• Title/Summary/Keyword: Chemical compositions

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Case Study of the Heavy Asian Dust Observed in Late February 2015 (2015년 2월 관측된 고농도 황사 사례 연구)

  • Park, Mi Eun;Cho, Jeong Hoon;Kim, Sunyoung;Lee, Sang-Sam;Kim, Jeong Eun;Lee, Hee Choon;Cha, Joo Wan;Ryoo, Sang Boom
    • Atmosphere
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    • v.26 no.2
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    • pp.257-275
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    • 2016
  • Asian dust is a seasonal meteorological phenomenon influencing most East Asia, irregularly occurring during spring. Unusual heavy Asian dust event in winter was observed in Seoul, Korea, with up to $1,044{\mu}g\;m^{-3}$ of hourly mean $PM_{10}$, in 22~23 February 2015. Causes of such infrequent event has been studied using both ground based and spaceborne observations, as well as numerical simulations including ECMWF ERA Interim reanalysis, NOAA HYSPLIT backward trajectory analysis, and ADAM2-Haze simulation. Analysis showed that southern Mongolia and northern China, one of the areas for dust origins, had been warm and dry condition, i.e. no snow depth, soil temperature of ${\sim}0^{\circ}C$, and cumulative rainfall of 1 mm in February, along with strong surface winds higher than critical wind speed of $6{\sim}7.5m\;s^{-1}$ during 20~21 February. While Jurihe, China, ($42^{\circ}23^{\prime}56^{{\prime}{\prime}}N$, $112^{\circ}53^{\prime}58^{{\prime}{\prime}}E$) experienced $9,308{\mu}g\;m^{-3}$ of hourly mean surface $PM_{10}$ during the period, the Asian dust had affected the Korean Peninsula within 24 hours traveling through strong north-westerly wind at ~2 km altitude. KMA issued Asian dust alert from 1100 KST on 22nd to 2200 KST on 23rd since above $400{\mu}g\;m^{-3}$ of hourly mean surface $PM_{10}$. It is also important to note that, previously to arrival of the Asian dust, the Korean Peninsula was affected by anthropogenic air pollutants ($NO_3^-$, $SO_4^{2-}$, and $NH_4^+$) originated from the megacities and large industrial areas in northeast China. In addition, this study suggests using various data sets from modeling and observations as well as improving predictability of the ADAM2-Haze model itself, in order to more accurately predict the occurrence and impacts of the Asian dust over the Korean peninsula.

PHOTOCATALYTIC ANTIEUNGAL ACTIVITY AGAINST CANDIDA ALBICANS BY $TiO_2$ COATED ACRYLIC RESIN DENTURE BASE

  • Yang Ji-Yeon;Kim Hee-Jung;Chung Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.3
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    • pp.284-294
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    • 2006
  • Statement of problem. Proliferation of Candida albicans is primarily within the plaque on the fitting surface of the denture rather than on the inflamed mucosa. Consequently, the treatment of the denture is equally important as treatment of the tissue. Cleansing and disinfection should be efficiently carried-out as the organisms can penetrate into the voids of the acrylic resin and grow in them, from which they can continue to infect and reinfect bearing tissues. Purpose. The purpose of this study was to evaluate the applicability of photocatalytic reaction to eliminate Candida albicans from acrylic resin denture base, and to investigate the anti-fungal effect with various UVA illumination time. Materials and Methods. The specimens were cured by the conventional method following the manufacturer's instruction using thermal polymerized denture base resin (Vertex RS: Dentimex, Netherlands). $TiO_2$ photocatalyst sol(LT), which is able to be coated at normal temperature, was made from the Ti-alkoxide progenitor. The XRD patterns, TEM images and nitrogen absorption ability of the $TiO_2$ photocatalyst sol(LT) were compared with the commercial $TiO_2$ photocatalyst P-25. The experimental specimens were coated with the mixture of the $TiO_2$ photocatalyst sol(LT) and binder material (silane) using dip-coater, and uncoated resin plates were used as the control group. Crystallinity of $TiO_2$ of the specimen was tested by the XRD. Size, shape and chemical compositions were also analyzed using the FE-SEM/ EDS. The angle and methylene blue degradation efsciency were measured for evaluating the photocatalytic activity of the $TiO_2$ film. Finally, the antifungal activity of the specimen was tested. Candida albicans KCTC 7629(1 ml, initial concentration $10^5$ cells/ ml) were applied to the experiment and control group specimens and subsequently two UVA light source with 10W, 353 nm peak emission were illuminated to the specimens from 15cm above. The extracted $2{\mu}l$ of sample was plated on nutrient agar plate ($Bacto^{TM}$ Brain Heart Infusion; BD, USA) with 10 minute intervals for 120 minute, respectively. It was incubated for 24 hours at $37^{\circ}C$ and the colony forming units (CFUs) were then counted. Results. Compared the characteristics of LT photocatalyst with commercial P-25 photocatalyst, LT were shown higher activity than P-25. The LT coated experimental specimen surface had anatase crystal form, less than 20 nm of particle size and wide specific surface area. To evaluate the photocatalytic activity of specimens, methylene blue degradation reaction were used and about 5% of degradation rate were measured after 2 hours. The average contact angle was less than $20^{\circ}$ indicating that the LT photocatalyst had hydrophilicity. In the antifungal activity test for Candida albicans, 0% survival rate were measured within 30 minute after irradiation of UVA light. Conclusion. From the results reported above, it is concluded that the UVA-LT photocatalytic reaction have an antifungal effect on the denture surface Candida albicans, and so that could be applicable to the clinical use as a cleaning method.

