• 한국세라믹학회지
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• 제37권4호
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• pp.302-307
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• 2000

The objective of this study was to investigate the sintering behavior, crystallization characteristic of glass-ceramic and optimal sintering condition on the glass/ceramic composite for fabricating substrate of LTCC. Glass/ceramic composite was made from alumina powder and glass frit, which was composed of SiO2-TiO2-RO-PbO/(R: Ba, Sr, Ca), and was sintered for 0, 30, 60minutes in the temperature range from 700$^{\circ}C$ to 1000$^{\circ}C$. Properties of frit and glass/ceramic compsoite were analyzed by DTA, XRD, SEM and Network Analyzer and so on. Main sintering mechanism was densification occurred above 730$^{\circ}C$ by viscous flow and crystallization starting about 780$^{\circ}C$ affected sintering also. So viscous flow was affected by sintering temperature, duration time, and creation of crystallization phase etc. From this study, it was possible to fabricate glass/ceramic composite by changing sintering temperature and duration time.

• 한국세라믹학회지
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• 제33권2호
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• pp.192-202
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• 1996

In Li0.4Ca0.05AlP0.5Si0.75O4.5 composition glass, glass-ceramic having a near 100% crystallinity after nucleation heat treatment of 74$0^{\circ}C$/2 h and crystallization heat treatment of 90$0^{\circ}C$/2 h and in-situ TiO2 whisker reinforced glass-ceramic after heat treatment of 105$0^{\circ}C$ for 20 h were fabricated with the addition of 4% TiO2 as a nucleating agent. With these materials a ball-on-disc type wear test was conducted in order to examine the effect of TiO2 whisker prepcipitation on ambient and high temperature wear properties of the glass-ceramic. Wear test results indicated that all specimens exhibited micro-fracture wear mechanism in ambient temperature. As temperature increased the wear rates of the materials were increased. However the in-situ TiO2 whisker reinforced glass-ceramic exhibited the lowest wear rate over the test temperature range. This resulted from the improvement of harness and fracture toughness of the material as the glass converted into the glass-ceramic followed by precipitation of TiO2 whiskers throughout the glass-ceramic matrix.

• 한국세라믹학회지
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• 제53권6호
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• pp.700-706
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• 2016

Etch rate, surface roughness and microstructure as plasma resistance were evaluated for six kinds of oxide glass with different compositions. Borosilicate glass (BS) was found to be etched at the highest etch rate and zinc aluminum phosphate glass (ZAP) showed a relatively lower etch rate than borosilicate. On the other hand, the etching rate of calcium aluminosilicate glass (CAS) was measured to be similar to that of sintered alumina while yttrium aluminosilicate glass (YAS) showed the lowest etch rate. Such different etch rates by mixture plasma as a function of glass compositions was dependent on whether or not fluoride compounds were formed on glass and sublimated in high vacuum. Especially, in view that $CaF_2$ and $YF_3$ with high sublimation points were formed on the surface of CAS and YAS glasses, both CAS and YAS glasses were considered to be a good candidate for protective coating materials on the damaged polycrystalline ceramics parts in semi-conductor and display processes.

• 한국전기전자재료학회논문지
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• 제29권2호
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• pp.101-105
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• 2016

The basic characteristics of glass are highly fragile and brittle consequences the ultimate purpose of glass manufacturing is to make a transparent glass with complex shape. In order to solve this problem, mechanical properties of glass can be increased by crystallization of its amorphous glass. However, glass-ceramics has become opaque through crystallization process due to the distracted interface of glass by precipitated particles. This study has been investigated thermal processing conditions of LAS transparent glass-ceramic by using DTA (differential thermal analysis), in order to control size of precipitated particle and then fabricate transparent glass-ceramic. DTA indicated that crystallization peak area was declined with increased nucleation temperature. Subsequently, we have been established optimum temperature for crystallization depending on the nucleation temperature. The transmission and thermal expansion were measured after crystallization, and the size of precipitated particle was identified in range of 20~100 nm by FE-SEM. In addition, by setting the optimized crystallization condition, with high transmission and low thermal expansion glass was synthesized through this experiment.

• 반도체디스플레이기술학회지
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• 제21권1호
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• pp.119-126
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• 2022

MAS-based glass, which has been studied to replace the ceramic material used in the plasma etching chamber, has problems such as forming and processing due to its high melting temperature. To solve this problem, in this study, fluoride was added to the existing MAS-based glass to increase the workability in the glass manufacturing and to improve the chemical resistance to CF₄/Ar/O₂ plasma gas. Through RAMAN analysis, the structural change of the glass according to the addition of fluoride was observed. In addition, it was confirmed that high-temperature viscosity and thermal properties decreased as the fluoride content increased and plasma resistance was maintained, it showed an excellent etching rate of up to 11 times compared to quartz glass.

