• Title/Summary/Keyword: Chemical and mechanical stability

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Effect of Fillers on the Mechanical and Thermal Properties of Glass/Novolac Composites (충전재의 종류에 따른 유리/노볼락 복합재료의 기계적 및 열적 성질 연구)

  • Lee, Soo;Lee, In-Kyu;Park, Sang-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.15-22
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    • 2008
  • The effects of fillers on the mechanical and thermal properties of glass/novolac composites have been studied. The matrix polymer and reinforcement were novolac type phenolic resin and milled glass fiber, respectively. Three different fillers, such as calcium carbonate, aluminum oxide, and wood powder were used for glass fiber reinforced plastic(GFRP) manufacture. Gravity, moisture content, tensile and flexural strength were measured to analyze the mechanical properties of GFRP and the final composites was burned in the electronic furnace at $1000^{\circ}C$ to confirm thermal properties GFRP containing aluminium oxide shows the highest thermal stability with 32% of weight loss at $1000^{\circ}C$ for one hour. GFRP containing calcium carbonate shows the maximum flexural strength (146 MPa), but that containing wood powder dose the highest tensile strength (65 MPa). Conclusively, we found that the characteristics of final composites strongly depend on several factors, such as types of materials, contents and chemical affinity of fillers. Therefore, it is very important to set up the combination of fillers for GFRP manufacturing to improve both mechanical and thermal properties at the same time.

Planarizaiton of Cu Interconnect using ECMP Process (전기화학 기계적 연마를 이용한 Cu 배선의 평탄화)

  • Jeong, Suk-Hoon;Seo, Heon-Deok;Park, Boum-Young;Park, Jae-Hong;Jeong, Hae-Do
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.3
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    • pp.213-217
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    • 2007
  • Copper has been used as an interconnect material in the fabrication of semiconductor devices, because of its higher electrical conductivity and superior electro-migration resistance. Chemical mechanical polishing(CMP) technique is required to planarize the overburden Cu film in an interconnect process. Various problems such as dishing, erosion, and delamination are caused by the high pressure and chemical effects in the Cu CMP process. But these problems have to be solved for the fabrication of the next generation semiconductor devices. Therefore, new process which is electro-chemical mechanical polishing(ECMP) or electro-chemical mechanical planarization was introduced to solve the technical difficulties and problems in CMP process. In the ECMP process, Cu ions are dissolved electrochemically by the applying an anodic potential energy on the Cu surface in an electrolyte. And then, Cu complex layer are mechanically removed by the mechanical effects between pad and abrasive. This paper focuses on the manufacturing of ECMP system and its process. ECMP equipment which has better performance and stability was manufactured for the planarization process.

Ionic Passivation and Oxidation Dynamics for Enhanced Viability of Copper-Based On-Skin Bioelectrodes in Biological Environments

  • Jungho Lee;Gaeun Yun;Juhyeong Jeon;Phuong Thao Le;Seung Whan Kim;Geunbae Lim
    • Journal of Sensor Science and Technology
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    • v.32 no.6
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    • pp.352-356
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    • 2023
  • The integration of bioelectronic devices with the skin is a promising strategy for personalized healthcare monitoring and diagnostics. On-skin bioelectrodes hold great potential for the real-time tracking of physiological parameters. However, persistent challenges of stability and reliability have instigated exploration beyond conventional noble metals. This study focuses on the ionic passivation and oxidation dynamics of copper-based on-skin thin-film bioelectrodes. Through parylene chemical vapor deposition, we harness a controlled thin film of parylene insulation to counter the intrinsic susceptibility of copper to oxidation in the ionic environment. The results represent the relationship among the parylene insulation thickness, copper oxidation, and electrode impedance over temporal intervals. Comparative analyses indicate that the short-term stability of the copper electrode is comparable to that of the gold electrode. Therefore, we propose a cost-effective strategy for fabricating copper-based on-skin bioelectrodes by introducing enhanced ionic stability within a discernible operational timeframe. This study enriches our understanding of on-skin bioelectronics and affordable material choices for practical use in wearable healthcare devices.