BaCeO3-BaZrO3 Solid Solution (BCZY) as a High Performance Electrolyte of Protonic Ceramic Fuel Cells (PCFCs) (BaCeO3-BaZrO3 고용체(BCZY) 기반 프로톤 세라믹 연료전지(PCFC)용 고성능 전해질 개발)

  • An, Hyegsoon;Shin, Dongwook;Choi, Sung Min;Lee, Jong-Ho;Son, Ji-Won;Kim, Byung-Kook;Je, Hae June;Lee, Hae-Weon;Yoon, Kyung Joong
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.271-277
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    • 2014
  • To overcome the limitations of the solid oxide fuel cells (SOFCs) due to the high temperature operation, there has been increasing interest in proton conducting fuel cells (PCFCs) for reduction of the operating temperature to the intermediate temperature range. In present work, the perovskite $BaCe_{0.85-x}Zr_xY_{0.15}O_{3-\delta}$ (BCZY, x = 0.1, 0.3, 0.5, and 0.7) were synthesized via solid state reaction (SSR) and adopted as an electrolyte materials for PCFCs. Powder characteristics were examined using X-ray diffraction (XRD), thermogravimetric analysis (TGA) and Brunauer, Emmett and Teller (BET) surface area analysis. Single phase BCZY were obtained in all compositions, and chemical stability was improved with increasing Zr content. Anode-supported cell with $Ni-BaCe_{0.55}Z_{0.3}Y_{0.15}O_{3-\delta}$ (BCZY3) anode, BCZY3 electrolyte and BCZY3-$Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-\delta}$ (BSCF) composite cathode was fabricated and electrochemically characterized. Open-circuit voltage (OCV) was 1.05 V, and peak power density of 370 ($mW/cm^2$) was achieved at $650^{\circ}C$.

Chemical compositions and functional characteristics of Korean and imported pomegranate (Punica granatum L.) (국내산과 수입산 석류의 화학적 성분과 기능적 특성)

  • Kim, Mi Sook;Yun, Seol Hee;Na, Hwan Sik;Park, Hark Jae;Choi, Gyeong Cheol;Yang, Soo In;Lee, Ji Heon
    • Food Science and Preservation
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    • v.20 no.3
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    • pp.342-347
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    • 2013
  • In recent years, polyphenol-rich herbs, fruits and processed foods, which are made of plant origin, have attracted much attention due to their potential health benefits. Pomegranate (Punica granatum L.) is an important source of bioactive compounds and has been used to treat diseases because of its medicinal properties. This research was focused on characterizing Korea's national cultivar and a similar product from California, USA. To evaluate their bioactive compounds and pharmacological activities, their anti-oxidation and cancer inhibition properties, as well as their organic acid and free sugar contents, were investigated. The national cultivar had low total sugar and high organic acid contents, contrary to the imported product. The results showed that the peel of national cultivar had high polyphenol and ellagic acid contents compared to imported product. The free radical scavenging capacity was evaluated via 2,2-diphenyl-1-picrylhydrazyl (DPPH) and its positive correlation with the total polyphenol contents was found. The anti-cancer activity of methanol extracts revealed growth inhibition against the prostate cancer cell. These results signify that while pomegranate, national cultivar, is more sour than the imported product, its health benefits could be excellent. Also, the polyphenol compound content of the non-edible part (such as the peel and the seed) was higher than that of the juice. Thus, it is suggested that the byproduct of the juice extraction could be potentially used in other fields such as medicine or dietary agents.

