• 제목/요약/키워드: Chemical accidents

검색결과 482건 처리시간 0.024초

화학실험 교과목에서 ARCS 동기모형을 적용한 교수자료 개발 (Development of the Teaching Materials Based on the ARCS Motivation Model in Chemistry Experiments Subject)

  • 박선희;김형수;윤기종
    • 공학교육연구
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    • 제13권3호
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    • pp.87-95
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    • 2010
  • 본 연구의 목적은 화학실험 교과목에서 ARCS 동기모형을 적용한 교수자료를 개발하고 이를 적용하는 것이다. 이를 위해 요구분석(교수, 학생, 실험조교), 교과내용분석, ARCS 이론을 적용한 교수자료 설계, 개발, 적용, 효과분석을 하였다. 본 연구에서 개발된 교수자료를 적용한 결과, 실험에 대한 이해, 흥미, 동기부여, 집중정도, 실험과 이론을 연결하여 이해하는 능력이 증가하였고 실험시간은 단축되었으며 실험의 오차 범위가 줄어들었다. 그리고 안전사고 예방, 학생들이 실험에 대한 막연함 등을 해결하는데 효과가 있는 것으로 나타났다.

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유기 다공성 소재의 흡유 효과 (Oil Absorption Effects of Organic Porous Materials)

  • 강영구;한상범
    • 한국안전학회지
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    • 제21권1호
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    • pp.86-91
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    • 2006
  • Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

할로겐화합물청정소화약제 안전기준 설정에 관한 연구 (Study on the Safety Standard Establishment of Halogen Clean Extinguishing Agents)

  • 조중래;이종호
    • 한국화재소방학회논문지
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    • 제32권5호
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    • pp.22-33
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    • 2018
  • 화재에 대한 우수한 소화력, 적응성 및 잔류물이 남지 않는 등의 장점으로 최근 할로겐화합물청정소화약제의 사용량이 증가하고 있다. 하지만 유해성에 대한 검증과 안전기준이 설정되지 않은 상태로 사용되어 사망사고 등의 재해가 다발하고 있는 실정이다. 본 논문은 문헌 및 실험연구를 통해 할로겐화합물청정소화약제의 안전한 사용을 위한 법적인 노출기준과 가스 모니터링과 연계된 정량적 환기시스템, 유해성 주지 및 적정 보호구 선정을 포함한 안전기준 설정을 제안하고자 하였다.

The Research and Application of Protective Coating for PCCP

  • Lin, Zhu;Xu, Cuizhu;Zhang, Li;Fan, Yunpeng;Zhang, Qibin
    • Corrosion Science and Technology
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    • 제7권5호
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    • pp.265-268
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    • 2008
  • Prestressed Concrete Cylinder Pipe(PCCP) had became one of the dominating kinds of pipes substituting for steel pipes because of its unique feature (high intensity, high pressure and high leakproofness). PCCP was produced firstly by Bonna company in France. By the end of 20th century, there were over 19000 km of this product installed in America. PCCP was introduced from Ameron company by Shandong Eletric Power Pipeline Engineering Company in 1988. As the statistical data in 2002, 700 km of PCCP had been applied in China, and the application trended towards rapid increase.Since prestressing wire would be corroded in environment, Several accidents due to the breakdown of pipe had happened. Consequently the external wall of pipe should be covered with protective coatings. There was a lack of technical study in corrosion and control of PCCP, because PCCP had been applied for a short time in China. in order to ensure the service life of PCCP, we have developed a kind of protective coating for concrete pipe, which had high intensity and anti-corrosive property with convenient applicability. The physical and chemical properties, painting technology and field application of this coating was introduced in the paper, at the same time, the future of external protective coating for PCCP was looked into.

