• Title/Summary/Keyword: Chemical flow control

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Research for High Quality Ingot Production in Large Diameter Continuous Czochralski Method (대구경 연속성장 초크랄스키법에서 고품질 잉곳 생산을 위한 연구)

  • Lee, Yu Ri;Jung, Jae Hak
    • Current Photovoltaic Research
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    • v.4 no.3
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    • pp.124-129
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    • 2016
  • Recently industry has voiced a need for optimally designing the production process of low-cost, high-quality ingots by improving productivity and reducing production costs with the Czochralski process. Crystalline defect control is important for the production of high-quality ingots. Also oxygen is one of the most important impurities that influence crystalline defects in single crystals. Oxygen is dissolved into the silicon melt from the silica crucible and incorporated into the crystalline a far larger amount than other additives or impurities. Then it is eluted during the cooling process, there by causing various defect. Excessive quantities of oxygen degrade the quality of silicone. However an appropriate amount of oxygen can be beneficial. because it eliminates metallic impurities within the silicone. Therefore, when growing crystals, an attempt should be made not to eliminate oxygen, but to uniformly maintain its concentration. Thus, the control of oxygen concentration is essential for crystalline growth. At present, the control of oxygen concentration is actively being studied based on the interdependence of various factors such as crystal rotation, crucible rotation, argon flow, pressure, magnet position and magnetic strength. However for methods using a magnetic field, the initial investment and operating costs of the equipment affect the wafer pricing. Hence in this study simulations were performed with the purpose of producing low-cost, high-quality ingots through the development of a process to optimize oxygen concentration without the use of magnets and through the following. a process appropriate to the defect-free range was determined by regulating the pulling rate of the crystals.

A Numerical Study on Effects of Displacement of a Variable Area Nozzle on Flow and Thrust in a Jet Engine (가변노즐의 변위가 제트 엔진의 유동 및 추력특성에 미치는 영향에 관한 수치해석)

  • Park, Junho;Sohn, Chae Hoon;Park, Dong Chang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.1-9
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    • 2013
  • Variable area nozzle, where both throat and exit area vary, is required for optimal expansion and optimal nozzle shape upon operation of after-burner. Steady-state and transient analyses are carried out for each condition with and without afterburner operation and as a function of the location of the nozzle flap. Effects of that nozzle displacement on flow and thrust characteristics are analyzed from numerical results. With variable area nozzle adopted, the combustion field is variable in time, leading to periodically variable thrust. For off-design conditions, flow separation shows up due to over expansion at the flap tips and shock wave does in the nozzle due to under expansion. The undesirable phenomena can be solved by control of variable area nozzle.

The Development of HACCP-Based Standardized Recipe and the Quality Assessment of Cook/Chilled Soy Sauce Glazed Mackerel (쿡췰(Cook/Chill)시스템을 이용한 고등어조림의 HACCP 레시피 개발 및 생산과정의 품질평가)

  • Kwak, Tong-Kyung;Lee, Kyung-Eun;Park, Hye-Won;Ryu, Kyung;Hong, Wan-Soo;Choi, Eun-Jung;Jang, Hye-Ja;Kim, Sung-Hee
    • Korean journal of food and cookery science
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    • v.13 no.5
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    • pp.592-601
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    • 1997
  • The purposes of this study were to develop Hazard Analysis Critical Control Point-based standardized recipe applicable to cook/chilled soy sauceglazed mackerel and to evaluate the qualities related to the product flow of this item. After conducting experimental cooking, preliminary test, and analysis of recipes, critical control points were identified, control methods were determined, and HACCP-based recipe was standardized. At each critical control point, time-temperature profile was recorded and microbiological analysis (total aerobic plate counts, psychrotrophic plate count, coliform, and fecal coliform count), chemical analysis (pH, acid value and volatile based nitrogen (VBN)) and sensory evaluation of the item were done. Time-temperature data showed that the time the menu item had passed through temperature danger zone (5∼60$^{\circ}C$) during all phases was 60 min. At rapid cooling, but after cooling at room temperature, the temperature of this menu item did not drop below the ambient temperature. The results of microbiological test were negative throughout all phases following cooking and the results of chemical analysis did not change significantly in terms of storage periods except for VBN which increased on 7th day significantly(p<0.05). After steam/convection oven reheating and microwave oven reheating, the sensory score of the only appearance decreased significantly related to the storage time of overall quality profiles. But significant differences were not detected according to two reheating methods. In conclusion, this HACCP-based recipe was considered as an effective tool for assuring microbial as well as sensory quality of this cook/chilled item.