• 한국재료학회지
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• 제26권5호
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• pp.266-270
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• 2016

Glass-ceramics were developed many years ago and have been applied in many fields such as electronics, chemistry, optics, etc. Much is already known about glass-ceramic technology, but many challenges in glass-ceramic research are still unresolved. Recently, large amounts of slag have steadily increased in the steel industry as by-products. To promote recycling of industrial waste, including steel industry slags, many studies have been performed on the fabrication of basalt-based high-strength glass-ceramics. In this study, we have fabricated such ceramics using various slags to replace high performance cast-basalt, which is currently imported. Glass-ceramic material was prepared in similar chemical compositions with commercial cast-basalt through a pyro process using slags and power plant by-product (Fe-Ni slag, converter slag, dephosphorization slag, Fly ash). The properties of the glass-ceramic material were characterized using DTA, XRD, and FE-SEM; measurements of compressive strength, Vicker's hardness, and abrasion were carefully performed. It is found that the prepared glass-ceramic material showed better performance than that of commercial cast-basalt.

• 한국세라믹학회지
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• 제48권1호
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• pp.26-33
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• 2011

The glass in the system of CaO-$SiO_2-P_2O_5$ and the corresponding glass-ceramics are prepared for bone cements and the behaviors of the hardening and hydroxyapatite formation were studied for the glass and glass-ceramic powders. The glass crystallized into apatite, $\alpha$-wollastonite and $\beta$-wollastonite depending on the glass composition when they were heat-treated at $950^{\circ}C$ for 4 h. A DCPD (dicalcium phosphate dihydrate : $CaHPO_4{\cdot}2H_2O$) was developed when the prepared glass and glass-ceramic powders were mixed with 3M-$H_3PO_4$ solution. The DCPD (Ca/P=1.0) transformed to HAp (Ca/P=1.67) when the bone cement was soaked in simulated body fluid (SBF), and this HAp formation strongly depended on the releasing capacity of $Ca^{2+}$ ions from the glass and glass-ceramic cements. The glass-ceramic bone cement containing $\alpha$-wollastonite crystals showed faster transformation of DCPD to HAp than other glass-ceramics containing $\alpha$- and $\beta$-wollastonite crystals. No hydroxyapatite was observed when the glass-ceramic bone cement containing apatite crystals (36P6C) was soaked in SBF even for 1 month, because no $Ca^{2+}$ ion can be released from the stable apatite crystals.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.555-557
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• 2004

We report the effect of the particle size (D50) and PSD (Particle Size Distribution) of glass frit on the transparency of transparent dielectric layer of PDP. The milling efficiency of wet milling with water was the best among the dry milling, wet milling with IPA and wet milling with water. The transparency increased with the reduction of particle size of glass frit as the milling time increased. Also the transparency changed by the PSD of glass frit. Glass frits of broad PSD showed high transparency compared with the glass frits of sharp PSD.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.558-560
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• 2004

We report the effect of wet ball milling conditions on the transparency of glass frit. Generally, the particle size of glass frit decreased as the milling time increased. And the transparency of glass frit changed with the particle size variation. The transparency of glass frit A increased as the milling time increased. But, the transparency of glass frit B, containing high $B_2O_3$ decreased as the particle size decreased. It seems to be the result of chemical reaction with water and glass frit.

• 한국세라믹학회지
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• 제25권5호
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• pp.431-436
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• 1988

The properties of scid-resistance to boiling HCl, thermal expansion coefficient and softening temperature of mother glass and glass-ceramic of LAS systems were investigated at the contents of SiO2 varing from 57 to 67wt%. The nucleation and growth of crystalline phase of LAS compositions were carried out at 50$0^{\circ}C$ and $700^{\circ}C$. The crystalline phase jconsists of lithium alumino silicate, lithum meta silicate, lithium disilicate, $\alpha$-crystobalite and $\alpha$-quartz. Lithium alumino silicate(virgilite) is the major crystalline phase in the glass ceramics. The degree of acid resistant property was increased in proportion with the silica content for both glass and ceramics. Glass-ceramic gives lower acid-resistance and thermal expansion coefficient while softening temperature shows higher for glass-ceramic than for mother glass.