• Title/Summary/Keyword: Chemical Gas Sensor

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Improved Sensitivity of an NO Gas Sensor by Chemical Activation of Electrospun Carbon Fibers

  • Kang, Seok-Chang;Im, Ji-Sun;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.1
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    • pp.21-25
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    • 2011
  • A novel electrode for an NO gas sensor was fabricated from electrospun polyacrylonitrile fibers by thermal treatment to obtain carbon fibers followed by chemical activation to enhance the activity of gas adsorption sites. The activation process improved the porous structure, increasing the specific surface area and allowing for efficient gas adsorption. The gas sensing ability and response time were improved by the increased surface area and micropore fraction. High performance gas sensing was then demonstrated by following a proposed mechanism based on the activation effects. Initially, the pore structure developed by activation significantly increased the amount of adsorbed gas, as shown by the high sensitivity of the gas sensor. Additionally, the increased micropore fraction enabled a rapid sensor response time due to improve the adsorption speed. Overall, the sensitivity for NO gas was improved approximately six-fold, and the response time was reduced by approximately 83% due to the effects of chemical activation.

A Study on the Selectivity of Gas Sensors by Sensing Pattern Recognition (감지 패턴 인식에 의한 가스센서의 선택성 연구)

  • Lee, Sung-Pil
    • Journal of Sensor Science and Technology
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    • v.20 no.6
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    • pp.428-433
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    • 2011
  • We report on the building of a micro sensor array based on typical semiconductor fabrication processes aimed at monitoring selectively a specific gas in ambient of other gases. Chemical sensors can be applied for an electronic nose and/or robots using this technique. Microsensor array was fabricated on the same chip using 0.6${\mu}m$ CMOS technology, and unique gas sensing patterns were obtained by principal component analysis from the array. $SnO_2$/Pt sensor for CO gas showed a high selectivity to buthane gas and humidity. $SnO_2$ sensor for hydrogen gas, however, showed a low selectivity to CO and buthane gas. We can obtain more distinguishable patterns that provide the small sensing deviation(the high seletivity) toward a given analyte in the response space than in the chemical space through the specific parameterization of raw data for chemical image formation.

Thermal Transport Phenomena in the FET Typed MWCNT Gas Sensor with the 60 μm Electrode Distance (60 μm의 전극 간극을 갖는 FET식 MWCNT 가스센서에서 열 유동 현상)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.6
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    • pp.403-407
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    • 2015
  • Generally, MWCNT, with thermal, chemical and electrical superiority, is manufactured with CVD (chemical vapor deposition). Using MWCNT, it is comonly used as gas sensor of MOS-FET structure. In this study, in order to repeatedly detect gases, the author had to effectively eliminate gases absorbed in a MWCNT sensor. So as to eliminate gases absorbed in a MWCNT sensor, the sensor was applied heat of 423[K], and in order to observe how the applied heat was diffused within the sensor, the author interpreted the diffusion process of heat, using COMSOL interpretation program. In order to interpret the diffusion process of heat, the author progressed modeling with the structure of MWCNT gas sensor in 2-dimension, and defining heat transfer velocity($u={\Delta}T/{\Delta}x$), accorded to governing equation within the sensor, the author proposed heat transfer mechanism.

Palladium-based Electrical and Optical Hydrogen Gas Sensors

  • Jinwoo, Lee;Minah, Seo
    • Journal of Sensor Science and Technology
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    • v.31 no.6
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    • pp.397-402
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    • 2022
  • In this short review, we explore the recent progress in metal-based gas-sensing techniques. The strong interaction between the metal films and hydrogen gas can be considered to play a considerably important role in the gas-sensing technique. The physical and chemical reactions in Pd-Pd hydride systems were studied in terms of the phase transition and lattice expansion of the metals. Two types of represented detection, electrical and optical, were introduced and discussed along with their advantages.

Quasi-Solid-State Hybrid Electrolytes for Electrochemical Hydrogen Gas Sensor

  • Kim, Sang-Hyung;Han, Dong-Kwan;Hong, SeungBo;Jeong, Bo Ra;Park, Bok-Seong;Han, Sang-Do;Kim, Dong-Won
    • Journal of Electrochemical Science and Technology
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    • v.10 no.3
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    • pp.294-301
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    • 2019
  • The quasi-solid-state hybrid electrolytes were synthesized by chemical cross-linking reaction of methacrylate-functionalized $SiO_2$ ($MA-SiO_2$) and tetra (ethylene glycol) diacrylate in aqueous electrolyte. A quasi-solid-state electrolyte synthesized by 6 wt.% $MA-SiO_2$ exhibited a high ionic conductivity of $177mS\;cm^{-1}$ at room temperature. The electrochemical $H_2$ sensor assembled with quasi-solid-state electrolyte showed relatively fast response and high sensitivity for hydrogen gas at ambient temperature, and exhibited better durability and stability than the liquid electrolyte-based sensor. The simple construction of the sensor and its sensing characteristics make the quasi-solid-state hydrogen sensor promising for practical application.

