• Title/Summary/Keyword: Ceramic filler

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Preparation and Dielectrics Properties of Ceramic-polymer Composite Materials (세라믹-폴리머 복합체 제조 및 유전 특성)

  • Park, Myoung-Sung;Myoung, Seong-Jae;Chun, Myoung-Pyo;Jo, Jung-Ho;Nam, Joong-Hee;Kim, Byung-Ik;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.182-183
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    • 2008
  • 본 연구에서는 유전 손실이 낮고, 고분자(LCP)의 유전율을 높이기 위하여 (100-x)LCP(polymer)-xNPO(ceramic) 복합체 (x= 0, 10, 20, 30, 40, 50)의 유전 특성 및 미세구조를 연구하였다. LCP와 ceramic filler(NPO)는 Brabender Mixer를 사용하여 $300^{\circ}C$에서 혼합한 후, Hot press 사용하여 $300^{\circ}C$, 7ton 성형 압력으로 pellet 형태 $(2.5cm\times2.5cm\times0.1cm)$로 제조 하였다. LCP-NPO 복합 소재를 SEM을 통해 미세구조를 관찰하였고, 복합체의 유전 특성을 조사하였다.

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A study on the TIG Autogenous Welding and Filler Material Welding Technology of Brake Lamp for Vehicle (자동차용 제동등의 TIG 제살용접 및 용가재 용접에 관한 연구)

  • Hahn, Chang-Su;Cho, Hyoung-Ki;Kim, Jin-Pyeong;Park, Ho;Kim, Dong-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.771-777
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    • 2006
  • Recently regulations which make it mandatory to use the environment-friendly goods are increaing in automobiles. In this study the TIG autogenous welding process was developed by solving the problem of previous spot welding of side part and the ceramic protection Jig was developed for the welding of fragile glass ball. And the optimal process parameter was selected by complementing the demerit of the previous filler material welding to fill up the bottom part. Finally the lamp aging test and earthquake resistant test was done to check the reliability of welded brake lamp.

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A study on dielectric characteristic of phosphate glass-ceramic for AC-PDP (AC-PDP용 인산염 결정화 유리의 유전적 특성에 관한 연구)

  • Kim, Joon-Hyung;Yon, Seog-Joo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.102-107
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    • 2007
  • Dielectric layer of phosphate glass for plasma display panel (PDP) device made by silk screen printing on soda-lime glass. For regulate thermal expansion coefficient (CTE) of between substrate glass and dielectric layer use addition of $Al_2O_3$ and $TiO_2$. The crystallization process of glass-ceramics for dielectric layer have been examined by DTA, XRD some of optical, electrical properties of the dielectric layer were evaluated by UV-spectrometer, dilatometer, impedance analyser. The principal crystalline phase was identified as zinc metaphosphate [$Zn(PO_3)_2$] and zinc pyrophosphate [$Zn_2P_2O_7$]. Reflectance and dielectric constance increased with the addition of $TiO_2$ filler, dielectric constant lower the out side reflectance unchanging of the adding of $Al_2O_3$ filler. Besides CTE was at about $62{\times}10^{-7}/^{\circ}C$.

Evaluation of Organic-Inorganic Hybrid Insulation Material Using Inorganic Filler and Polyurethane (무기질 충진재와 폴리우레탄을 활용한 유·무기 복합 단열소재의 특성 평가)

  • Lee, Jong-Kyu;Soh, Jung-Sub;Noh, Hyun-Kyung
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.604-608
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    • 2012
  • Recently, inorganic-organic hybrid materials have attracted much attention not only for their excellent thermal conductivity but also for their flame retardant properties. In this study, the properties of organic-inorganic hybrid insulating materials using inorganic fillers and polyurethane foam with different foaming conditions have been investigated. The addition of 1.5 wt% water to polyurethane as foaming agent shows the best foaming properties. The pore size was decreased in the foaming body with increasing of the $CaCO_3$ addition. The apparent density and thermal conductivity were increased by increasing the $CaCO_3$ addition. With an increasing amount of $CaCO_3$ powder, the flame retardant property is improved, but the properties of thermal conductivity and apparent density tend to decrease. When the addition of fine particles of $CaCO_3$, the apparent density and thermal conductivity were increased and, also, with the addition of coarse particles over $45{\mu}m$ in size, the apparent density and thermal conductivity were increased as well. In this study, the adding of $CaCO_3$ with average particle size of $27{\mu}m$ led to the lowest thermal conductivity and apparent density. After evaluation with different inorganic fillers, $Mg(OH)_2$ showed the highest thermal conductivity; on the other hand, $CaCO_3$ showed the lowest thermal conductivity.

Preparation of Transparent Organic-Inorganic Hybrid Hard Coating Films and Physical Properties by the Content of SiO2 or ZrO2 in Their Films (투명 유-무기 하이브리드 하드코팅 필름 제조 및 SiO2 또는 ZrO2함량에 따른 필름의 물성)

  • Seol, Hyun Tae;Na, Ho Seong;Kwon, Dong Joo;Kim, Jung Sup;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.12-18
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    • 2017
  • Transparent organic-inorganic hybrid hard coating films were prepared by the addition of $SiO_2$ or $ZrO_2$, as an inorganic filler to improve the hardness property, filler was highly dispersed in the acrylic resin. To improve the compatibility in the acrylic resin, $SiO_2$ or $ZrO_2$ is surface-modified using various silanes with variation of the modification time and silane content. Depending on the content and kind of the modified inorganic oxide, transparent modified inorganic sols were formulated in acryl resin. Then, the sols were bar coated and cured on PET films to investigate the optical and mechanical properties. The optimized film, which has a modified $ZrO_2$ content of 4 wt% markedly improved in terms of the hardness, haze, and transparency as compared to neat acrylate resin and acrylate resin containing modified $SiO_2$ content of 8 wt%. Meanwhile, the low transparency and high haze of these films slowly appeared at $SiO_2$ content above 10 wt% and $ZrO_2$ content of 5 wt%, but the hardness values were maintained at 2H and 3H, respectively, in comparison with the HB of neat acrylate resin.