Forged Product Characteristic and Cold Rolling Simulation for High-Nitrogen Stainless Steel (HNS) (TP304계 고질소 스테인레스강의 단조특성과 냉간압연 모사)

  • Lee, M.R.;Lee, J.W.;Kim, B.K.;Kim, Y.D.;Shin, J.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.310-313
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    • 2009
  • Several high nitrogen stainless steel ingots(100kg) were fabricated with changing Ni and $[N]_2$ contents by Pressurized Vacuum Induction Melting(P_VIM). After free forging process, chemical compositions, microstructure and mechanical properties were estimated. Hardness was increased with the increase of $[N]_2$ content. Furthermore, microstructure including a lot of tempering twins was observed with optical microscope. Mechanical properties were estimated as function of solution treatment temperature and cooling method(air/water) under duration time of 1 hr on sample that were fabricated with Ni content under the atmospheric $[N]_2$ pressure. At solution treatment range of $1050{\sim}1100^{\circ}C$, hardness was decreased with the increase of solution temperature and there were little discrepancy of microstructure and hardness with cooling method. Computer simulation was carried out in order to inspect pass schedule in cold rolling process. When the condition of simulation was roll speed of 2.5mpm, rolling rate $15{\sim}17%$ per pass, it was ascertained that the formation such as deformation by sticking and lamellar sliver etc. was restricted from a simulation.

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Properties of Ramyon (deep fried noodle) Changed by the Addition of Sangwhang Mushroom (Phellinus linteus) Extract (상황버섯 추출액을 첨가한 라면의 품질특성)

  • Kim, Haeng-Ran;Hong, Jin-Sun;Kim, Tae-Young;Kim, Sang-Bum;Cho, Soo-Muk;Chun, Hye-Kyung
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.928-932
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    • 2005
  • Effects of sangwhang mushroom (Phellinus linteus) extract on quality and functionality of ramyon (deep-fried noodle) were investigated by adding 17.5(v/w; II) and 35%(v/w; III) sangwhang mushroom extracts. Although little differences were generally observed in chemical compositions of ramyon samples II, III, and control, potassium contents of samples II and III were lower than control. Content of $(1{\rightarrow}3),\;(1{\rightarrow}4)\;and\;(1{\rightarrow}6)-{\beta}-D-glucan$, major functional component of sangwhang mushroom, increased in proportion to amount of extract added, 2.04 and $3.69{\mu}g/g$ in samples II and III, respectively, much higher than $0,09{\mu}g/g$ of control. Lightness (L) decreased, whereas redness (a) and yellowness (b) increased with increasing amount of extract added. Ramyons containing extract showed higher preference than control in texture analysis (hardness and tension) and sensory evaluation (taste and texture).

Influence of the homogenizing grade and meathematical treatment on the determination of ground beef components with near infrared reflectance spectroscopy (식품의 근적외선 반사분광분석법에서 균질의 정도가 흡광도에 미치는 영향 및 수학적 처리방법에 관한 연구)

  • Oh, Eun-Kyong;Grossklaus, Dieter
    • Korean Journal of Food Science and Technology
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    • v.24 no.5
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    • pp.408-413
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    • 1992
  • This study was conducted to determine the effect of the homogenizing grade of sample on absorbance of near infrared reflectance spectrophotometer with which chemical compositions of food were rapidly and effectively analyzed. By the mathematical treatment of absorbance values standard error of prediction was reduced as follows. 1. The absorbance values of various samples ground for the same periods of time were calibrated before or after treatment with first or second derivative in an attempt to accurately predict the components of samples ground for the different periods of time. The standard error of prediction for moisture content were 1.478%, 0.658% and 0.580%, respectively, those for fat content 0.949%, 0.637% and 0.527%, respectively, and those for protein content 0.514%, 0.493% and 0.394%, respectively. Calibration of absorbance values after second derivative treatment showed the highest accuracy in predicting sample components. 2. The absorbance values of various samples ground for the different periods of time were calibrated before or after treatment with first or second derivative in order to accurately predict the components of samples ground for the different periods of time. The standard error of prediction for moisture content were 1.026%, 0.589% and 0.568%, respectively, and those for protein content 0.860%, 0.557% and 0.399%, respectively. The standard error of prediction were lower in the order of calibrations before and after first and second derivative treatments. As a result, calibration of absorbance values after second derivative treatment showed higher accuracy regardless of grinding time of samples.