GOTHIC-3D APPLICABILITY TO HYDROGEN COMBUSTION ANALYSIS

  • LEE JUNG-JAE;LEE JIN-YONG;PARK GOON-CHERL;LEE BYUNG-CHUL;YOO HOJONG;KIM HYEONG-TAEK;OH SEUNG-JONG
    • Nuclear Engineering and Technology
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    • 제37권3호
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    • pp.265-272
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    • 2005
  • Severe accidents in nuclear power plants can cause hydrogen-generating chemical reactions, which create the danger of hydrogen combustion and thus threaten containment integrity. For containment analyses, a three-dimensional mechanistic code, GOTHIC-3D has been applied near source compartments to predict whether or not highly reactive gas mixtures can form during an accident with the hydrogen mitigation system working. To assess the code applicability to hydrogen combustion analysis, this paper presents the numerical calculation results of GOTHIC-3D for various hydrogen combustion experiments, including FLAME, LSVCTF, and SNU-2D. In this study, a technical base for the modeling oflarge- and small-scale facilities was introduced through sensitivity studies on cell size and bum modeling parameters. Use of a turbulent bum option of the eddy dissipation concept enabled scale-free applications. Lowering the bum parameter values for the flame thickness and the bum temperature limit resulted in a larger flame velocity. When applied to hydrogen combustion analysis, this study revealed that the GOTHIC-3D code is generally able to predict the combustion phenomena with its default bum modeling parameters for large-scale facilities. However, the code needs further modifications of its bum modeling parameters to be applied to either small-scale facilities or extremely fast transients.

An Application of Affective-Cognitive Ambivalence Theory in Environmental Risk Attitude: The Case Study of Marion County, Ohio in the U.S.

  • Lee, Jae-Young;Lee, Hyon-Yong;Fortner, Rosanne W.
    • 한국지구과학회지
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    • 제28권5호
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    • pp.635-642
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    • 2007
  • Using data from 132 telephone interviewees, we examined the role of affective-cognitive ambivalence in forming overall attitude and behavior toward toxic chemical and radioactive waste issues in Marion, Ohio in the U.S. In order to compare attitudinal preference, participants were divided into four A-C groups: action-group (Affective+/Cognitive+), detached-group (A-/C+), concerned-group (A+/C-), and inaction-group (A-/C-). Affective and cognitive components interacted, producing redundant influences on overall attitudes and judgments as frequently observed and postulated in previous attitude studies. The results showed that the action-group who were feeling unsafe and believed that environmental accidents had happened or are happening in Marion were less willing to move to the area than other three groups who were feeling safe and/or doubted reports of contamination and its relation with leukemia. Affective and cognitive components were found to have redundant influences on overall attitude. It was also observed that affective-cognitive ambivalence theory has a great potential for explaining the mechanism by which people form attitudes, especially when people have moderate or positive feelings (e.g. sympathy or eagerness for resources) toward the objects and/or when uncertainty is a major feature of environmental issue under consideration (e.g. global climate change).

SAFETY STUDIES ON HYDROGEN PRODUCTION SYSTEM WITH A HIGH TEMPERATURE GAS-COOLED REACTOR

  • TAKEDA TETSUAKI
    • Nuclear Engineering and Technology
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    • 제37권6호
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    • pp.537-556
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    • 2005
  • A primary-pipe rupture accident is one of the design-basis accidents of a High-Temperature Gas-cooled Reactor (HTGR). When the primary-pipe rupture accident occurs, air is expected to enter the reactor core from the breach and oxidize in-core graphite structures. This paper describes an experiment and analysis of the air ingress phenomena and the method fur the prevention of air ingress into the reactor during the primary-pipe rupture accident. The numerical results are in good agreement with the experimental ones regarding the density of the gas mixture, the concentration of each gas species produced by the graphite oxidation reaction and the onset time of the natural circulation of air. A hydrogen production system connected to the High-Temperature Engineering Test Reactor (HTTR) Is being designed to be able to produce hydrogen by themo-chemical iodine-Sulfur process, using a nuclear heat of 10 MW supplied by the HTTR. The HTTR hydrogen production system is first connected to a nuclear reactor in the world; hence a permeation test of hydrogen isotopes through heat exchanger is carried out to obtain detailed data for safety review and development of analytical codes. This paper also describes an overview of the hydrogen permeation test and permeability of hydrogen and deuterium of Hastelloy XR.