Evaluation of Chemical Resistance and Cleaning Efficiency Characteristics of Multi bore PSf Hollow Fiber Membrane (Multi-bore PSf 중공사막의 내화학성 및 세척 효율 특성평가)

  • Im, Kwang Seop;Kim, Tae Han;Jang, Jae Young;Nam, Sang Yong
    • Membrane Journal
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    • v.30 no.2
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    • pp.138-148
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    • 2020
  • The purpose of this study was to identify the cleaning efficiency of fouled multi-bore hollow fiber membranes after purification of contaminated water. The PSf (polysulfone) based hollow fiber membrane manufactured by Pure & B Tech Co., Ltd. Was used in this study. The antifouling characteristics during the water treatment were studied using bovine serum albumin (BSA) as a model compound and the chemical resistance was evaluated after long-term impregnation in sodium hypochlorite (NaOCl) solution and Citric acid to understand the long term stability of the membranes. Water permeability and mechanical strength of the membranes after prolonged chemical exposure was measured to observe the change in mechanical stability and long term performance of the membrane. moreover, the recovery efficiency was also evaluated after chemical enhanced backwashing of a membrane contaminated with bovine serum albumin. The PSf hollow fiber membrane exhibited excellent chemical resistance, and it was confirmed that the efficiency of sodium hypochlorite was high as a result of chemical enhanced backwashing.

On the Method for Hot-Fire Modeling of High-Frequency Combustion Instability in Liquid Rocket Engines

  • Sohn, Chae-Hoon;Seol, Woo-Seok;Valery P. Pikalov
    • Journal of Mechanical Science and Technology
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    • v.18 no.6
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    • pp.1010-1018
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    • 2004
  • This study presents the methodological aspects of combustion instability modeling and provides the numerical results of the model (sub-scale) combustion chamber, regarding geometrical dimensions and operating conditions, which are for determining the combustion stability boundaries using the model chamber. An approach to determine the stability limits and acoustic characteristics of injectors is described intensively. Procedures for extrapolation of the model operating parameters to the actual conditions are presented, which allow the hot-fire test data to be presented by parameters of the combustion chamber pressure and mixture (oxidizer/fuel) ratio, which are customary for designers. Tests with the model chamber, based on the suggested scaling method, are far more cost-effective than with the actual (full-scale) chamber and useful for injector screening at the initial stage of the combustor development in a viewpoint of combustion instabilities.

Planarization of Cu intereonnect using ECMP process (전기화학 기계적 연마를 이용한 Cu 배선의 평탄화)

  • Jeong, Suk-Hoon;Seo, Heon-Deok;Park, Boum-Young;Park, Jae-Hong;Lee, Ho-Jun;Oh, Ji-Heon;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.79-80
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    • 2007
  • Copper has been used as an interconnect material in the fabrication of semiconductor devices, because of its higher electrical conductivity and superior electro-migration resistance. Chemical mechanical polishing (CMP) technique is required to planarize the overburden Cu film in an interconnect process. Various problems such as dishing, erosion, and delamination are caused by the high pressure and chemical effects in the Cu CMP process. But these problems have to be solved for the fabrication of the next generation semiconductor devices. Therefore, new process which is electro-chemical mechanical planarization/polishing (ECMP) or electro-chemical mechanical planarization was introduced to solve the. technical difficulties and problems in CMP process. In the ECMP process, Cu ions are dissolved electrochemically by the applying an anodic potential energy on the Cu surface in an electrolyte. And then, Cu complex layer are mechanically removed by the mechanical effects between pad and abrasive. This paper focuses on the manufacturing of ECMP system and its process. ECMP equipment which has better performance and stability was manufactured for the planarization process.

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Experimental Study on Physical Characteristics along Chemical Compositions of MR Fluid (MR 유체의 화학적 조성에 따른 물리특성 실험연구)

  • Baek, Dae-Sung;Lee, Seok-Hyun;Kim, Ki-Young;Kwon, Young-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.10
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    • pp.4747-4752
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    • 2013
  • Physical characteristics of a magneto-rheological(MR) fluid can be influenced by a magnetic field. MR fluid is a suspension of micrometer-sized magnetic particles in a base liquid such as oil. Therefore, the key issue is dispersion stability because density of micrometer-sized magnetic particles are different from that of oil. In the present study, dispersion stability and physical characteristics along chemical compositions of MR fluid are investigated. 216 kinds of MR fluids are made by using magnetic powder(#2), surfactant(#2), base oil(#2), functional additive(#3), density(#3) and viscosity(#3). From experimental results, SEM photograph, magnetic flux density, supernatant and sediment of 216 kinds of MR fluids are obtained.