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Formation of Alteration Minerals in Gouges of Quaternary Faults at the Eastern Blocks of the Ulsan Fault, Southeastern Korea (울산단층 동부지역 제4기단층 비지대내 변질광물의 형성)

  • Chang, Tae-Woo;Chae, Yeon-Joon;Choo, Chang-Oh
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.205-214
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    • 2005
  • Some Quaternary faults developed in the eastern block of the Ulsan fault are Gaegok 1, Gaegok 2, Singye, Madong, Wonwonsa and Jinhyeon faults, which are characterized by thin gouge and narrow cataclasitic tones. This study was performed to emphasize the role of mineral alteration and microtexture in response to hydrothermal alteration of fault gouges during fault activity, using XRD, EPMA, BSE (backscattered electron image), and K-Ar age dating methods. Alteration minerals in fault gouges were formed in the age range of $44.3\~28.9Ma$ by hydrothermal alteration attributed to fault activity. XRD results show that fault gouges consist predominantly of clay minerals, quartz and feldspars. Clay minerals formed in the gouge zones are mainly composed of smectite with trace chlorite, illite and kaolinite. The evidence to support the hydrothermal alteration of preexisting minerals due to fault activity are easily recognized at the host rocks in contact with gouges zones. Injected gouge and calcite veins indicate that they were originated from multiple deformation by repeated fault activity. Gouge with green or greenish grey color, for example Jinhyeon fault, contains higher $Al_2O_3$ and lower MgO and CaO compared to those with reddish color. Various colors of fault gouge are intimately related to the chemical compositions of main constituent mineral as well as mineral assemblage.

Studies on Taste Compounds in Alaska Pollack Sikhae during Fermentation (전통 명태식해 숙성중의 정미성분에 관한 연구)

  • Cha, Yong-Jun;Kim, So-Jung;Kim, Eun-Jeong;Kim, Hun;cho, Woo-Jin;Yoo, Mi-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.9
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    • pp.1515-1521
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    • 2004
  • As one of the research series for the industrialization of sikhae, this study was evaluated the taste compounds present in different temperature conditions, $5^{\circ}C$, $20^{\circ}C$ and alternating temperature (stored at $5^{\circ}C$ after 10 days fermentation at $20^{\circ}C$), respectively. The changes in proximate compositions were negligible but the amounts of total sugar decreased during fermentation. The pH of sikhae products except the product fermented at $5^{\circ}C$, decreased during fermentation and was maintained at the rage of 3.8~4.4 after 10 days. The values of acidity, VBN and amino-N gradually increased with fermentation times and with increasing temperature condition in all products. Three organic acids (lactic, citric and malic acid) were disclosed as key compounds affecting the sourness in Alaska pollack sikhae. The result of taste value revealed that 6 amino acids having sweet and umami taste (aspartic acid, glutamic acid, alanine and lysine) and bitter taste (valine and methionine) as major amino acids affecting the taste of sikhae products, and increased with fermentation times. Hypoxanthine was the main component in ATP related compounds. Amino-N was comprised more over 50% of the Ex-N in sikhae products, and followed by total creatinine-N, TMAO-N and TMA-N in that order.

Physicochemical Properties of Traditional Chonggugjang Produced in Different Regions (전통청국장의 이화학적 특성)

  • Yoo, Seon-Mi;Choe, Jeong-Sook;Park, Hong-Ju;Hong, Sun-Pyo;Chang, Chang-Moon;Kim, Jin-Sook
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.377-383
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    • 1998
  • This study was undertaken to obtain the fundamental data for improving the quality of Korean traditional chonggugjang. To compare the physicochemical properties of traditional chonggugjang produced in different regions, sixty-seven chonggugjang samples collected at nine provinces were analyzed. The average moisture, protein, fat, non-fibrous carbohydrate, fiber, ash, amino nitrogen contents and pH value of collected chonggugjang samples were 55.0%, 17.6%, 3.3%, 13.3%, 4.9%, 5.8%, 0.23%, and 7.21, respectively. The average fatty acid compositions of chonggugjang were 53.8% for linoleic, 21.1% for oleic, 12.4% for palmitic, 9.0% for linolenic, and 3.7% for stearic acid. Traditional chonggugjang contained large amounts of glutamic acid, aspartic acid, and leucine, but less than 0.2% of cysteine and methionine. The average free sugar content was 3.3%, and the dominant free sugar among them were sucrose and galactose. The total average organic acid content of the samples analyzed was 883.0 mg% and citric, acetic, latic, malonic, succinic, formic, tartaric acid were also detected. The Hunter's color L, a, and b values of samples were 49.1, 7, 2, and hardness was $8.3\;kg/{\Phi}20\;mm$.

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