• Title/Summary/Keyword: Chemical compositions

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Chemical compositions of Lentinula in growth stage - A study on application plan of Lentinula I - (표고버섯의 생육시기별 성분분석 - 표고버섯의 활용방안 연구 I -)

  • 조덕봉;현규환;나광출;최지호;서재신;강성구;김용두
    • Korean Journal of Plant Resources
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    • v.15 no.2
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    • pp.128-134
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    • 2002
  • Content of crude protein in both pileus and stalk increased progresively as growth period became longer and then decreased at old stage. Contents of ash and reducing sugars followed the same trend as that of the crude protein. However, content of crude lipid decreased as growth progressed more. Seventeen kinds of amino acid were detected in Lentinula. Content of total amino acid increased as mushroom grew more, but decreased after old stage. The amino acid such as Glu, His, Gly and Ala were contained with relatively large amount in Lentinula. Content of free amino acid showed the similar trends as that of total amino acid. Contents of most of the mineral increased as growth period progressed, but K content decreased as growth period became longer. Contents of K and P were much higher than contents of other mineral. The major fatty acid contained in Lentinula were linoleicacid, palmitic acid and oleic acid. The large amount of volatile component in Lentinula was 1-octen-3-ol, so that this material was speculated to be major source of perfume. Other perfumic materials such ethyl acetate, 3-octanone, ethanol, (E)-2-octenal, 4-octen-3-one, acetaldehyde, ethyl formate were also contained in Lentinula, especially in pilous.

A Study on Modified Silicon Surface after $CHF_3/C_2F_6$ Reactive Ion Etching

  • Park, Hyung-Ho;Kwon, Kwang-Ho;Lee, Sang-Hwan;Koak, Byung-Hwa;Nahm, Sahn;Lee, Hee-Tae;Kwon, Oh-Joon;Cho, Kyoung-Ik;Kang, Young-Il
    • ETRI Journal
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    • v.16 no.1
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    • pp.45-57
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    • 1994
  • The effects of reactive ion etching (RIE) of $SiO_2$ layer in $CHF_3/C_2F_6$ on the underlying Si surface have been studied by X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometer, Rutherford backscattering spectroscopy, and high resolution transmission electron microscopy. We found that two distinguishable modified layers are formed by RIE : (i) a uniform residue surface layer of 4 nm thickness composed entirely of carbon, fluorine, oxygen, and hydrogen with 9 different kinds of chemical bonds and (ii) a contaminated silicon layer of about 50 nm thickness with carbon and fluorine atoms without any observable crystalline defects. To search the removal condition of the silicon surface residue, we monitored the changes of surface compositions for the etched silicon after various post treatments as rapid thermal anneal, $O_2$, $NF_3$, $SF_6$, and $Cl_2$ plasma treatments. XPS analysis revealed that $NF_3$ treatment is most effective. With 10 seconds exposure to $NF_3$ plasma, the fluorocarbon residue film decomposes. The remained fluorine completely disappears after the following wet cleaning.

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Antifungal Activity of Lagenaria breviflora Fruit Extracts Against Wood Rotting Fungi on Vitex doniana Wood

  • Adedeji, Gabriel Adetoye;Eguakun, Funmilayo Sarah;Elufloye, Taiwo Olayemi;Uriel, Tamunobubeleye
    • Journal of Forest and Environmental Science
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    • v.33 no.4
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    • pp.322-329
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    • 2017
  • As a result of contemporary environmental concerns, a number of studies from plants' tissues as one of the alternatives to conventional chemicals are increasingly investigated. In tandem with these trends, Lagenaria breviflora (LB) fruit, reputed as antiviral and depilatory agents in the Yoruba folkloric medicine was examined on Vitex doniana wood to ascertain its antifungal activity. Fungicides of 25%, 50%, 75%, and 100% LB fruits formulations (concentrations) were developed through simple one-step mechanical-forming process, including control. In this study, the yield, the chemical compositions, the absorption capacity of the fungicides and wood weight losses (WWL) analysis were evaluated to investigate the antifungal activity of LB fruit on wood. The fruit extract yielded 35.4% of fresh juice weight. LB fruits contained total: alkaloids ($8.78{\pm}0.21mg/mL$), flavonoids ($2.01{\pm}0.02mg/mL$), phenol ($7.42{\pm}0.09mg/mL$), saponins ($11.00{\pm}0.10mg/mL$) and tannins ($5.47{\pm}0.05mg/mL$) contents. All the formulations provided effective protection against the tested wood fungi compared to control. Interestingly, the antifungal activity of 50% and 25% formulations of 6.8% WWL and 9.9% WWL satisfied the excellent fungal resistance class description against white rot fungus (Ganoderma lucidum) and brown rot fungus (Fibroporia vaillantii), respectively according to ASTM D 2017. These results thus, support LB fruit as a strong potential source of natural antifungals for industrial wood production.