The Preparation of Copper Powder Using Solvothermal Process and Its Application as EMI Shielding Agent (솔보써말 방법을 이용한 구리분말 제조 및 전자파 차폐제로의 응용)

  • Lee, Hyo-Won;Kim, Soo-Ryong;Kwon, Woo-Teck;Choi, Duck-Kyun;Kim, Young-Hee
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.285-291
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    • 2006
  • Copper powders have been widely used in electrically conductive coatings, electrode materials et al. and are very prospective since they are cheaper than noble metal powders such as silver or palladium. In this study, copper powders for metal filler of EMI shielding have been prepared using a solvothermal process from $CuSO_4$, NaOH, Glucose, mixed solvent ($H_2O$: Ethanol) and hydrazine which was used as a reducing agent at various reaction conditions. The prepared copper powders showed finely dispersed spherical shape without agglomerate, uniform morphology, narrow size distribution, high purity and were about 400-700 nm in size. The prepared powders were characterized using XRD, SEM, TGA, XPS, particle size measurement and EMI shielding efficiency.

Densification and Dielectric Properties of Ba0.5Sr0.5TiO3-Glass Composites for LTCC Applications

  • Shin, Hyun-Ho;Byun, Tae-Hun;Yoon, Sang-Ok
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.100-104
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    • 2012
  • Barium zincoborate (BZB) glass was added to $Ba_{0.5}Sr_{0.5}TiO_3$, and sintered at $875^{\circ}C$ for 2 h in air. When the BZB glass was added in quantities ranging from 15 to 20 wt%, the relative bulk density ranged from 93.1% to 94.2%, while the density decreased to roughly 81% thereafter up to 30 wt% glass addition. Quantitative XRD analysis showed that the $Ba_{0.5}Sr_{0.5}TiO_3$ filler was significantly dissolved into the BZB glass. However, no secondary phase was identified by XRD up to 30 wt% glass addition. The dielectric constant was about 130 to 140 at 1MHz up to 20 wt% BZB glass addition, while it decreased to about 60 thereafter, which may be ascribed to decreased density, partial dissolution of the $Ba_{0.5}Sr_{0.5}TiO_3$, and associated changes in the glass composition. The dielectric loss of the 20 wt% glass added specimen was 0.008.

Preparation of Glass-like High-density Carbon by Polymerization of Thermosetting Resin (열경화성 수지의 축중합에 의한 고밀도 유리상 탄소의 제조)

  • Kim, Ji-Hyun;Kim, Hee-Seok;Lim, Yun-Soo;Park, Hong-Soo;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.153-159
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    • 2001
  • Due to its low density, good mechanical properties and chemical inertness, glassy carbon(GC) has been studied for appications in several fields. A raw thermosetting resin of furanic resin was polymerized with a curing agent of p-toluenesulfonic acid monohydrate. The maximum yield of GC was obtained at the curing agent content of 1.0 wt% in furanic resin. In order to make thick GC, the affect of graphite filler addition to the furanic resin was investigated. The density and electrical resitivity of GC after graphitization were 1.45 $g/cm^{3}$ and 47 ${\times}10^{-4}$ ${\Omega}$ ${\cdot}$ cm respectively and the amorphous structure of GC was confirmed by XRD profiles with very broad peaks comparable to those of graphite at $206^{\circ}$ and $45^{\circ}$.

Design of a new barrier rib with low dielectric constant and thermal stability

  • Lee, Chung-Yong;Hwang, Seong-Jin;You, Young-Jin;Lee, Sang-Ho;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.725-727
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    • 2009
  • Lowering the dielectric constant is one of the important issues for the efficiency and the power consumption in the plasma display panel (PDP) industry. This study examined the effect of the addition of ceramic filler (up to 10% of crystalline and amorphous silica, respectively) to a $B_2O_3$-ZnO- $P_2O_5$ glass matrix on the dielectric, coefficient of thermal expansion, etching behaviors and residual stress for the barrier ribs in plasma display panels. The dielectric constant of barrier ribs is affected by containing two types of $SiO_2$ filler for the barrier rib composition in PDP.

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Effects of Chemical Composition and Particle Size of Starting Aluminum Source on the Spheroidization in the Flame Fusion Process (화염용융법에 의한 구상 알루미나 제조에 미치는 초기 알루미나 원료의 화학조성과 입도의 영향)

  • Eom, Sun-Hui;Pee, Jae-Hwan;Lee, Jong-Keun;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of Powder Materials
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    • v.16 no.6
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    • pp.431-437
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    • 2009
  • Various inorganic fillers improve the thermal conductivity and physical properties of organic products. Alumina has been used a representative filler in the heat radiation sheet for the heat radiation of electric device. The high filling rate of alumina increases the thermal conductivity and properties of products. We successfully developed the spherical alumina by flame fusion process using the oxygen burner with LPG fuel. In the high temperature flame (2500$\sim$3000$^{\circ}C$) of oxygen burner, sprayed powders were melting and then rotated by carrier gas. This surface melting and rotation process made spherical alumina. Especially effects of chemical composition and particle size of stating materials on the melting behavior of starting materials in the flame and spheroidization ratio were investigated. As a result, spheroidization ratio of boehmite and aluminum hydroxide with endothermic reaction of dehydration process was lower than that of the sintered alumina without dehydration reaction.