• Title/Summary/Keyword: Charge/discharge test

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Solid state electrochemical double layer capacitors with natural graphite and activated charcoal composite electrodes

  • Hansika, P.A.D.;Perera, K.S.;Vidanapathirana, K.P.;Zainudeen, U.L.
    • Advances in materials Research
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    • v.8 no.1
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    • pp.37-46
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    • 2019
  • Electrochemical double layer capacitors (EDLCs) which are fabricated using carbon based electrodes have been emerging at an alarming rate to fulfill the energy demand in the present day world. Activated charcoal has been accepted as a very suitable candidate for electrodes but its cost is higher than natural graphite. Present study is about fabrication of EDLCs using composite electrodes with activated charcoal and Sri Lankan natural graphite as well as a gel polymer electrolyte which is identified as a suitable substitute for liquid electrolytes. Electrochemical Impedance Spectroscopy, Cyclic Voltammetry and Galvanostatic Charge Discharge test were done to evaluate the performance of the fabricated EDLCs. Amount of activated charcoal and natural graphite plays a noticeable role on the capacity. 50 graphite : 40 AC : 10 PVdF showed the optimum single electrode specific capacity value of 15 F/g. Capacity is determined by the cycling rate as well as the potential window within which cycling is being done. Continuous cycling resulted an average single electrode specific capacity variation of 48 F/g - 16 F/g. Capacity fading was higher at the beginning. Later, it dropped noticeably. Initial discharge capacity drop under Galvanostatic Charge Discharge test was slightly fast but reached near stable upon continuous charge discharge process. It can be concluded that initially some agitation is required to reach the maturity. However, the results can be considered as encouraging to initiate studies on EDLCs using Sri Lankan natural graphite.

Charge/Discharge Characteristics of $LiMnO_2$ Battery using Carbon as Anode Materials (카본을 부극으로 사용하는 $LiMnO_2$ 전지의 전기화학적 특성)

  • Jin, En-Mei;Lim, Seung-Gyu;Kim, Nam-In;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.277-278
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    • 2008
  • Orthorhombic $LiMnO_2$(o-$LiMnO_2$) has attracted public attentions as a cathode materials of Lithium ion battery because it has low cost and high theoretical discharge capacity of 285mAh $g^{-1}$. In our study, o-$LiMnO_2$ is synthesized by quenching method. To verify their phase structure, X-ray diffraction is accomplished. Test cells are assembled to check electrochemical characteristics using acquired o-$LiMnO_2$ cathode and carbon anode. Charge/Discharge cycling was carried out for 50cycles. And impedance was measured at 1, 2, 5, 10, 30, 50cycle. During cycle test, the max discharge capacity was recorded 139mAh $g^{-1}$ at 10cycle.

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Insulation Performance Estimation of Main Relays by Partial Discharges (부분방전에 의한 주계전기의 절연성능 평가)

  • Kil, Gyung-Suk;Kim, Il-Kwon;Park, Dae-Won;Song, Jae-Yong;Lee, Gang-Won;Cho, Eun-Je
    • Journal of the Korean Society for Railway
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    • v.10 no.4
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    • pp.388-392
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    • 2007
  • A new dielectric test on main relays of electric traction vehicles, the partial discharge(PD) test, is proposed. The PD test will not affect the insulation performance of specimen during the test and provide much more detailed information on insulation, the types of defects, and so on. Insulation performance of relays is estimated by discharge inception voltage(DIV), discharge extinction voltage (DEV), and apparent charge as a function of test voltage and time. Three main relays of different manufacturing date were estimated by applying AC voltage with three patterns in ranges of $0{\sim}1,200[V]$. From the results, we could estimate insulation state and which types of defects exist in them.

Development of Silicone coated by Carbon driven PVDF and its anode characteristics for Lithium Battery (전구체로서 PVDF를 이용한 탄소 도포 실리콘 재료의 개발 및 리튬이차전지 음극 특성)

  • Doh, Chil-Hoon;Jeong, Ki-Young;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.350-351
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    • 2005
  • The electrochemical behavior of Si-C material synthesized by heating the mixture of silicon and polyvinylidene fluoride (PVDF). Coin cells of the type 2025 were made using the synthesized material and the electrochemical studies were performed. Si-C/Li cells were made by using the developed Si-C material. Charge/discharge test was performed at 0.1C hour rate. Initial charge and discharge capacities at Si-C material derived from 20 wt.% of PVDF was found to be 1,830 and 526 mAh/g respectively. Initial charge/discharge characteristics of the electrode were analyzed. The level of reversible specific capacity was about 216 mAh/g at Si-C material derived from 20 wt.% of PVDF, IIE, intercalation efficiency at initial charge/discharge, was 68 %. Surface irreversible specific capacity was 31 mAh/g, and average specific resistance was 2.6 ohm*g.

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Study on the Address Discharge Characteristics for the Improvement of the Mis-firing Problem in AC PDP (AC PDP의 오방전 개선을 위한 어드레스 방전 특성 연구)

  • Jeon, Won-Jae;Kim, Dong-Hun;Lee, Seok-Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.6
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    • pp.1151-1156
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    • 2009
  • Unstable sustain discharges can occur at the bottom cells of the panel at high temperature. To solve this problem, the wall charge variation during an address period was investigated. A test panel of 7.5 inch XGA level was used and one green cell was measured. In order to realize operating condition equal to that of the bottom cells of 50 inch panel, the addressing stress pulses are applied. It seems that the resultant wall charge loss during address period increased with increase of stress time, temperature, pressure and Xe %. Wall charge loss increases with potential difference between scan electrode and address electrode, therefore wall charge loss can be minimized by the increase of scan voltage during address period.