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Carbon molecular sieves from soybean straw-based activated carbon for CO2/CH4 separation

  • Xu, Yuxian;Chen, Xiaochuan;Wu, Dan;Luo, Yongjin;Liu, Xinping;Qian, Qingrong;Xiao, Liren;Chen, Qinghua
    • Carbon letters
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    • v.25
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    • pp.68-77
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    • 2018
  • Soybean straw (SS)-based activated carbon was employed as a precursor to prepare carbon molecular sieves (CMSs) via chemical vapor deposition (CVD) technique using methane as carbon source. Prior to the CVD process, SS was activated by 0.5 wt% $ZnCl_2$, followed by a carbonization at $500^{\circ}C$ for 1 h in $N_2$ atmosphere. $N_2$ (77 K) adsorption-desorption and $CO_2$ (273 K) adsorption tests were carried out to analyze the pore structure of the prepared CMSs. The results show that increasing the deposition temperature, time or methane flow rate leads the decrease in $N_2$ adsorption capacity, micropore volume and average pore diameter of CMSs. The adsorption selectivity coefficient of $CO_2/CH_4$ achieves as high as 20.8 over CMSs obtained under the methane flow rate of $30mL\;min^{-1}$ at $800^{\circ}C$ for 70 min. The study demonstrates the prepared CMSs are a candidate adsorbent for $CO_2/CH_4$ separation.

Characteristics of flow field of nose-only exposure chamber for inhalation toxicity evaluation (흡입독성평가를 위한 비부노출 챔버의 유동흐름 특성)

  • Noh, Hakjae;Bong, Choonkeun;Bong, Hakyung;Kim, Yonggu;Cho, Myunghaing;Kim, Sanghwa;Kim, Daesung
    • Particle and aerosol research
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    • v.12 no.1
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    • pp.1-9
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    • 2016
  • In this work, we evaluated the characteristics of flow field and uniformity of the nose-only exposure chambers for the inhalation toxicity test. Computational fluid dynamics (CFD) modeling was carried out to demonstrate uniformity of the nose-only exposure chambers. Because it is very important in the inhalation toxicity experiments that test materials are distributed uniformly to each holder of the chamber. The test was done with these 3 types of chamber with different form to develop inhalation toxicity evaluation system, easy-to-operate system among exposure chamber used for evaluating inhalation toxicity of environmental chemical mixtures. Through CFD interpretation, nose-only exposure chamber was made with the selection of the optimal conditions. For its evaluation, one type of fragrance was selected and measured particle size distribution of each port. The gene becoming luminous to green fluorescence was combined with GPT-SPE, a type of tGFP vector, to be inhaled to the mouse. Based on this, luminous intensity was checked. As a result, total particle number concentration of each port had average value of $3.17{\times}10^6{\sharp}/cm^3$ and range of the highest and lowest concentration value was approximately ${\pm}4.8%$. Autopsy of lung tissues of mouse showed that it had clearly better delivery of gene compared to the control group.

A Solid-Contact Indium(III) Sensor based on a Thiosulfinate Ionophore Derived from Omeprazole

  • Abbas, Mohammad Nooredeen;Amer, Hend Samy
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1153-1159
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    • 2013
  • A novel solid-contact indium(III)-selective sensor based on bis-(1H-benzimidazole-5-methoxy-2-[(4-methoxy-3, 5-dimethyl-1-pyridinyl) 2-methyl]) thiosulfinate, known as an omeprazole dimer (OD) and a neutral ionophore, was constructed, and its performance characteristics were evaluated. The sensor was prepared by applying a membrane cocktail containing the ionophore to a graphite rod pre-coated with polyethylene dioxythiophene (PEDOT) conducting polymer as the ion-to-electron transducer. The membrane contained 3.6% OD, 2.3% oleic acid (OA) and 62% dioctyl phthalate (DOP) as the solvent mediator in PVC and produced a good potentiometric response to indium(III) ions with a Nernstian slope of 19.09 mV/decade. The constructed sensor possessed a linear concentration range from $3{\times}10^{-7}$ to $1{\times}10^{-2}$ M and a lower detection limit (LDL) of $1{\times}10^{-7}$ M indium(III) over a pH range of 4.0-7.0. It also displayed a fast response time and good selectivity for indium(III) over several other ions. The sensor can be used for longer than three months without any considerable divergence in potential. The sensor was utilized for direct and flow injection potentiometric (FIP) determination of indium(III) in alloys. The parameters that control the flow injection method were optimized. Indium(III) was quantitatively recovered, and the results agreed with those obtained using atomic absorption spectrophotometry, as confirmed by the f and t values. The sensor was also utilized as an indicator electrode for the potentiometric titration of fluoride in the presence of chloride, bromide, iodide and thiocyanate ions using indium(III) nitrate as the titrant.

