• Title/Summary/Keyword: Changed Energy

Search Result 1,896, Processing Time 0.024 seconds

Synthesis and Investigation of LiVPO4O1-xFxvia Control of the Fluorine Content for Cathode of Lithium-ion Batteries (플루오린 함량 제어를 통한 LiVPO4O1-xFx 합성 및 리튬 이차전지 양극소재 전기화학 특성 분석)

  • Minkyung Kim;Dong-hee Lee;Changyu Yeo;Sooyeon Choi;Chiwon Choi;Hyunmin Yoon
    • Journal of Powder Materials
    • /
    • v.30 no.6
    • /
    • pp.516-520
    • /
    • 2023
  • Highly safe lithium-ion batteries (LIBs) are required for large-scale applications such as electrical vehicles and energy storage systems. A highly stable cathode is essential for the development of safe LIBs. LiFePO4 is one of the most stable cathodes because of its stable structure and strong bonding between P and O. However, it has a lower energy density than lithium transition metal oxides. To investigate the high energy density of phosphate materials, vanadium phosphates were investigated. Vanadium enables multiple redox reactions as well as high redox potentials. LiVPO4O has two redox reactions (V5+/V4+/V3+) but low electrochemical activity. In this study, LiVPO4O is doped with fluorine to improve its electrochemical activity and increase its operational redox potential. With increasing fluorine content in LiVPO4O1-xFx, the local vanadium structure changed as the vanadium oxidation state changed. In addition, the operating potential increased with increasing fluorine content. Thus, it was confirmed that fluorine doping leads to a strong inductive effect and high operating voltage, which helps improve the energy density of the cathode materials.

Estimation of Fundamental Frequency Using an Instantaneous Frequency Based on the Symmetric Higher Order Differential Energy Operator (대칭구조를 갖는 일반적인 고차의 미분 에너지함수를 기반한 순간주파수를 이용한 음성의 기본주파수 추정)

  • Iem, Byeong-Gwan
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.60 no.12
    • /
    • pp.2374-2379
    • /
    • 2011
  • The fundamental frequency of the voiced speech is estimated using the instantaneous frequency based on the symmetric higher order differential energy operator. The instantaneous frequency based on the symmetric higher order energy operator shows better frequency estimation result since it is aligned to the time instance of the signal. The speech is pre-processed by a lowpass filter to remove higher frequency components. Then, it is processed by the instantaneous frequency to obtain the fundamental frequency estimates. The symmetric higher order energy operator has been used as an indicator to determine the voiced/unvoiced speech. The fundamental frequency estimates are further processed by a moving average filter to obtain the monotonically changed estimates. The obtained fundamental frequency estimates have been compared with the spectrogram of the speech to confirm its accuracy.

Microstructure of Laser Surface Melted Ni-Base Alloy 600 after Heat Treatment

  • Lim, Yun-Soo;Cho, Hai-Dong;Kuk, Il-Hiun;Kim, Joung-Soo
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 1998.05b
    • /
    • pp.66-71
    • /
    • 1998
  • A study of treatment effects on laser surface melted Ni-base alloy 600, especially on precipitation behavior ad chemical composition changes on the grain boundary were conducted with microscopic equipments. Long-term aging treatment at 40$0^{\circ}C$ caused no considerable effects on the grain boundary properties. Cr-rich M$_2$$_3$C$_{6}$ and Cr$_{7}$C$_3$ carbides were precipitated and the resultant Cr depletion below 12 wt pct on some high angle grain boundaries was occurred by heat treatment at $600^{\circ}C$ for 24 hours. These results can imply that the resistance of intergranular stress corrosion cracking of heat treated alloy 600 might not be changed considerably in comparion with the as-LSM one.e.e.

  • PDF

A Study on the Properties of Porous Concrete according to Rheological Property of Binder and Compaction Energy (결합재의 유동특성 및 다짐에너지에 따른 포러스콘크리트의 특성에 관한 연구)

  • Lee, Jun;Park, Seong-Bum;Kim, Jeong-Hwan;Kim, Bum-Kyou;Kim, Hyung-Seok
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2004.05a
    • /
    • pp.596-599
    • /
    • 2004
  • The purpose of this study is to investigate properties of porous concrete according to rheological properties of binder and compaction factor. The results of this study, the rheological property of binder is stabilized when a mixing time is over 240 seconds in case of target flow values are $175\%\;and\;200\%$. The void ratio of specimen has a very near value by target void ratio on the whole according as the rheological properties of binder and compaction energy are changed when target flow value is $200\%$, compaction energy is $75kN{\cdot}m/m^2$. The specimen has the excellent compressive strength when compaction energy and target flow value are $100kN{\cdot}m/m^2$ and $200\%$ respectively.

