• Journal of Electrical Engineering and Technology
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• 제9권2호
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• pp.635-642
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• 2014

The space charge behaviors of oil-paper insulation affect the stability and security of oil-filled converter transformers of traditional and new energies. This paper presents the results of the electrical aging of oil-impregnated paper under AC-DC combined voltages by the pulsed electro-acoustic technique. Data mining and feature extractions were performed on the influence of electrical aging on charge dynamics based on the experiment results in the first stage. Characteristic parameters such as total charge injection and apparent charge mobility were calculated. The influences of electrical aging on the trap energy distribution of an oil-paper insulation system were analyzed and discussed. Longer electrical aging time would increase the depth and energy density of charge trap, which decelerates the apparent charge mobility and increases the probability of hot electron formation. This mechanism would accelerate damage to the cellulose and the formation of discharge channels, enhance the acceleration of the electric field distortion, and shorten insulation lifetime under AC-DC combined voltages.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1993년도 하계학술대회 논문집 B
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• pp.624-626
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• 1993

The Electrical Charge generated by friction in flowing insulating oil can create hazadous accidents. Neutralization of static charges in the oil during transportation is an obvious method of overcoming the problem of internal electric charge. It is known that SCR(Static Charge Reducer) can neutralize much of this charge by the needle electrode and mixing it with the original charge. In our experiment, a filter to generate static charge was set just befor a measurement pipe, and streaming current from the filter to the earth $I_s$, current from the electrode to the earth $I_e$ and current from the receiving tank to the earth $I_f$ were measured in a steady state. As a result, charge density and needle electrode current increases with increasing of oil temperature. Charge elimination rate decreases with increasing of oil flow rate, and increases with increases of oil temperature. Faraday Cage current decreases with increasing of oil temperature.

• 전기전자학회논문지
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• 제25권4호
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• pp.770-773
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• 2021

본 논문에서는 tapering과 ferroelectric(HfO₂)구조가 적용된 3D NAND flash memory의 프로그램 이후 시간경과에 따른 retention특징을 분석했다. Nitride에 trap된 전자는 시간이 지남에 따라 lateral charge migration이 발생한다. 프로그램 이후 시간이 지남에 따라 trap된 전자가 tapering에 의해 두꺼워진 채널 쪽으로 lateral charge migration이 더 많이 발생하는 것을 확인했다. 또한 Oxide-Nitride-Ferroelectric (ONF) 구조는 polarization에 의해 lateral charge migration이 완화되기 때문에 기존 Oxide-Nitride-Oxide (ONO) 구조 보다 문턱전압(V_th)의 변화량이 줄어든다.

• 대한기계학회논문집B
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• 제27권10호
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• pp.1498-1507
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• 2003

A SMPS(scanning mobility particle sizer) system measures the number size distribution of particles using electrical mobility detection technique. An aerosol charge neutralizer, which is a component of the SMPS, is a bipolar charger using a radioactive source to apply an equilibrium charge distribution to aerosols of unknown charge distribution. However, the performance of aerosol charge neutralizers is not well known, especially for highly charged particles. In this study, the effect of the particle charging characteristics of two aerosol charge neutralizers on the measurement using a SMPS system was experimentally investigated for highly charged polydisperse particles. One has radioactive source of $^{85}$ Kr (beta source, 2 mCi) and the other has $^{210}$ Po (alpha source, 0.5 mCi). The air flow rate passing through each aerosol charge neutralizer was changed from 0.3 to 3.0 L/min. The results show that the non-equilibrium character in particle charge distribution appears as the air flow rate increases although the particle number concentration is relatively low in the range of 1.5∼2x10$^{6}$ particles/㎤. The low neutralizing efficiency of the $^{85}$ Kr aerosol charge neutralizer for highly charged particles can cause to bring an artifact in the measurement using a SMPS system. However, the performance of the $^{210}$ Po aerosol charge neutralizer is insensitive to the air flow rate.