Relation between Arc Phenomena and Spattering Ratio of Flux Cored Arc Welding with 100% $CO_2$ Shielding gas (플럭스 코어드 아크 용접의 아크현상과 스패터 발생량과의 관계)

  • S.W. Kang;D.S. Um;E.S. Oh;D.S. You
    • Journal of the Society of Naval Architects of Korea
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    • v.35 no.4
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    • pp.65-75
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    • 1998
  • The $CO_2$ welding with 100% $CO_2$ gas is commonly used because of its cost and efficiency. Arc phenomena and spattering ratio of the $CO_2$ welding are influenced by various factors such as chemical compositions of welding wire, shielding gas, welding condition and welding power source etc.. Spattering ratio is predominantly influenced by the welding condition which determines a droplet transfer rode. In this study, arc phenomena and spattering ratio are investigated by using two type of FCW(titania type, semi-metal type). Then, the welding quality and optimum welding condition can be selected. From this study, the following results ware obtained; 1) In low current range(140A), FCW up to welding voltage(22V) resulted in a typical short circuit transfer, increase of spattering ratio and growth of spatter diameter. 2) In high current range(320A), the arc stability in titania FCW of a typical globular transfer is better than that of semi-metal FCW.

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Characteristics of Kimchi Added with Anchovy Sauce from Heat and Non-heat Treatments (가열 및 비가열 처리 액젓을 첨가하여 제조한 김치의 특성 비교)

  • Kang, Hyun-Woo
    • Culinary science and hospitality research
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    • v.19 no.5
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    • pp.49-58
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    • 2013
  • The principal objective of this study was to understand the quality characteristics of kimchi added with anchovy sauce from heat and non-heat treatments. The kimchi made through such treatments contained 1.1% or 1.3% of salinity and 4.05 or 4.16 of pH. Generally, the kimchi with anchovy sauce from non-heat treatment contained higher Ca and Fe values than the one with anchovy sauce from heat treatment did. However, P, Zn, Na values were higher in the kimchi with anchovy sauce from heat treatment. Also, measurement of total-microbial, Lactobacillus sp. and Leuconostoc sp. from kimchi after filtration of anchovy sauce from heat treatment showed $5.2{\times}10^6$, $1.3{\times}10^8$, and $2.1{\times}10^8$ CFU/mL, respectively. In addition, kimchi after filtration of anchovy sauce from non-heat treatment showed $8.3{\times}10^6$, $2.5{\times}10^7$, and $1.6{\times}10^7$ CFU/mL, respectively. The present results help understand chemical compositions of kimchi and encourage its application for the food industry and cooking.

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Sonocatalytic Degradation of Rhodamine B in the Presence of TiO2 Nanoparticles by Loading WO3

  • Meng, Ze-Da;Sarkar, Sourav;Zhu, Lei;Ullah, Kefayat;Ye, Shu;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.6-12
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    • 2014
  • In the present work, $WO_3$ and $WO_3-TiO_2$ were prepared by the chemical deposition method. Structural variations, surface state and elemental compositions were investigated for preparation of $WO_3-TiO_2$ sonocatalyst. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and transmission electron microscopy (TEM) were employed for characterization of these new photocatalysts. A rhodamine B (Rh.B) solution under ultrasonic irradiation was used to determine the catalytic activity. Excellent catalytic degradation of an Rh.B solution was observed using the $WO_3-TiO_2$ composites under ultrasonic irradiation. Sonocatalytic degradation is a novel technology of treating wastewater. During the ultrasonic treatment of aqueous solutions sonoluminescence, cavitaties and "hot spot" occurred, leading to the dissociation of water molecules. In case of a $WO_3$ coupled system, a semiconductor coupled with two components has a beneficial role in improving charge separation and enhancing $TiO_2$ response to ultrasonic radiations. In case of the addition of $WO_3$ as new matter, the excited electrons from the $WO_3$ particles are quickly transferred to $TiO_2$ particle, as the conduction band of $WO_3$ is 0.74 eV which is -0.5 eV more than that of $TiO_2$. This transfer of charge should enhance the oxidation of the adsorbed organic substrate. The result shows that the photocatalytic performance of $TiO_2$ nanoparticles was improved by loading $WO_3$.