  • PDF

Structural Health Monitoring Based on Wave Propagation Characteristics (파동전파특성에 기초한 구조 건전도 모니터링)

  • Kim, Seung-Joon;Park, Jun-Hong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2007.05a
    • /
    • pp.311-314
    • /
    • 2007
  • The experimental method of measuring dynamic properties of structures was presented. The method is based on the flexural wave propagation characteristics. Using the method, change in structural dynamic properties due to damage is measured. The crack has much more significant impact on the strain energy than the inertial effects. From this, the sensitivity of the dynamic stiffness on the crack location is estimated by calculating the strain energy. When the wave propagates, the strain and kinetic energies shows cyclic changed over space. The crack that occurred at locations where the wave energy is in the form of the potential energy affected most significantly the wave propagation characteristics. The effects of crack location on the wave propagation were used to determine the crack location.

  • PDF

Using reverberation time to evaluate the amount of scattered sound energy from a tree (잔향시간지표를 이용한 나무의 음향확산성 평가)

  • Yang, Hong-Seok
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2014.04a
    • /
    • pp.141-144
    • /
    • 2014
  • In urban spaces surrounded by buildings, trees could disperse sound energy, which affect sound level distribution and street canyon reverberation. Therefore, this paper examines the amount of scattered sound energy from a tree in open field by means of a reverberation time (RT). Five trees of different species and crown sizes were considered. The influential factors include crown size and shape, foliage condition, and source-receiver distance. The results show that RT is proportionally increased with the increase of tree crown sizes, which is the most determining factor. The maximum RT measured was 0.34 sec at 4000 Hz for the studied trees in leaf. The presence of leaves increased RT at high frequencies, typically by 0.14 sec at 4000 Hz. With increasing source-receiver distance within 40 m, RT was slightly changed.

  • PDF

Photovoltaic Solar Energy Conversion : Recent Progress

  • Green, Martin A.
    • Electrical & Electronic Materials
    • /
    • v.11 no.10
    • /
    • pp.100-105
    • /
    • 1998
  • Along with fusion energy, photovoltaic solar energy conversion has long been considered as one of the few sustainable options for large scale energy supply in the future. In the past, commercial use has been restricted largely to remote area applications where conventional electricity is expensive. However, 1998 marked a year of transition where the major application of the cells changed to become generation of residential electricity in urban areas already supplied by the conventional grid. The current state of the technology is discussed as are major overseas programs to accelerate the urban residential use of photovoltaics, particularly in Japan, Europe and the United States, includng the "million roof" program in the latter. Finally, the planned use of photovoltaics in the Sydney 2000 Olympics is described, where the technology will be used to provide most of the electricity requirements of the 665 residences which will be a legacy of the Olympic Village.

  • PDF

Piezoelectric Energy Harvesting Characteristics of GaN Nanowires Prepared by a Magnetic Field-Assisted CVD Process

  • Han, Chan Su;Lee, Tae Hyeon;Kim, Gwang Mook;Lee, Da Yun;Cho, Yong Soo
    • Journal of the Korean Ceramic Society
    • /
    • v.53 no.2
    • /
    • pp.167-170
    • /
    • 2016
  • Various piezoelectric nanostructures have been extensively studied for competitive energy harvesting applications. Here, GaN nanowires grown by a nonconventional magnetic field-assisted chemical vapor deposition process were investigated to characterize the piezoelectric energy harvesting characteristics. As a controlling parameter, only the growth time was changed from 15 min to 90 min to obtain different crystallinity and morphology of the nanowires. Energy harvesting characteristics were found to depend largely on the growth time. A longer growth time tended to lead to an increased output current, which is reasonable when considering the enhanced charge potentials and crystallinity. A maximum output current of ~14.1 nA was obtained for the 90 min-processed nanowires.

A study of the micro power generators with a coil and a magnet using vibration of low frequencies (저 진동수에서 코일과 자석을 이용한 초소형 발전기 연구)

  • Lee, Dong-Ho;Kim, Seong-Il;Lee, Yoon-Pyo;Park, Min-Chul
    • New & Renewable Energy
    • /
    • v.2 no.3
    • /
    • pp.5-9
    • /
    • 2006
  • We have fabricated a micro power generator which changes vibrational energy into useful energy. With vibrating a magnet on the surface of a winding coil, the micro power generator produce alternating voltage. We have changed the vibrational frequency from 0.5Hz to 10Hz. AC voltage of $20{\sim}25mV$ was generated at the frequency of 1Hz. When the vibration was 3Hz, AC voltage of 80mV was obtained. We have rectified and stepped up the input voltage using a quadrupler circuit. The voltage was stepped up to 130mV.

  • PDF

The Study on the Tube Drawing Process with a Floating Plug (프로팅 프러그를 사용한 관재 인발가공에 관한 연구)

  • Choi, Jae-Chan;Jin, In-Tai
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.5 no.4
    • /
    • pp.24-31
    • /
    • 1988
  • The Upper Bound Solution has been used to investigate the effect of the various parameters on the floating-plug tube-drawing precess. A kinematically admissible velocity field considering the change of the tube thickness is proposed for the deformation process. Taking into account the position of the plug in the deforming region, shear energy at entrance and exit, friction energy on contact area, homogeneous energy are calculated. The theoretical values in proposed velocity field are good agreement with experimental values, It is investigated that the tube thickness in the deforming region is changed slightly toward minimization of deforming energy and then the drawing stress in lower than the crawing stress in the velocity field that the tube thickness is uniform.

  • PDF