조건에서의 실험결과는 예측 값 78% 보다 약 7% 낮은 71% 자일로즈 수율을 얻을 수 있었다. SEM과 XRD분석을 통해 전처리 전후의 시료의 이미지 분석을 하여 산 전처리 공정을 통해 섬유소 기질 외 다른 성분인 반 섬유소가 분해 되어 추출액상으로 자일로즈로 용해 되었음을 가시적으로 확인 할 수 있었고 전처리 된 고추대의 결정화 도가 전처리 전보다 증가했음을 확인 할 수 있었다. 이로써 비결정성 물질인 반섬유소와 기타 성분들이 묽은 황산을 이용한 자일로즈 분별공정에 의해 분리되었음을 확인하였다.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 춘계학술대회 논문집
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• pp.29-36
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• 2004

A numerical study is carried out on the detonation wave propagation through a T-shaped flame tube, which represents a crucial part of the combustion wave ignition (CWI) system aimed for simultaneous ignition of multiple combustion chambers by delivering detonation waves. The formulation includes the Euler equations and an induction-parameter model. The reaction rate is treated based on a chemical kinetics database obtained from a detailed chemistry mechanism. A second-order implicit time integration and a third-order TVD algorithm are Implemented to solve the theoretical model numerically. A total of more than two-million grid points are used to provide direct insight into the dynamics of the detonation wave. Several important phenomena including detonation wave propagation, degeneration, and re-initiation are carefully examined. Information obtained can be effectively used to facilitate the design and optimization of the flame tubes of CWI systems.

• 융복합기술연구소 논문집
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• 제4권2호
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• pp.47-50
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• 2014

Voloxidation is a process for converting $UO_2$ into $U_3O_8$ while removing some volatile products in spent fuels (SF). Various oxidative gas conditions including air and mixture of Ar and $O_2$ could be adopted for the process. The gas flows into a reactor under high temperature ($>500^{\circ}C$) and components of SF are reacted with the gas. SF is composed of various components such as actinides, lanthanides, and alkali metals. Therefore, it is of significance to understand their behavior during the reactions for process development. However, due to the limit of available experiments, phase diagram analysis should be preceded. TPP diagram is constructed with respect to temperature-pressure-pressure. It shows a stable phase depending on partial pressures of gas components as well as temperature. In this work, we investigated TPP diagrams for actinides, lanthanides and other oxides to determine stable oxide forms under different gas conditions. The results would be used to set up a material balance under a pyroprocessing scheme of SF and compare the gas conditions for the optimization of fission products removal.

• Carbon letters
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• 제14권4호
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• pp.210-217
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• 2013

The synthesis of carbon nanomaterials (CNMs) by a chemical vapor deposition method using three different plant oils as precursors is presented. Because there are four parameters involved in the synthesis of CNM (i.e., the precursor, reaction temperature of the furnace, catalysts, and the carrier gas), each having three variables, it was decided to use the Taguchi optimization method with the 'the larger the better' concept. The best parameter regarding the yield of carbon varied for each type of precursor oil. It was a temperature of $900^{\circ}C$ + Ni as a catalyst for neem oil; $700^{\circ}C$ + Co for karanja oil and $500^{\circ}C$ + Zn as a catalyst for castor oil. The morphology of the nanocarbon produced was also impacted by different parameters. Neem oil and castor oil produced carbon nanotube (CNT) at $900^{\circ}C$; at lower temperatures, sphere-like structures developed. In contrast, karanja oil produced CNTs at all the assessed temperatures. X-ray diffraction and Raman diffraction analyses confirmed that the nanocarbon (both carbon nano beads and CNTs) produced were graphitic in nature.