Study on the Compositional Change of Free Sugars and Glucosinolates of Rapeseed during Germination (발아에 의한 유채의 Glucosinolate 및 유리당 함량의 변화에 관한 연구)

  • Kim, In-Sook;Kwon, Tae-Bong;Oh, Sung-Ki
    • Korean Journal of Food Science and Technology
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    • v.20 no.2
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    • pp.194-199
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    • 1988
  • The objective of this study was to investigate the technical feasibility of producing toxicant-free rapeseed by germination. To this end, rapeseed(Brassica napus L.)was germinated at $25^{\circ}C$ for 120 hours, and the chemical compositions-glucosinolates and free sugers-were determinated in every 24 hours during germination. The amount of glucosinolates in rapeseed measured by UV method was very close to that measured by GLC method. The glucosinolates were considerably abundant in rapeseed before germination, and the total content was found to be 13.6 mg/g. Rapeseed showed the lowest glucosinolate content in 72 hours during germination, and it gradually increased glucosinolate content from 96 hours. Free suger content in rapeseed before germination was as follows : 3.03 mg/g of fructose, 2.97 mg/g of glucose and 5.63 mg/g of sucrose. Raffinose and stachyose were not detected, and in general free sugars were gradually decreased during germination. However, sucrose was increased in the early period of gremination and decreased in the later period.

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Effect of Grain Size on Ductile-Brittle Transition Behavior of Austenitic Fe-18Cr-10Mn-N-C Alloys (오스테나이트계 Fe-18Cr-10Mn-N-C 합금의 연성-취성 천이 거동에 미치는 결정립 크기의 영향)

  • Lee, Sang-In;Lee, Seung-Yong;Nam, Seung Hoon;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.25 no.10
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    • pp.559-565
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    • 2015
  • The ductile-brittle transition behavior of two austenitic Fe-18Cr-10Mn-N-C alloys with different grain sizes was investigated in this study. The alloys exhibited a ductile-brittle transition behavior because of an unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy specimens with a smaller grain size had a higher yield and tensile strengths than those with a larger grain size due to grain refinement strengthening. However, a decrease in the grain size deteriorated the low-temperature toughness by increasing the ductile-brittle transition temperature because nitrogen or carbon could enhance the effectiveness of the grain boundaries to overcome the thermal energy. It could be explained by the temperature dependence of the yield stress based on low-temperature tensile tests. In order to improve both the strength and toughness of austenitic Fe-Cr-Mn-N-C alloys with different chemical compositions and grain sizes, more systematic studies are required to understand the effect of the grain size on the mechanical properties in relation to the temperature sensitivity of yield and fracture stresses.

The Process Simulation of Entrained Flow Coal Gasification in Dynamic State for 300MW IGCC (300MW급 IGCC를 위한 건식 분류층 석탄 가스화 공정의 동적 상태 모사)

  • Kim, Mi-Yeong;Joo, Yong-Jin;Choi, In-Kyu;Lee, Joong-Won
    • Journal of Hydrogen and New Energy
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    • v.21 no.5
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    • pp.460-469
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    • 2010
  • To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.

Manufacturing of Sintered Lightweight Aggregate using Paper Mill Sludge Ash (제지 슬러지 소각재를 이용한 소성 경량골재의 제조)

  • 문경주;김재신;소양섭
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.114-122
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    • 2001
  • The purpose of this study was to manufacture sintered lightweight aggregate using paper sludge ash and to evaluate the qualities of the aggregate according to various mix proportions, conditions of pelletization and sintering. The paper sludge ash alone, due to its mineral and chemical compositions could not gain suitable expansion and strength. Hence, it was essential to add mineral additives such as clay, fly ash etc. The optimum muting ratio range determined in this study is as follows , paper sludge ash 30∼50 %, clay 30∼50 %, fay ash 0∼40 %, Paper sludge 0∼10% and hematite 2∼3 %(for manufacturing lightweight aggregate both for non-structural and structural concrete). It was possible to manufacture various lightweight aggregate whose dry specific gravity ranged about from 0.6 to 1.4 by using this optimum mixing ratio. From the test results of the qualities of aggregate, it showed that the 10% granules crushing value test and water absorption percentage ranged about 5∼10 ton and 10∼20%. Thus, it was favorably comparable to those of the imported aggregate. The manufactured lightweight aggregate could be used for structural concrete and non-structural concrete.