Combustion Stability Characteristics of the Model Chamber with Various Configurations of Triplet Impinging-Jet Injectors

  • Sohn Chae-Hoon;Seol Woo-Seok;Shibanov Alexander A.
    • Journal of Mechanical Science and Technology
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    • v.20 no.6
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    • pp.874-881
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    • 2006
  • Combustion stability characteristics in actual full-scale combustion chamber of a rocket engine are investigated by experimental tests with the model (sub-scale) chamber. The present hot-fire tests adopt the combustion chamber with three configurations of triplet impinging-jet injectors such as F-O-O-F, F-O-F, and O-F-O configurations. Combustion stability bound-aries are obtained and presented by the parameters of combustion-chamber pressure and mixture (oxidizer/fuel) ratio. From the experimental tests, two instability regions are observed and the pressure oscillations have the similar patterns irrespective of injector configuration. But, the O-F-O injector configuration shows broader upper-instability region than the other configurations. To verify the instability mechanism for the lower and upper instability regions, air-purge acoustic test is conducted and the photograph or the flames is taken. As a result, it is found that the pressure oscillations in the two regions can be characterized by the first impinging point of hydraulic jets and pre-blowout combustion, respectively.

A Numerical Study on Combustion-Stability Rating of Impinging-Jet Injector Using Air-Injection Technique (공기분사 기법을 이용한 충돌형 제트 분사기의 연소 안정성 평가에 관한 수치적 연구)

  • Sohn, Chae-Hoon;Park, I-Sun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.11 s.254
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    • pp.1093-1100
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    • 2006
  • Combustion stability rating of jet injector is conducted numerically using air-injection technique in a model chamber, where air is supplied to oxidizer and fuel manifolds of the model five-element injector head. A sample F(fuel)-O(oxidizer)-O-F impinging-jet injector is adopted. In this technique, we can simulate mixing process of streams flowing through oxidizer and fuel orifices under cold-flow condition without chemical reaction. The model chamber was designed based on the methodologies proposed in the previous work regarding geometrical dimensions and operating conditions. From numerical data, unstable regions can be identified and they are compared with those from air-injection acoustic and hot-fire tests. The present stability boundaries are in a good agreement with experimental results. The proposed numerical method can be applied cost-effectively to stability rating of jet injectors when mixing of fuel and oxidizer jets is the dominant process in instability triggering.

Long Term Stability of Slopes Excavated in Weathered Granite Rock Masses Subjected to Extreme Climatic Conditions (극한 기후 조건하에서 풍화된 화강암반 절취사면에 대한 장기적 안정성 연구)

  • Yang, Kwang-Yong;Park, Yeon-Jun;You, Kwang-Ho;Woo, Ik;Park, Chan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.655-662
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    • 2003
  • Slope stability is an important issue ill civil engineering works or in open pit mines where both economy and efficiency is required. These are the long-term stability problems which depend on the change of physical properties under a certain weather condition. These can also result in progress of weathering which can change mechanical or hydro-geological properties of rock mass considerably. In this study, weathering in nature was simulated by freeze-thaw test and Soxhlet test which represent mechanical and chemical weathering respectively. Measured were elastic wave velocities, absorption rate, volume change. Uniaxial compression strengths before and after the weathering tests were also measured. The change in weight and volume of the specimens were not clearly related to the weathering process, but P, S wave velocities were clearly decreased as weathering progresses. For some class of rocks, P-wave velocity was increased probably because of the saturation due to improved connectivity of the pre-existing pores. Based on the test results, stability of the slopes were analyzed using FLAC$\^$2D/. Due to the reduced strength parameters, the factors of safety were decreased for the selected sites.

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