Visual Demonstration of Simulated Moving Bed (Simulated Moving Bed Chromatography의 시각적 설명)

  • Oh, Nan Suk;Lee, Chong-Ho;Kim, Jin Il;Koo, Yoon-Mo
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.360-365
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    • 2005
  • SMB (simulated moving bed) is a continuous chromatographic process by shifting periodically port position. Binary of mixture, Blue dextran and Orange G, was separated by SMB. These components have unique color individually, that is, Blue dextran is blue and Orange G is orange. It is easy to understand SMB process by observing the shift of color changes in SMB. These components was not adsorbed to stationary phase and isolated by difference of size exclusion factor. Mass transfer coefficient was determined by single pulse test under several flow rate conditions. Operation condition was obtained by standing wave theory and optimized for high purities in extract and raffinate streams. Experiment was performed in open loop 4 zone (2-2-2-2) SMB. There are several advantages in open loop SMB, where extract is product for high purity. It is also easy to control flow rate and monitor experimental state during operation. Experimental, extract and raffinate history is well fitted with simulation results, however, column concentration profile is a little different from simulation results. Purities were 99.5% for extract and 98.9% for raffinate and extract and raffinate yields were obtained as 98.9% and 99.4% respectively.

An aluminum-based reflective nanolens array that enhances the effectiveness of a continuous-flow ultraviolet disinfection system for livestock water

  • Changhoon Chai;Jinhyung Park
    • Journal of Animal Science and Technology
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    • v.65 no.1
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    • pp.258-270
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    • 2023
  • Climate change has worsened droughts and floods, and created conditions more likely to lead to pathogen contamination of surface water and groundwater. Thus, there is a growing need to disinfect livestock water. Ultraviolet (UV) irradiation is widely accepted as an appropriate method for disinfecting livestock water, as it does not produce hazardous chemical compounds and kills pathogens. However, UV-based disinfection inevitably consumes electricity, so it is necessary to improve UV disinfection effectiveness. Aluminum-based reflective nanolens arrays that enhanced the effectiveness of a continuous-flow UV water disinfection system were developed using electrochemical and chemical processes, including electropolishing and two-step anodization. A continuous UV disinfection system was custom designed and the parts were produced using a three-dimensional printer. Electropolished aluminum was anodized at 40 and 80 V in 0.3 M oxalic acid, at 120 and 160 V in 1.0 M phosphoric acid, and at 200 and 240 V in 1.5 M citric acid. The average nanolens diameters (D) of the aluminum-based reflective nanolens arrays prepared using 40, 80, 120, 160, 200, and 240 V anodization were 95.44, 160.98, 226.64, 309.90, 296.32, and 339.68 nm, respectively. Simple UV reflection behind irradiated water disinfected Escherichia coli O157:H7 in water more than did the non-reflective control. UV reflection and focusing behind irradiated water using an aluminum-based reflective nanolens array disinfected E. coli O157:H7 more than did simple UV reflection. Such enhancement of the UV disinfection effectiveness was significantly effective when a nanolens array with D 226.64 nm, close to the wavelength of the irradiated UV (254 nm), was used.

Hydrodynamics control for the well field of in-situ leaching of uranium

  • Yongmei Li;Chong Zhang;Zhipeng Tang;Chunguang Li;Zhenzhong Liu;Kaixuan Tan;Longcheng Liu
    • Nuclear Engineering and Technology
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    • v.56 no.10
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    • pp.4176-4183
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    • 2024
  • In this study, the groundwater hydrodynamics of two adjacent well sites were simulated under different pumping-injection ratios. The aim is to select an optimal pumping-injection ratio that can ensure the groundwater of the two well sites don't affect each other. In addition, the sulfur isotope composition of groundwater in the two well sites were analyzed to verify the simulated results. The results show that the flow velocity at different points outside the edge drilling hole decreases exponentially with the distance between the point and the edge hole. The streamline gradually extends outside of the borehole with the increase of leaching time. It is found that the optimal pumping-injection ratio is 1.003. In this case, the maximum distance between the moving front and the injection borehole is 28.44 m after leaching for 5 years. This indicates that the groundwater flow fields of the two well sites are well controlled. The significant difference in sulfur isotopes between the two well-sites further proves that the SO42- in the acid mining zone does not affect the groundwater in the zone leached by CO2+O2.

Effect of Secondary Air on Flow and Combustion Characteristics in a Pyrolysis Melting Incinerator (열분해 용융소각로 연소실의 2차공기 주입 영향에 관한 전산해석 및 실험)

  • Jeon, Byoung-Il;Park, Sang-Uk;Shin, Dong-Hoon;Ryu, Tae-Woo;Jeon, Kum-Ha;Hwang, Jung-Ho;Lee, Jin-Ho
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.149-157
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    • 2004
  • In the present paper we studied experimentally fundamental optimization of oxygen enriched pyrolysis melting incinerator, Characteristics of this system was confirmed dealing with the gas flow and combustion properties for the inside secondary air injection. The experiment setup has a disposal rate of 30kg/hr which was measured by the inside temperature and gas. Along with above experiments, the three-dimensional computation was employed to analyse the combustion fluid dynamics and gas residence time. Equations for turbulence and heat - transmission as well as chemical reactions were solved by using common codes. The experimental combustion chamber was composed of staged combustion types structure for reducing NOx. Finally, it was verified that the control of the secondary air and air ratio of thermo stack were important. In the computational analysis, it showed reasonable agreement with the experimental results regarding the temperature and discharged gas concentration.

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