• Bulletin of the Korean Chemical Society
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• 제24권9호
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• pp.1389-1392
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• 2003

• Bulletin of the Korean Chemical Society
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• 제12권5호
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• pp.574-582
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• 1991

The CO molecules adsorbed on Ni(111) surface is studied in the cluster approximation employing EH method with self-consistent charge iteration. The effect of CO coverage is simulated by allowing the variation of valence state ionization potentials of each Ni atom in model cluster according to the self-consistent charge iteration method. The CO coverage dependent C-O stretching frequency shift, adsorption site conversion, and metal work function change are attributed to the charge transfer between metal surface and adsorbate. For CO/Ni(111) system, net charge transfer from Ni surface to chemisorbed CO molecules makes surface Ni atoms be more positive with increasing coverage, and lowers Ni surface valence band. This leads to a weaker interaction between metal surface valence band and Co $2{\pi}^{\ast}$ MO, less charge transfer to a single CO molecule, and the bule shift of C-O stretching frequency. Further increase of coverage induces the conversion of 3-fold site CO to lower coordination site CO as well as the blue shift of C-O stretching frequency. This whole process is accompanied by the continuous increase of metal work function.

• Journal of information and communication convergence engineering
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• 제9권1호
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• pp.78-82
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• 2011

This paper proposes a new circuit for capacitive sensing based on Dickson's charge pump. The proposed touch sensing circuit includes three stages of NMOS diodes and capacitors for charge transfer. The proposed circuit which has a simplified capacitive touch sensor model has been analyzed and simulated by Spectre using Magna EDMOS technology. Looking from the simulation results, the proposed circuit can effectively be used as a capacitive touch sensing circuit. Moreover, a simple structure can provide maximum flexibility for making a digitally-controlled touch sensor driver with lowpower operations.

• 접착 및 계면
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• 제22권4호
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• pp.144-152
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• 2021

유기반도체와 게이트 절연체 간 계면전하이동을 이해하는 것은 고성능 유기메모리, 고안정성 유기전계효과 트랜지스터 (이하 유기트랜지스터) 개발에 기여할 수 있다. 본 연구에서는 계면 간 전하이동의 특이거동, 즉 홀전하가 유기반도체에서 고분자절연체로 이동되어 편재화되는 것이 편재화 준위간의 커플링에 의해 비선형적으로 가속화될 수 있음을 최초로 밝혀내었다. 이의 규명을 위해 rubrene 단결정과 Mylar 절연체를 기반으로 한 유기트랜지스터를 vacuum lamination 공정으로 제작하여 반도체-절연체 계면의 반복적인 전사와 박리에도 안정적인 소자를 개발하였다. Rubrene 단결정과 Mylar film의 표면을 각각 광유도 산소 확산법과 UV-오존 처리를 통해 결함을 생성시켰다. 그 결과, 계면 간 전하이동과 이에 의한 바이어스 스트레스 효과가 rubrene과 Mylar가 가진 편재화 준위 간 커플링에 의해 비선형적으로 급격하게 가속화되었음을 관측하였다. 특히, rubrene 단결정에 있는 적은 밀도의 편재화 준위가 계면 간 전하이동을 촉진하는데 가교역할을 함을 밝혀내었다

• 대한전자공학회논문지SD
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• 제46권12호
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• pp.80-86
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• 2009

전하펌프의 성능은 공급전압에 의해 크게 영향을 받는다. 본 논문에서는 표준 twin-well CMOS 로직 공정으로 제작 가능하며, 낮은 공급전압에서도 높은 효율을 갖는 새로운 전하펌프 회로를 제안하고 검증하였다. 제안한 전하펌프는 이중의 전하 전달 경로와 간단한 2-phase 클락을 사용한다. 한 주기의 펌핑 사이클 동안 각 펌핑 단에서 입력전압을 2배로 승압하며, 상보적으로 연결된 PMOS 트랜지스터를 전달 스위치로 사용하여 트랜지스터의 문턱전압에 의한 전압강하 없이 승압된 전압을 다음 승압 단으로 전달한다. 시뮬레이션과 측정을 통해 제안한 전하펌프를 검증하였으며, 동일한 공정조건에서 제작 가능한 기존 전하펌프들 보다 높은 출력전압과 큰 전류 구동능력 그리고 더 높은 전력효율을 가진다는 것을 확인하였다.