가연성물질의 폭발한계에 관한 연구 - 용액열역학 및 MRSM 모델에 의한 3성분계 폭발한계 - (A Study on Explosive Limits of Flammable Materials - Explosive Limits of Ternary System by Means of Solution Thermodynamics and MRSM Model -)

  • 하동명
    • 한국안전학회지
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    • 제20권3호
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    • pp.91-97
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    • 2005
  • The research on the explosive limits is one of fundamental fields of combustion process, and information on the explosive limits of mixture of fuel and oxidant, with or without additives, is very important for the prevention in industrial fire and explosion accidents. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Batten, Le Chatelier and MRSM(modified response surface methodology) model. In this study, the reference values of lower explosive limits(LEL) of the ethanol+toluene+ethylacetate system were compared with the calculated values by using the solution thermodynamics and the MRSM model, respectively. The values calculated by the proposed equations were a good agreement with literature data within a few percent. By means of this methodology, it is possible to evaluate reliability of experimental data of the lower explosive limits of the flammable mixtures. Also, from given results, it is possible to predict explosive limits of the other flammable liquid mixtures used in the chemical process by the use of the proposed equations.

현대의 고도화, 자동화된 시스템이 파생한 휴먼에러에 관한 이론적 고찰을 통한 리스크 대응전략 설정 (A Study on Countermeasure Strategy on Risk of Human Errors driven by Advanced and Automated Systems Through Consideration of Related Theories)

  • 신인재
    • 한국안전학회지
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    • 제29권1호
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    • pp.86-92
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    • 2014
  • This paper provides an integrated view on human and system interaction in advanced and automated systems, which adopting computerized multi-functional artifacts and complicated organizations, such as nuclear power plants, chemical plants, steel and semi-conduct manufacturing system. As current systems have advanced with various automated equipments but human operators from various organizations are involved in the systems, system safety still remains uncertain. Especially, a human operator plays an important role at the time of critical conditions that can lead to catastrophic accidents. The knowledge on human error helps a risk manager as well as a designer to create and control a more credible system. Several human error theories were reviewed and adopted for forming the integrated perspective: gulf of execution and evaluation; risk homeostasis; the ironies of automation; trust in automation; design affordance; distributed cognition; situation awareness; and plan delegation theory. The integrated perspective embraces human error theories within three levels of human-system interactions such as affordance level, psychological logic level and trust level. This paper argued that risk management process should dealt with human errors by providing (1) reasoning improvement; (2) support to situation awareness of operators; and (3) continuous monitoring on harmonization of human system interaction. This approach may help people to understand risk of human-system interaction failure characteristics and their countermeasures.

기후 변화에 따른 자기 애자의 시멘트 경도 변화 (Hardness Profiles of Porcelain Insulators by Climate Changes)

  • 이주현;김홍식;김준동;최인혁
    • 한국전기전자재료학회논문지
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    • 제31권1호
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    • pp.24-28
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    • 2018
  • Insulators used in overhead transmission lines are continuously exposed to a number of mechanical and electrical stresses owing to external environmental factors, resulting in corrosion, reduction in durability, and deterioration. Widely used porcelain insulators are fabricated with cement and porcelain and are especially common in Korea. Changes in the hardness and chemical reactivity of the cement increase the leakage and fault currents and increase the possibility of flashover due to insulation breakdown. Therefore, it is important to evaluate the durability and defects of porcelain insulators. Studies on the reliability of various evaluation methods are needed to prevent accidents by accurately determining the replacement timing and potential defects in porcelain insulators. In this study, the hardness of the cement part of the porcelain insulator was measured using the Vickers hardness test and its composition was analyzed by energy dispersive spectroscopy and X-ray diffraction analysis. The performance of the insulators was compared in two different regions with varying climatic conditions. This study presents an evaluation method of the defects in porcelain insulators by measuring humidity, which can also be used to assess the reliability of the insulators.