• 한국입자에어로졸학회지
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• 제14권1호
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• pp.17-24
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• 2018

Since the motion of the charged particle strongly depends on its charge characteristics, information on charge distributions of target particles is one of the important variables in aerosol research. In this study, charged distribution of atomized NaCl particles were measured using a Gerdien type ion counter. Two kinds of particle charging conditions were used in this study. First, atomized NaCl particles were passed through an aerosol neutralizer to have a Boltzmann charge distribution, and then its charge distribution was measured. In this case, the portion of uncharged particles was compared with the portion obtained from the Boltzmann charge distribution for verifying the suggested experimental method. Second, same experiment was conducted without the aerosol neutralizer to measure the charge distribution of atomized and un-neutralized NaCl particles. In the conclusion, the portion of uncharged, negatively charged and positively charged particles were 19%, 62% and 20%, respectively, for neutralized particles. The atomized particles, which was generated without the aerosol neutralizer, also had almost a zero charge state, but the standard deviation in charge distribution was larger than that of neutralized particles. The test method proposed in this study is expected to be used in various aerosol research fields because it can obtain simple information on the particle charge characteristics more easily and quickly than the existing test methods.

• Applied Biological Chemistry
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• 제17권2호
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• pp.143-148
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• 1974

Aflatoxin $B_1$은 전자수용성(電子受容性)을 높여주는 염화아연(鹽化亞鉛) 존재하(存在下)에서 전자공여성분자(電子供與性分子)인 Benzene과 Charge-transfer Complex를 만들며, 그 생성기구(生成機構)는 Aflatoxin $B_1$이 염화아연(鹽化亞鉛)과 일차적(一次的)으로 배위결합(配位結合)된 화합물(化合物)을 거쳐, 이것이 Benzene과 결합(結合)하여 착물(錯物)을 형성(形成)한다. 이 착물(錯物)의 안정도상수(安定度常數) 즉(卽) 평형상수(平衡常數) 0.198 l/mole이었다. 따라서 Aflatoxin $B_1$은 약(弱)한 전자수용체(電子受容體)이나, Benzene 보다 강(强)한 전자공여체(電子供與體)와는 염화아연(鹽化亞鉛)이 존재(存在)하지 않아도 Charge-transfer Complex를 만들 수 있다는 가능성(可能性)을 제시(提示)해 주는 것이며, Tryptophane, Histidine과 같은 강(强)한 전자공여체(電子供與體)를 함유(含有)한 단백질(蛋白質) 또는 Guanine, Adenine과 같은 전자공여체(電子供與體)를 함유(含有)한 DNA등(等)과의 Aflatoxin $B_1$의 결합(結合)은 그 결합(結合) Mechanism으로서 Charge-transfer Complex 형성(形成)으로 이루어진다는 추정(推定)을 할 수 있다.

• Journal of Electrical Engineering and Technology
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• 제10권3호
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• pp.1124-1130
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• 2015

Moisture and high temperature are the most important factors that lead to the ageing of oil-paper insulation, but the research about space charge characteristics of oil-paper insulation does not take the combined effect of ambient temperature, moisture and thermal ageing into account. The pulsed electroacoustic (PEA) method was used to investigate the influence of moisture and temperature on space charge characteristics of oil paper at different ageing stages. The results showed that moisture could speed up formation of space charge in oil paper when water concentration was low, but the formation was restrained if the water concentration was high. At the beginning of thermal ageing, heterogeneous charge accumulation had predominance, but it gradually changed to homogeneous charge injection with ageing. It was believed that moisture concentration could speed up ageing and enhance charge accumulation on one hand, and accelerate or slow down the establishment speed of space charge on the other hand, therefore, charge accumulation type changed with ageing. The more seriously the oil-paper insulation was thermally aged, the deeper the trap energy level was, hence more space charge was trapped, which could be speeded up by increasing the ageing temperature, but the effect of ambient temperature did not fit the Arrhenius law.