Detection of Acoustic Signal Emitted during Degradation of Lithium Ion Battery (리튬이온전지의 열화손상에 의한 음향방출 신호 검출)

  • Choi, Chan-Yang;Byeon, Jai-Won
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.198-204
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    • 2013
  • Acoustic emission(AE) signal was detected during charge and discharge of lithium ion battery to investigate relationships among cumulative count, discharge capacity, and microdamages. AE signal was received during accelerated charge/discharge cycle test of a coin-type commercial battery. A number of AE signals were successfully detected during charge and discharge, respectively. With increasing number of cycle, discharge capacity was decreased and AE cumulative count was observed to increase. Microstructural observation of the decomposed battery after cycle test revealed mechanical damages such as interface delamination and microcracking of the electrodes. These damages were attributed to sources of the detected AE signals. Based on a linear correlation between discharge capacity and cumulative count, feasibility of AE technique for evaluation of battery degradation was suggested.

Relation of X-ray diffraction and charge/discharge capacity Of LiMn$_2$O$_4$ cathode for Lithium ion batteries (리튬 이온 전지용 LiMn$_2$O$_4$ 정극의 X-선 회절 분석과 충방전 용량과의 관계)

  • 정인성;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.347-350
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    • 1998
  • We studied relation of X-ray diffraction and charge/discharge capacity of LiMn$_2$O$_4$ cathode. LiMn$_2$O$_4$ is prepared by reacting stoichiometric mixture of LiOH.$H_2O$ and MnO$_2$ (mole ratio 1 : 2) and heating at $700^{\circ}C$, 80$0^{\circ}C$ for 24hr, 36hr, 48hr, 60hr and 72hr. Through X-ray diffraction pattern, it is analyzed that crystal structure and lattice parameter and peak ratio so on. We obtained X-ray diffraction pattern that varied lattice parameter and peak intensity by function of calcining temperature and time. Cathode active materials calcined at 80$0^{\circ}C$ for 36hr shown that (111)/(311) Peak ratio at X-ray diffraction pattern was 0.37. It means that crystal structure is formed very well in this temperature and time. In the result of charge/discharge test, cathode active material calcined at 80$0^{\circ}C$ for 36hr displayed excellent charge/discharge properties than that of cathode active materials calcined at other temperature and title. In this study, we certified that spinel structure basied cubic is formed very well at 80$0^{\circ}C$ for 36hr. In this case, (111)/(311) peak ratio at X-ray diffraction is 0.37, and charge/discharge properties is excellent than others.

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An Analysis of Damage Mechanism of Semiconductor Devices by ESD Using Field-induced Charged Device Model (유도대전소자모델(FCDM)을 이용한 ESD에 의한 반도체소자의 손상 메커니즘 해석)

  • 김두현;김상렬
    • Journal of the Korean Society of Safety
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    • v.16 no.2
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    • pp.57-62
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    • 2001
  • In order to analyze the mechanism of semiconductor device damages by ESD, this paper adopts a new charged-device model(CDM), field-induced charged nudel(FCDM), simulator that is suitable for rapid routine testing of semiconductor devices and provides a fast and inexpensive test that faithfully represents ESD hazards in plants. The high voltage applied to the device under test is raised by the fie]d of non-contacting electrodes in the FCDM simulator. which avoids premature device stressing and permits a faster test cycle. Discharge current md time are measured and calculated The FCDM simulator places the device at a huh voltage without transferring charge to it, by using a non-contacting electrode. The only charge transfer in the FCMD simulator happens during the discharge. This paper examine the field charging mechanism, measure device thresholds, and analyze failure modes. The FCDM simulator provides a Int and inexpensive test that faithfully represents factory ESD hazards. The damaged devices obtained in the simulator are analyzed and evaluated by SEM Also the results in this paper can be used for to prevent semiconductor devices from ESD hazards.

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A Study on Iron Electrode of Ni/Fe Battery(II) (니켈/철 축전지의 철전극에 관한 연구(II))

  • 김운석;박성용;조원일;조병원;윤경석
    • Journal of Energy Engineering
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    • v.2 no.3
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    • pp.300-307
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    • 1993
  • To develop high performance nickel-iron secondary battery, the characteristics of charge-discharge reaction of iron electrode were examined by cyclic voltammetry technique, SEM and XRD analysis. The capacity of the test electrodes was determined by the constant current charge-discharge method. It was found that the temperature and concentration of electrolyte were the major determinant factors of electrode capacity, and especially the 1st discharge capacity was increased with the increase of temperature. The effect of fore forming agent on the electrode capacity was negligible. The electrode capacity was above 350 ㎃h/g(36% utility) at 0.25C discharge rate. The stability of electrode was very good, but the activation occurred slowly.

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Performance improvement of SOC indicator for electric vehicle using hydrometer (온-라인 비중계를 이용한 전기자동차용 바테리 잔존용량계의 성능개선)

  • 박종건;임영철;박철수;류영재
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.423-426
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    • 1996
  • The conditions to be satisfied with SOC(State-of-Charge) indicator installed on the electric vehicle were that it should be used under frequent loading conditions and that it should enable the monitor to adjust to the aging effect. But, the state-of-charge test requires a lengthy stabilization period after discharge cycles and the ampere-hour test requires the knowledge of the battery capacity in terms of amp-hours. However, a monitoring technique combining the state-of-charge test to enable the monitor to adjust to the aging effect with the ampere-hour test to use under frequent loading condition is studied and implemented on a microcontroller-based circuit in this paper. Specially, optical fiber is used to realize hydrometer which is immune to electromagnetic interference and toxic environment and makes it possible to be used in a wide temperature range.

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