• Bulletin of the Korean Chemical Society
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• 제32권10호
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• pp.3726-3729
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• 2011

Biofilm formation is inevitable in a bioelectrochemical system in which microorganisms act as a sole biocatalyst. Cathodic biofilm (CBF) works as a double-edged sword in the performance of the air-cathode microbial fuel cells (MFCs). Proton and oxygen crossover through the CBF are limited by the robust structure of extracellular polymeric substances, composition of available constituents and environmental condition from which the biofilm is formed. The MFC performance in terms of power, current and coulombic efficiency is influenced by the nature and origin of CBF. Development of CBF from different ecological environment while keeping the same anode inoculums, contributes additional charge transfer resistance to the total internal resistance, with increase in coulombic efficiency at the expense of power reduction. This study demonstrates that MFC operation conditions need to be optimized on the choice of initial inoculum medium that leads to the biofilm formation on the air cathode.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.55.1-55.1
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• 2011

Dye-sensitized solar cell(DSSC) have been considered one of the promising alternatives to conventional solar cells, because of their low cost, easy fabrication and relatively high energy conversion efficiency. However, although the cell offers reasonable efficiency at least 11%, the use of a liquid electrolyte placed technological challenges for achieving the desired durability and operational stability of the cell. In order to prevent or reduce electrolyte leakage considerable efforts have been made, such as p-type semiconductor or organic hole-transport material that better mechanical properties and simple fabrication processes. In this work, we synthesized solid-state electrolyte containing LiI and KI metal salt with starting materials of poly ethylene oxide to substitute liquid electrolyte enhance the ionic conductivity and solar conversion efficiency. Li+ leads to faster diffusion and higher efficiency and K+ leading to higher ionic conductivity. The efficiency of poly ethylene oxide/LiI system electrolyte is 1.47% and poly ethylene oxide/potassium electrolyte is 1.21%. An efficiency of 3.24% is achieved using solid-state electrolyte containing LiI and KI concentrations. The increased solar conversion efficiency is attributed to decreased crystallinity in the polymer that leads to enhanced charge transfer.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.268-273
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• 2001

A fundamental study on the harvest-type ice storage system applied ice making method in-water and its temperature characteristics in ice storage system was performed experimentally of the charge and discharge of cold. This paper is concerned with the development of a new method for making and separating ice and saving floated ice by installing an evaporation plate at in-water within a storage tank. In a conventional harvest-type ice storage system, a tank saves ice by separating a formed ice from an installed evaporation plate, which is located above an ice storage tank as an ice storage system. A new harvest-type method shows very good heat transfer efficiency than a convectional method. It is because the evaporation panel is directly contacted with water in a storage tank. Also, at a conventional system a circulating pump, a circulating water distributor and a piping are installed, but these components are not necessary in a new method. In this study two kinds of ice storage systems are experimentally investigated to study the thermal characteristics of ice storage tanks.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2008년도 하계학술대회 논문집
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• pp.37-39
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• 2008

In this paper, a three-port bidirectional modular circuit applied in charging and discharging equalization for lithium-ion battery strings is proposed. This circuit consists of four MOSFETs and one transformer which provide a simple structure to be easily modularized. Compared to conventional individual cell equalization schemes, it utilizes the transformer as the energy transfer element, allowing direct transfer of energy between arbitrary two cells of three-cell battery module, thus improving the equalization efficiency significantly by using much less number of equalizers for long battery strings. Simulation results are presented to validate the circuit operation and confirm its capability to equalize the three-cell battery module.

• 수산해양교육연구
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• 제25권4호
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• pp.998-1007
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• 2013

At container terminals, a major measurement of productivity can be work efficiency. For improving the productivity of container crane, the more efficient container yard operation method is necessary in container terminals. Recently, container terminal operators make an experiment on the dual cycle operation, which ship loading/unloading were carried out simultaneously, for increasing the productivity of container crane. In this paper, propose a system operating efficient dual cycle methods as utilize Ad-hoc technology in distributed port operation system. The dual cycle methods that proposed recognizes position information of Y/T during an action in Ad-hoc networks in case of container transfer works by real time as load an Ad-hoc module to Y/T taking charge of a container transfer with quay and yard. Utilize Ad-hoc networks technology in an operating system of container yard, and efficiently distributed processing done Y/T to container crane compare with operation systems of the existing dedicated method, and an improvement can do an operating system of an yard.

• Bulletin of the Korean Chemical Society
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• 제11권3호
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• pp.224-227
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• 1990

The excitation mechanism of polycyclic aromatic amines (amino-PAHs) and polycyclic aromatic hydrocarbons(PAHs) for the chemiluminescence arising from the reaction between oxalate ester, bis(2,4,6-trichlorophenyl)oxalate (TCPO) or bis(2,4-dinitrophenyl)oxalate (DNPO) and hydrogen peroxide has been studied in terms of the excitation efficiencies to singlet excitation energies and the oxidative half-wave potentials. As a results of the study, the excitations of both amino-PAHs and PAHs appear to involve the charge transfer type of energy transfer. However the chemiluminescence efficiency corrected for fluorescence quantum yield of the amino-PAHs are varied more sensitively to the oxidative half-wave potential than that of PAHs possibly due to the large difference in solvation energy between the compounds and their ions.

