• Title/Summary/Keyword: Ceramic-polymer film

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Characterization and Evaluation of Porous Vermiculite Containing Polyethylene Composites Film

  • Lee, Hye Sun;Chang, Jeong Ho
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.85-89
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    • 2018
  • This work reported the preparation and evaluation of a freshness-keeping film prepared by composite of a porous ceramic material such as vermiculite and polyethylene polymer. The ceramic material was pretreated physically and chemically to control the specific surface areas and particle size. A high content master-batch was prepared using the pretreated vermiculite. The master-batch, which contained 30% ceramic material, was mixed with a polymer material to prepare a film containing 3% vermiculite. The oxygen permeability and various physicochemical properties were evaluated for the prepared films. Compared to plain polyethylene film, the vermiculite loaded polyethylene film has a freshness maintenance property, indicating the creation of an improved film.

Development of Stretchable PZT/PDMS Nanocomposite Film with CNT Electrode

  • Yun, Ji Sun;Jeong, Young Hun;Nam, Joong-Hee;Cho, Jeong-Ho;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.22 no.6
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    • pp.400-403
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    • 2013
  • The piezoelectric composite film of ferroelectric PZT ceramic ($PbZr_xTi_{1-x}O_3$) and polymer (PDMS, Polydimethylsiloxane) was prepared to improve the flexibility of piezoelectric material. The bar coating method was applied to fabricate flexible nanocomposite film with large surface area by low cost process. In the case of using metal electrode on the composite film, although there is no problem by bending process, the electrode is usually broken away from the film by stretching process. However, the well-attached, flexible CNT electrode on PZT/PDMS film improved flexibility, especially stretchability. PZT particles was usually settled down into polymer matrix due to gravity of the weighty particle, so to improve the dispersion of PZT powder in polymer matrix, small amount of additives (CNT powder, Carbon nanotube powder) was physically mixed with the matrix. By stretching the film, an output voltage of PZT(70 wt%)/PDMS with CNT (0.5 wt%) was measured.

Dielectric Properties of Polymer-ceramic Composites for Embedded Capacitors

  • Yoon, Jung-Rag;Han, Jeong-Woo;Lee, Kyung-Min
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.116-120
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    • 2009
  • Ceramic-polymer composites have been investigated for their suitability as embedded capacitor materials because they combine the processing ability of polymers with the desired dielectric properties of ceramics. This paper discusses the dielectric properties of the ceramic ($BaTiO_3$)-polymer (Epoxy) composition as a function of ceramic particle size at a ceramic loading of 40 vol%. The dielectric constant of these ceramic-polymer composites increases as the powder size decreases. Results show that ceramic-polymer composites have a high dielectric constant associated with the $BaTiO_3$ powder with a 200 nm particle size, high insulation resistance, high breakdown voltage (> 22 KV/mm), and low dielectric loss (0.018-0.024) at 1 MHz.

Preparation and Characterization of Low k Thin Film using a Preceramic Polymer (Preceramic Polymer를 이용한 저유전박막 제조 및 특성 분석)

  • Kim, Jung-Ju;Lee, Jung-Hyun;Lee, Yoon-Joo;Kwon, Woo-Teck;Kim, Soo-Ryong;Choi, Doo-Jin;Kim, Hyung-Sun;Kim, Young-Hee
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.499-503
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    • 2011
  • Recently, variety of organic and inorganic hybrid materials have recently investigated as alternative routes to SiOC, $SiO_2$ thin film formation at low temperatures for applications in electronic ceramics. Specially, silicon based polymers, such as polycarbosilane, polysilane and polysilazane derivatives have been studied for use in electronic ceramics and have been applied as dielectric or insulating materials. In this study, Polycarbosilane(PCS), which Si-$CH_2$-Si bonds build up the backbone of the polymer, has been investigated as low-k materials using a solution process. After heat treatment at 350$^{\circ}C$ under $N_2$ atmosphere, chemical composition and dielectric constant of the thin film were $SiO_{0.27}C_{1.94}$ and 1.2, respectively. Mechanical property measured using nanoindentor shows 1.37 GPa.

