Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Quasi-Solid-State Hybrid Electrolytes for Electrochemical Hydrogen Gas Sensor

  • Kim, Sang-Hyung (Department of Chemical Engineering, Hanyang University) ;
  • Han, Dong-Kwan (Department of Chemical Engineering, Hanyang University) ;
  • Hong, SeungBo (Department of Chemical Engineering, Hanyang University) ;
  • Jeong, Bo Ra (Department of Chemical Engineering, Hanyang University) ;
  • Park, Bok-Seong (Engineering & Technology, Sin Myung ENTEC Co., Ltd.) ;
  • Han, Sang-Do (R&D Center, ShinWoo Electronics Co., Ltd.) ;
  • Kim, Dong-Won (Department of Chemical Engineering, Hanyang University)
  • Received : 2019.02.18
  • Accepted : 2019.04.11
  • Published : 2019.09.30
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Abstract

The quasi-solid-state hybrid electrolytes were synthesized by chemical cross-linking reaction of methacrylate-functionalized $SiO_2$ ($MA-SiO_2$) and tetra (ethylene glycol) diacrylate in aqueous electrolyte. A quasi-solid-state electrolyte synthesized by 6 wt.% $MA-SiO_2$ exhibited a high ionic conductivity of $177mS\;cm^{-1}$ at room temperature. The electrochemical $H_2$ sensor assembled with quasi-solid-state electrolyte showed relatively fast response and high sensitivity for hydrogen gas at ambient temperature, and exhibited better durability and stability than the liquid electrolyte-based sensor. The simple construction of the sensor and its sensing characteristics make the quasi-solid-state hydrogen sensor promising for practical application.

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References

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