• Title/Summary/Keyword: Chemical Storage System

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Development of Fuel Cell Power System for Unmanned Aerial Vehicle (무인 항공기용 연료 전지 동력 시스템 개발)

  • Kim, Tae-Gyu;Shim, Hyun-Chul;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.87-90
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    • 2007
  • Fuel cell power system was developed for high-endurance unmanned aerial vehicle (UAV). Liquid chemical hydride was selected as a fuel due to its high energy density. Liquid storage of the fuel is an ideal alternative solution of the existing compressed hydrogen storage. The fueling system that extracts hydrogen from chemical hydride consists of catalytic reactor, micro-pump, fuel cartridge, separator, and controller. The fuel cell power system including the fueling system and the fuel cell that generates electricity was integrated into a proposed UAV. The performance verification of the fuel cell power system was performed to use as a power plant of the UAV.

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CO Tolerance Improvement of MEA Using Metal Thin Film by Sputtering Method in PEM Fuel Cell (스퍼터링 공정으로 제조된 금속박막을 이용한 고분자전해질 연료전지 막-전극접합체의 일산화탄소에 대한 내구성 연구)

  • Cho, Yong-Hun;Yoo, Sung-Jong;Cho, Yoon-Hwan;Park, Hyun-Seo;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.279-282
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    • 2007
  • When reformer for fuel cell is used, CO in hydrogen gas leads to a seriously decreased membrane electrode assembly (MEA) performance by catalyst poisoning. The effect of CO on performance of modified MEA by sputtering method is studied in this paper. The experimental results show that sputtered Pt and Ru thin film improve a single cell performance of MEA and sputtered metal thin film has a CO tolerance. The air injection process on anode show improved CO tolerance test result. Moreover, Pt, Ru and PtRu thin film by sputtering had influence on the CO tolerance with air injection process.

Simulation Analysis for Improving the Logistics Flow in an Chemical Storage System (석유화학 창고 시스템 내 물류 흐름 개선을 위한 시뮬레이션 분석)

  • Lee, Gi-Hwan;Jo, Jae-Young;Chae, Gyu-Tae;Jang, Seong-Yong
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.43 no.3
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    • pp.77-86
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    • 2020
  • In this study, to improve the logistics flow of existing given chemical logistics warehouse, four logistics flow alternatives were proposed to minimize truck interference by building simulation model. The simulation model for chemical storage warehouse was built to evaluate system performance. Among the four new improved alternatives based on the basic model, the model with the same truck's pathways and locations of facilities identified an increase in the number of interferences but a decrease in daily working hours as the number of resources in a particular facility increases. Therefore, the three groups were classified as 'efficiency', 'complementary', and 'safety' based on the daily working hours, and the ratio of trucks entering two types of logistics warehouse was set in consideration of future market fluctuations. For each of the six types, the optimal number of resources was selected as the number of resources in the facilities with the least number of interferences in the basic model and the evaluation measures and characteristics set in this study were compared and analyzed. As a result, the Alternative 4 model operating the underground roadway produced interference between 17.0% and 36.4% of the basic model, with 113.3% of the interior loadspace.

Optimal Inspection Policy for One-Shot Systems Considering Reliability Goal (목표 신뢰도를 고려한 원-샷 시스템의 최적검사정책)

  • Jeong, Seung-Woo;Chung, Young-Bae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.40 no.4
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    • pp.96-104
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    • 2017
  • A one-shot system (device) refers to a system that is stored for a long period of time and is then disposed of after a single mission because it is accompanied by a chemical reaction or physical destruction when it operates, such as shells, munitions in a defense weapon system and automobile airbags. Because these systems are primarily related with safety and life, it is required to maintain a high level of storage reliability. Storage reliability is the probability that the system will operate at a particular point in time after storage. Since the stored one-shot system can be confirmed only through inspection, periodic inspection and maintenance should be performed to maintain a high level of storage reliability. Since the one-shot system is characterized by a large loss in the event of a failure, it is necessary to determine an appropriate inspection period to maintain the storage reliability above the reliability goal. In this study, we propose an optimal inspection policy that minimizes the total cost while exceeding the reliability goal that the storage reliability is set in advance for the one-shot system in which periodic inspections are performed. We assume that the failure time is the Weibull distribution. And the cost model is presented considering the existing storage reliability model by Martinez and Kim et al. The cost components to be included in the cost model are the cost of inspection $c_1$, the cost of loss per unit time between failure and detection $c_2$, the cost of minimum repair of the detected breakdown of units $c_3$, and the overhaul cost $c_4$ of $R_s{\leq}R_g$. And in this paper, we will determine the optimal inspection policy to find the inspection period and number of tests that minimize the expected cost per unit time from the finite lifetime to the overhaul. Compare them through numerical examples.

Optimal design of batch-storage serial trains considering setup and inventory holding cost (준비비와 재고비를 고려한 직렬 비연속 공정과 중간 저장조의 최적설계)

  • Lee, Gyeong-Beom
    • Journal of Institute of Control, Robotics and Systems
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    • v.3 no.4
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    • pp.398-405
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    • 1997
  • This article presents a new model which is called Periodic Square-Wave(PSW) to describe the material flow of the periodic processes involving intermediate buffer. The material flows incoming into and outgoing from the intermediate buffer are assumed to be periodic square shaped. PSW model gives the same result as that of Economic Production Quantity(EPQ) model for determining optimal lot size of single stage batch storage system. However, for batch storage serial train system, PSW model gives a different optimal solution of about 6 % reduced total cost. PSW model provides the more accurate information on inventory and production system than the classical approach by maintaining simplicity and increasing computational burden.