• 대한전자공학회논문지SD
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• 제49권5호
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• pp.37-42
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• 2012

기존의 전류 스티어링 전하 펌프의 타이밍 부정합 감소를 위한 새로운 전하 펌프를 제안한다. 기존의 전류 스티어링 전하 펌프는 UP, DOWN 신호의 입력단에 NMOS를 사용하여 서로 다른 지연단 수를 갖게 된다. 제안한 전하 펌프에서는 DOWN 신호의 입력단에 PMOS를 사용함으로써 UP, DOWN 신호의 지연단 수를 동등하게 한다. 기존의 전류 스티어링 전하 펌프를 최적화하여 시뮬레이션한 결과 턴온과 턴오프에 대하여 지연시간의 차이는 각각 14ns, 6ns 이다. 반면에 제안한 전하 펌프는 타이밍 부정합이 향상되어 턴온과 턴오프에 대하여 지연시간의 차이는 각각 6ns, 5ns 이다. 타이밍 부정합의 감소로 인하여 기준 스퍼는 -26dBc에서 -39dBc로 줄어들었다. 제안하는 전하 펌프는 CMOS $0.18{\mu}m$ 공정을 사용하여 설계하였다. 측정 결과 전하 펌프 출력 전압 범위 0.3~1.5V에서 최대 1.5%의 전류 부정합을 보인다.

• 한국환경과학회지
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• 제14권6호
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• pp.525-532
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• 2005

Polyelectrolyte titration, which was called colloid titration is based on the stoichiometric reaction between oppositely charged polyelectrolytes, This can be used, for instance, to determine the charge density of a cationic polyelectrolyte, using an anionic polyelectrolyte of known charge density, such as potassium polyvinyl sulfate (PPVS). The technique requires a suitable method of end-point detection and there are several possibilities. In this work, two methods have been investigated: visual titrimetry based on the color change of a cationic dye (o-toluidine blue, o-Tb) and spectrophotometry based on the absorbance change corresponding to the color change of the same dye. These have been applied to several cationic polyelectrolytes with different charge density and molecular weight. In all cases, the cationic charge was due to quaternary nitrogen groups. In the case of cationic dye, it was shown that the sharpness depends on the charge density of cationic polyelectrolyte. With the polyelectrolytes of lower charge density, the binding to PPVS is weaker and binding of the dye to PPVS can occur before all of the polyelectrolyte charge has been neutralized. However, by carrying out titrations at several polyelectrolyte concentrations, good linear relationships were found, from which reliable charge density values could be derived. Effects of pH and ionic strength were also briefly investigated. For cationic polyelectrolytes (copolymers of acrylamide and dimethylaminoethy] acrylate), there was some loss of charge at higher pH values, probably as a result of hydrolysis. Increasing ionic strength causes a less distinct color change of o-Tb, as a result of weaker electrostatic interactions.

• Nuclear Engineering and Technology
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• 제11권4호
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• pp.295-301
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• 1979

열중성자에 의한 $U^{235}$의 핵분열 시에 가벼운 쪽 핵분열 생성물의 핵전하 분포를 질량수에 따라 계산했다. 1차 핵분열 생성물의 핵전하 분포를 계산해서 실험치와의 비교를 통해, 지금까지 게시된 핵분열 조각의 핵전하 분포를 결정하는 이론의 타당성을 검토한 결과 어느 이론도 핵분열 조각의 핵전하 분포를 정확하게 기술할 수 없는 것이 판명됐다. 핵분열 조각의 최빈전하 ($Z_{P}$)와 불변전하밀도($Z_{UCD}$, UCD : Unchanged Charge Density)와의 차이는 0.45~0.5 사이로 질량수에 따라 크게 변동하지 않음을 보여준다. 핵분열 조각의 핵전하 분포에서 분산도를 나타내는 표준편차 ($\sigma$)는 ~0.5의 값을 갖는 것으로 나타났다. 핵분열 생성물에서 중성자의 Odd-Even 효과가 나타나려면, 즉발중성자 방출확률에도 Odd-Even 효과가 나타나야 한다는 결론을 얻었다.