A Study on the Measurement of Halitosis of Human Mouth with Chemical Gas Sensor Arrays (화학 가스센서를 활용한 구취측정 방법에 관한 연구)

  • Lee, Seok-Jun;Kim, Sun-Tae;Kim, Han-Soo
    • Journal of Sensor Science and Technology
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    • v.20 no.4
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    • pp.279-285
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    • 2011
  • This study was carried out to apply chemical gas sensors for the identification of bad breath which is one of the important sensitive problem for the humans' daily life. Seven sensors, including five semiconductor sensors and two electrochemical sensors, were tested for the three panels three times in several conditions. The results showed that the reproducibility of sensors were generally good, and electrochemical sensors showed better reproducibility while semiconductor sensors showed better sensitivity. No rinsing before measurement showed relatively better results in terms of both sensitivity and reproducibility. Semiconductor gas sensors for hydrogen sulfide shows the highest sensitivity, and it was recommended to use the odor-free bag for the measurement of bad breath.

Signal Processing Techniques Based on Adaptive Radial Basis Function Networks for Chemical Sensor Arrays

  • Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.25 no.3
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    • pp.161-172
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    • 2016
  • The use of a chemical sensor array can help discriminate between chemicals when comparing one sample with another. The ability to classify pattern characteristics from relatively small pieces of information has led to growing interest in methods of sensor recognition. A variety of pattern recognition algorithms, including the adaptive radial basis function network (RBFN), may be applicable to gas and/ or odor classification. In this paper, we provide a broad review of approaches for various types of gas and/or odor identification techniques based on RBFN and drift compensation techniques caused by sensor poisoning and aging.

Fabrication of H2 Gas Sensor Based on ZnO Nanarod Arrays by a Sonochemical Method

  • Lee, Mi-Sun;Oh, Eu-Gene;Jeong, Soo-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3735-3737
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    • 2011
  • We report a simple method for fabricating ZnO gas sensors via a sonochemical route and their $H_2$ gas sensing properties. Vertically aligned ZnO nanorod arrays as a sensing material were synthesized on a Pt-electrode patterned alumina substrate under ambient conditions. The advantage of the proposed method is a high speed of processing. The gas sensor based on ZnO nanorod arrays with large specific surface area showed a high response to $H_2$ and a detection limit of 70 ppm at $250^{\circ}C$. Also, their response and recovery time were relatively short and a complete regeneration was observed. A mechanism for sensing $H_2$ gas on the surface of ZnO nanorods is proposed.

Fabrication of Chemical Sensors for the Detection of Acidic Gas using 1,3-bisdicyanovinylindane (1,3-bisdicyanovinylindane을 이용한 산성가스 감지용 화학 센서 제작)

  • Song, Hwan-Moon;Park, Young-Min;Son, Young-A;Lee, Chang-Soo
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.184-188
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    • 2008
  • This study presented simple and efficient fabrication of chemical sensors for the detection of acidic gas using 1,3-bisdicyanovinylindane as an indicator because it can be promising materials having property of the rapid color change according to the variation of pH. The dissociation of proton and dye in acidic condition as changing of ion pairs give rise to dramatically change the absorbance intensity of 1,3-bisdicyanovinylindane, which can be easily applied to the development of chemical sensors. In addition, indicator dyes having negatively charge in aqueous phase can be easily fabricated using layer-by-layer (LBL) methods by way of electrostatic interaction. For the proof of concept, we demonstrated the abrupt presentation of skeleton symbol on the chemical sensor, which could be resulted from the reaction of 1,3-bisdicyanovinylindane as background color with acidic gas. Thus, the rapid appearance of symbol will induce user's caution under the emergency condition. The presented chemical gas sensor using 1,3-bisdicyanovinylindane have strong advantages. First, the fabrication process of gas sensor was very simple and low-cost. Secondly, sensors reacted by acidic gas could be reused for several times. Finally, the chemical gas sensor would be environmentally friend, which can be a basic tool for the realization of eco-organic sensor device.