Evaluation of Piezoelectric Properties in Pb(Zr1Ti)O3-PVDF Composites for Thick Film Speaker Application (후막 스피커 응용을 위한 Pb(Zr1Ti)O3-PVDF 복합체의 압전 특성 평가)

  • Son Yong-Ho;Kim Sung-Jin;Kim Young-Min;Jeong Joon-Seok;Ryu Sung-Lim;Kweon Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.10
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    • pp.966-970
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    • 2006
  • We reported on characteristics of the piezoelectric ceramic-polymer composite for the application of the thick-film speaker. The PVDF-PZT composites were fabricated to incorporate the advantages of both ceramic and polymer with various mixing ratios by 3-roll mill mixer. The composite solutions were coated by the conventional screen-printing method on ITO electrode coated PET (Polyethylene terephthalate) polymer film. After depositing the top-electrode of silver-paste, 4 kV/mm of DC field was applied at $120^{\circ}C$ for 30 min to poling the composite films. The value of $d_{33}$ (piezoelectric charge constant) was increased when the PZT weight percent was increased. The maximum value of the $d_{33}$ was 24 pC/N at 70 wt% PZT. But the $g{33}$ (piezoelectric voltage constant) showed the maximum value of $32mV{\cdot}m/N$ at 65 wt% of PZT powder. The SPL (sound pressure level) of the speaker fabricated with the 65:35 composite film was about 68 dB at 1 kHz.

Molecular Aligning Properties of a Dielectric Layer of Polymer-Ceramic Nanocomposite for Organic Thin-Film Transistors

  • Kim, Chi-Hwan;Kim, Sung-Jin;Yu, Chang-Jae;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1200-1203
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    • 2004
  • We investigated the molecular aligning capability of a polymer layer containing ceramic nanoparticles which can be used as a gate insulator of organic thin-film transistors (OTFTs). Because of the enhanced dielectric properties arising from the nanoparticles and molecular aligning properties of the polymer, the composite layer provides excellent mobility characteristics of the OTFTs.

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The Influence of Polymers on the Hydration of Modified Cement System (속경형시멘트의 수화거동에서 폴리머의 영향)

  • Park, Phil-Hwan;Lee, Kyoung Hee
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.496-501
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    • 2007
  • The properties of the polymer-modified mortars are influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases. Also, this quality of polymer modified cement strongly depend on weather condition. To overcome this problem, polymer-modified cement based on rapid setting cement mortars were prepared by varying polymer/cement mass ratio (P/C) with a constant water/cement mass ratio of 0.5. The effect of polymer on the hydration of this polymer cement is studied on different curing temperature. The results showed that the polymer mortar which is modified with rapid setting cement have superior physical strength properties on independent curing temperature. In addition the PIC ratio, the compressive strength, flexural strength, tensile strength and adhesion strength of mortar is enhances and polymer-modified cement based on rapid setting cement is more beneficial to the improvement of the mortar properties in jobsite.

Preparation of Silicon Carbide Ceramic Thick Films by Liquid Process (액상공정을 이용한 탄화규소 세라믹 후막의 제조)

  • Kim, Haeng-Man;Kim, Jun-Su;Lee, Hong-Rim;Ahn, Young-Cheol;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.95-99
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    • 2012
  • Silicon carbide ceramics are used for oxidation resistive coating films due to their excellent properties like high strength, good oxidation resistance, and good abrasion resistance, but they have poor formability and are prepared by vapor process which is complicated, costly, and sometimes hazardous. In this study, preparation of silicon carbide coating film by liquid process using polymer precursor was attempted. Coating film was prepared by dip coating on substrate followed by heat treatment in argon at $1200^{\circ}C$. By changing the dipping speed, the thickness was controlled. The effects of plasticizer, binder, or fiber addition on suppression of crack generation in the polymer and ceramic films were examined. It was found that fiber additives was effective for suppressing crack generation.

The Influence of Polymer on the Early Hydration of OPC (시멘트의 초기수화에서 폴리머의 영향)

  • Park, Phil-Hwan;Song, Myong-Sin;Lee, Kyoung-Hee
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.744-749
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    • 2008
  • The properties of the polymer-modified mortars are influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases. Also, this quality of polymer modified cement strongly depend on weather condition and polymer cement ratio. To overcome this problem, polymer-modified cement were prepared by varying polymer/cement mass ratio (P/C) with $0{\sim}20%$ and constant water/cement mass ratio of 0.5. The effect of polymer on the hydration of this polymer cement is studied on different polymer cement ratio. The results showed that the polymer cement paste have increased the viscosity in addition the amount of polymer dosage and the polymers is completed resulting in a reduced degree of hydration caused by different ion elution amount. Also we know that the reactants is calcium acetate as a results of chemical reaction between acetate group in EVA which is hydrolysis in water and $Ca^{2+}$ ion during hydration of cement.