• Journal of Mechanical Science and Technology
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• 제20권5호
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• pp.681-691
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• 2006

Nucleate boiling heat transfer for refrigerants, R113, and R113+wt4% ethanol mixture, an azeotropic mixture under electric field was investigated experimentally in a single-tube shell/ tube heat exchanger. A special electrode configuration which provides a more uniform electric field that produces more higher voltage limit against the dielectric breakdown was used in this study. Experimental study has revealed that the electrical charge relaxation time is an important parameter for the boiling heat transfer enhancement under electric field. Up to 1210% enhancement of boiling heat transfer was obtained for R113+wt4% ethanol mixture which has the electrical charge relaxation time of 0.0053 sec whereas only 280% enhancement obtained for R113 which has relaxation time of 0.97 sec. With artificially machined boiling surface, more enhancement in the heat transfer coefficient in the azeotropic mixture was obtained.

• 대한기계학회논문집B
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• 제26권12호
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• pp.1646-1654
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• 2002

A two-phase closed thermosyphon was one of the most effective devices in the removing heat because of its simple structure, thermal diode characteristics, wide operating temperature range and so on. In this study, a two-phase closed thermosyphon(working fluid PFC(C6F14), container copper(inner grooved surface)) was fabricated with a reservoir which can change the fill charge ratio. The experiments were performed in the range of 50~600W heat flow rate and 10~70% fill charge ratio. The results were compared with some correlations that were presented by Rohsenow and Immura et al. in the evaporator, by Nusselt, Gross and Uehara et al. in the condenser and by Cohen and Bayley, Wallis, Kutateladze and Faghri et al. in heat transfer limitation etc.. The heat transfer coefficient at the evaporator increased with the input power. However the effect of the fill charge ratio was nearly negligible. At the condenser, it showed an opposite trend to the evaporator and with increase of the fill charge ratio, showed some enhancement of heat transfer. The heat transport limitation was occurred by the dry-out limitation for small fill charge ratio(10%) and presented about 100W. For the case of large fill charge ratio(Ψ$\geq$40%), it was occurred by the flooding limitation at about 500W.

• Journal of Electrical Engineering and Technology
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• 제1권2호
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• pp.233-236
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• 2006

A 3-D numerical simulation of a buried-channel CCD (Charge Coupled Device) with a deep depletion has been performed to investigate its electrical and physical behaviors. Results are presented for a deep depletion CCD (EEV CCD12; JET-X CCD) fabricated on a high-resistivity $(1.5k\Omega-cm)\;65{\mu}m$ thick epi-layer, on a $550{\mu}m$ thick p+ substrate, which is optimized for X-ray detection. Accurate predictions of the Potential minimum and barrier height of a CCD Pixel as a function of mobile electrons are found to give good charge transfer. The depletion depth approximation as a function of gate and substrate bias voltage provided average errors of less than 6%, compared with the results estimated from X-ray detection efficiency measurements. The result obtained from the transient simulation of signal charge movement is also presented based on 3-Dimensional analysis.

• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.179-185
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• 2013

The behavior of surface film formation was greatly dependent on the speed of potential cycling. In $LiClO_4$ / EC + DEC, cyclic voltammetry results showed that the peaks originated from surface film formation on graphite electrode at the high charge-discharge rate was shifted to the lower potentials as the charge-discharge rate decrease. This indicates that surface films with different morphology and thickness were formed by different charge-discharge rate. Transmission electron microscopy (TEM) results indicated that the properties such as thickness and morphology of the surface film were greatly affected by the charge-discharge rate. Electrochemical impedance spectroscopy (EIS) showed that the resistance of surface film was affected by the speed of potential cycling. In addition, the charge transfer resistance was also dependent on the charge-discharge rate indicating that the charge transfer reaction was affected by the nature of surface film. TEM and EIS results suggested that the chemical property as well as the physical property of the surface film was affected by the charge-discharge rate.

• Bulletin of the Korean Chemical Society
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• 제19권9호
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• pp.980-985
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• 1998

The excited-state intramolecular proton transfer (ESIPT) emission has been observed for 0.01 mM p-aminosalicylic acid (AS) in nonpolar aprotic solvents as demonstrated by the large Stokes' shifted fluorescence emission around 440 nm in addition to the normal emission at 330 nm. However in aprotic polar solvent such as acetonitrile, the large Stokes' shifted emission band becomes broadened, indicating existence of another emission band originated from intramolecular charge transfer (ICT). It is noteworthy that in protic solvents such as methanol and ethanol the normal and ICT emissions are quenched as the AS concentration decreases, followed by the appearance of new emission at 380 nm. These results are interpreted in terms of ESIPT coupled charge transfer in AS. Being consistent with these steady-state spectroscopic results, the picosecond time-resolved fluorescence study unravelled the decay dynamics of the ESIPT and ICT state ca. 300 ps and ca. 150 ps, respectively with ca. 40 ps for the relaxation time to form the ICT state.