• 한국광학회지
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• 제4권1호
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• pp.57-65
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• 1993

용량 이행형 방전여기에 의한 소형 XeCl레이저를 제작하고, 가스 혼합비에 따른 출력특성을 조사하였다. 내자형 capacitor에 의한 자동 예비전리 방식과 2.7 cm 간격의 Chang형상으로 가공된 전극구조의 레이저를 구성하여 2.7cm${\times}$1.5cm 크기의 출력 빔을 얻었고, Xe과 HC1의 농도 변화 및 완충 기체의 종류에 따른 최대 출력 에너지 및 최대 효율 조건을 조사하였다. 최대 레이저 펄스 에너지는 Ne 완충기체를 사용시 230mJ이며, 단위 방전 체적당 1.1 J/l의 에너지를 얻었으며, 최대 에너지 효율은 1.6%이었다. 1:3의 낮은 비율의 피-킹 캐패시턴스의 구성에 의해 레이저 펄스폭은 장펄스 효과를 나타내 foot-to-foot 200 ns로 측정되었다.

• Korean Chemical Engineering Research
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• 제61권4호
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• pp.627-634
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• 2023

Graphitic carbon nitride (g-C₃N₄) has attracted considerable attention since its discovery for its catalysis of water splitting to hydrogen and oxygen under visible light irradiation. However, pristine g-C₃N₄ confers only low photocatalytic efficiency and requires surface cocatalysts to reach moderate activity due to a lack of accessible surface active sites. Inspired by the high specific surface area and superior electron transfer of graphene, we developed a strongly coupled binary structure of graphene and g-C₃N₄ aerogel with 3D porous skeleton. The as-prepared 3D structure photocatalysts achieve a high surface area that favors efficient photogenerated charge separation and transfer, enhances the light-harvesting efficiency, and significantly improves the photocatalytic hydrogen evolution rate as well. The photocatalyst performance is observed to be optimized at the ratio 3:7 (g-C₃N₄:GO), leading to photocatalytic H₂ evolution of 16125.1 mmol. g^-1. h^-1 under visible light irradiation, more than 161 times higher than the rate achieved by bulk g-C₃N₄.

• Bulletin of the Korean Chemical Society
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• 제22권1호
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• pp.63-67
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• 2001

The photophysical properties and the singlet oxygen generation efficiency of tetrathiarubyrin have been investigated to elucidate the possibility of its use as a photodynamic therapy (PDT) photosensitizer by steady-state and time-resolved spectroscopic methods. The observed photophysical properties were affected by various molecular aspects, such as extended ${\pi}conjugation$, structural distortion, and internal heavy atom. The steady-state electronic absorption spectrum was red-shifted due to the extended $\pi-conjugation$, and the spin orbital coupling was enhanced by the structural distortion and the internal heavy atom effect. As a result of the enhanced spin orbital coupling, the triplet quantum yield increased to 0.90 $\pm$ 0.10 and the triplet state lifetime was shortened to 7.0 $\pm$ 1.2 ${\mu}s$. Since the triplet state decays at a relatively faster rate, the efficiency of the oxygen quenching of the triplet state decreases. The singlet oxygen quantum yield was estimated to be 0.52 $\pm$ 0.02, which is somewhat lower than expected. On the other hand, the efficiency of singlet oxygen generation during the oxygen quenching of triplet state, $f{\Delta}^T$, is near unity. Such high efficiency of singlet oxygen generation can be explained by the following two possible factors: The hydrogen bonding of ethanol which impedes the deactivation pathway of the charge transfer complex with oxygen to the ground state, the less probability of the aggregation formation.

• 한국재료학회지
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• 제31권11호
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• pp.593-600
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• 2021

Herein, a series of g-C₃N₄ modified Bi₂MoO₆ nanocomposites using Bi₂MoO₆ and melamine as original materials are fabricated via sintering process. For presynthesis of Bi₂MoO₆ an ultrasonic-assisted hydrothermal technique is researched. The structure and composition of the nanocomposites are characterized by Raman spectroscopy, X-ray diffraction (XRD), and high-resolution field emission scanning electron microscopy (SEM). The improved photoelectrochemical properties are studied by photocurrent density, EIS, and amperometric i-t curve analysis. It is found that the structure of Bi₂MoO₆ nanoparticles remains intact, with good dispersion status. The as-prepared g-C₃N₄/Bi₂MoO₆ nanocomposites (BMC 5-9) are selected and investigated by SEM analysis, which inhibits special morphology consisting of Bi₂MoO₆ nanoparticles and some g-C₃N₄ nanosheets. The introduction of small sized g-C₃N₄ nanosheets in sample BMC 9 is effective to improve the charge separation and transfer efficiency, resulting in enhancing of the photoelectric behavior of Bi₂MoO₆. The improved photoelectronic behavior of g-C₃N₄/Bi₂MoO₆ may be attributed to enhanced charge separation efficiency, photocurrent stability, and fast electron transport pathways for some energy applications.