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A Novel Hybrid Supercapacitor Using a Graphite Cathode and a Niobium(V) Oxide Anode

  • Park, Gum-Jae;Kalpana, D.;Thapa, Arjun Kumar;Nakamura, Hiroyoshi;Lee, Yun-Sung;Yoshio, Masaki
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.817-820
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    • 2009
  • To meet the high current load requirement from the high energy density realized by metal oxide and high power density graphite, we propose a novel hybrid supercapacitor consisting of Nb2O5 and KS6 graphite in 1.0 M LiPF6-EC:DEC (1:2). This new system exhibits a sloping voltage profile from 2.7 to 3.5 V during charging and presents a high operating voltage plateau between 1.5 and 3.5 V during discharging. The cell was tested at a current density of 100 mA/g with a cut-off voltage between 3.0 and 1.0 V. This novel energy storage system delivers the highest initial discharge capacity of 55 mAh/g and exhibits a good cycle performance.

Heat Transfer Characteristics of High Temperature molten salt storage for Solar Thermal Power Generation (태양열 발전을 위한 고온 축열 물질의 열전달 특성)

  • Aiming, Mao;KIm, Ki-Man;Han, Gui-Young;Seo, Tae-Beom;Kang, Yong-Heack
    • Journal of the Korean Solar Energy Society
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    • v.27 no.3
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    • pp.63-69
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    • 2007
  • The heat transfer characteristics of inorganic salt for high temperature heat storage material of solar power system were examined. The inorganic salts employed in this study was a mixture of $NaNO_3$ and $KNO_3$ and the operating temperature range was determined by measuring the melting temperature with DSC and by measuring the thermal decomposition temperature with TGA. The heat transfer characteristics was qualitatively obtained in terms of temperature profiles of salt in the tanks during the heat storage and heat release process as a function of steam flow rates, steam inlet temperature and the inlet position of steam. The effects of steam flow rates and inlet temperature of steam were experimentally determined and the effect of natural convection was observed due to significant density difference with temperature.

The hydrogen storage capacity of metal-containing polyacrylonitrile-based electrospun carbon nanofibers

  • Bai, Byong-Chol;Kim, Jong-Gu;Naik, Mehraj-Ud-Din;Im, Ji-Sun;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.3
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    • pp.171-176
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    • 2011
  • Polyacrylonitrile-based carbon nanofibers (CNFs) containing Ti and Mn were prepared by electrospinning. The effect of metal content on the hydrogen storage capacity of the nanofibers was evaluated. The nanofibers containing Ti and Mn exhibited maximum hydrogen adsorption capacities of 1.6 and 1.1 wt%, respectively, at 303 K and 9 MPa. Toward the development of an improved hydrogen storage system, the optimum conditions for the production of metalized CNFs were investigated by characterizing the specific surface areas, pore volumes, sizes, and shapes of the fibers. According to the results of Brunauer-Emmett-Teller analysis, the activation of the CNFs using potassium hydroxide resulted in a large pore volume and specific surface area in the samples. This is attributable to the optimized pore structure of the metal-containing polyacrylonitrile-based electrospun CNFs, which may provide better sites for hydrogen adsorption than do current adsorbates.

An Evaluation of a super-absorbent polymer as the Nucleating Agent for a Capsule-type Ice Storage System (고흡수성고분자가 조핵제로 첨가된 빙축열용 축열재 개발)

  • Choi, Hyung-Joon;Hong, Seong-Ahn;Park, Won-Hoon
    • Solar Energy
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    • v.10 no.2
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    • pp.28-37
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    • 1990
  • A study was conducted to investigate the feasibility of using a super-absorbent polymer made from a acrylic acid copolymer for a capsule-type ice storage system. In a simple pyrex-tube test, 25% of distilled water samples tested turned out not be frozen at all at $-12^{\circ}C$ and the average supercooling of the samples frozen was $9.8^{\circ}C$. With the addition of 0.5wt% super-absorbent polymer, however, the supercooling of the distilled water was dramatically reduced and more than 35% of samples tested did not show any supercooling. The heat transfer characteristics of a capsule-type ice storage unit was also investigated with a distilled water as the phase-change material. With the addition of 0.5wt% polymer, the supercooling of water was not observed at all and thus an overall heat transfer was enhanced. Based on these results, it was concluded that a super-absorbent polymer is a potential candidate as the nucleating agent for an ice-storage system.

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Optimization of Solar Water Battery for Efficient Photoelectrochemical Solar Energy Conversion and Storage (효율적인 광전기화학적 태양에너지 전환과 저장을 위한 Solar Water Battery의 최적화)

  • Go, Hyunju;Park, Yiseul
    • Clean Technology
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    • v.27 no.1
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    • pp.85-92
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    • 2021
  • A solar water battery is a system that generates power using solar energy. It is a combination of photoelectrochemical cells and an energy storage system. It can simultaneously convert and store solar energy without additional external voltage. Solar water batteries consist of photoelectrodes, storage electrodes and counter electrodes, and their properties and combination are important for the performance and the efficiency of the system. In this study, we tried to find the effect that changing the components of solar water batteries has on its system. The effects of the counter electrode during discharge, the kinds of photoelectrode and storage electrode materials, and electrolytes on the solar energy conversion and storage capacitance were studied. The optimized composition (TiO2 : NaFe-PB : Pt foil) exhibited 72.393 mAh g-1 of discharge capacity after 15 h of photocharging. It indicates that the efficiency of solar energy conversion and storage is largely affected by the configuration of the system. Also, the addition of organic pollutants to the chamber of the photoelectrode improved the battery's photo-current and discharge capacity by efficient photoelectron-hole pair separation with simultaneous degradation of organic pollutants. Solar water batteries are a new eco-friendly solar energy conversion and storage system that does not require additional external voltages. It is also expected to be used for water treatment that utilizes solar energy.