• Title/Summary/Keyword: Cement exposure

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Transformation of Asbestos-Containing Slate Using Exothermic Reaction Catalysts and Heat Treatment (발열반응 촉매제와 열처리를 이용한 석면함유 슬레이트의 무해화 연구)

  • Yoon, Sungjun;Jeong, Hyeonyi;Park, Byungno;Kim, Yongun;Kim, Hyesu;Park, Jaebong;Roh, Yul
    • Economic and Environmental Geology
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    • v.52 no.6
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    • pp.627-635
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    • 2019
  • Cement-asbestos slate is the main asbestos containing material. It is a product made by combining 10~20% of asbestos and cement components. Man- and weathering-induced degradation of the cement-asbestos slates makes them a source of dispersion of asbestos fibres and represents a priority cause of concern. When the asbestos enters the human body, it causes cellular damage or deformation, and is not discharged well in vitro, and has been proven to cause diseases such as lung cancer, asbestos, malignant mesothelioma and pleural thickening. The International Agency for Research on Cancer (IARC) has designated asbestos as a group 1 carcinogen. Currently, most of these slats are disposed in a designated landfill, but the landfill capacity is approaching its limit, and there is a potential risk of exposure to the external environment even if it is land-filled. Therefore, this study aimed to exam the possibility of detoxification of asbestos-containing slate by using exothermic reaction and heat treatment. Cement-asbestos slate from the asbestos removal site was used for this experiment. Exothermic catalysts such as calcium chloride(CaCl2), magnesium chloride(MgCl2), sodium hydroxide(NaOH), sodium silicate(Na2SiO3), kaolin[Al2Si2O5(OH)4)], and talc[Mg3Si4O10(OH)2] were used. Six catalysts were applied to the cement-asbestos slate, respectively and then analyzed using TG-DTA. Based on the TG-DTA results, the heat treatment temperature for cement-asbestos slate transformation was determined at 750℃. XRD, SEM-EDS and TEM-EDS analyses were performed on the samples after the six catalysts applied to the slate and heat-treated at 750℃ for 2 hours. It was confirmed that chrysotile[Mg3Si2O5(OH5)] in the cement-asbestos slate was transformed into forsterite (Mg2SiO4) by catalysts and heat treatment. In addition, the change in the shape of minerals was observed by applying a physical force to the slate and the heat treated slate after coating catalysts. As a result, the chrysotile in the cement-asbestos slate maintained fibrous form, but the cement-asbestos slate after heat treatment of applying catalyst was broken into non-fibrous form. Therefore, this study shows the possibility to safely verify the complete transformation of asbestos minerals in this catalyst- and temperature-induced process.

Rapid Corrosion Test on Reinforcing Steels in Chloride-Penetrating Concrete Structures with Various Crack Patterns (염화물 침투 콘크리트의 균열 특성에 관한 철근부식에 관한 연구)

  • 류금성;정영수;유환구;김국한;조창백
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.693-696
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    • 1999
  • Reinforced concrete is, in general, known as high durability construction material under normal environments due to strong alkalinity of cement. It is , however, well known that moderate or minor cracks in reinforced concrete should be most serious causes to deteriorate the durability of RC structures. Furthermore, chloride contents penetrating through unexpected cracks in reinforced concrete bridges get to weaken corrosion resistance of reinforcement steel in concrete and than to accelerate the deterioration of concrete durability. The objective of this experimental research is 1) to evaluate the effect of various corrosion protection system for reinforced concrete specimens with moderate or minor cracks which are exposed to cyclic wet and dry seawater, and then 2) to develop effective corrosion protection system for reinforced concrete bridges under the exposure of various detrimental environments such as seawater, deicing and etc.

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A Study on the Performance Evaluation of Form Using the Aluminum Alloy Frame Reinforced Panel (Aluminum 합금재 Frame을 이용한 벽체거푸집공법의 성능평가에 관한 연구)

  • 안재철;오상균;강병희
    • Journal of the Korea Institute of Building Construction
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    • v.1 no.1
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    • pp.135-142
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    • 2001
  • This study is for the investigation of form using the aluminum-compound metal frame(Aluminum frame reinforced panel : AFR panel) which is improved in the capacity in the wall-concrete structure in steal of using the existing form which has problems such as, excessive exposure of cement, the loss of labor when it is constructed or disjointed, and it's economical efficiency compared with that of EURO Form. AFR panel passes the KS F 8006 test, and as a result of field test, it's displacement is satisfied with Specification. And using AFR panel is more economical than that of EURO Form because saving labor cost which plays a major part in cost saving in formwork is more effective in retrenching total cost than increment of material cost.

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A Case of Root Canal Treatment and Crown Therapy on Fractured Canine Teeth of Lion (골절된 사자 견치의 근관치료 및 Crown 장착 1례)

  • 이기환;신남식;권수완;김양범;이은창;정성목;이충호;김완희;권오경
    • Journal of Veterinary Clinics
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    • v.17 no.1
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    • pp.298-298
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    • 2000
  • Seven years old male lion in Everland Zoo has three fractured canine tooth. To avoid the risk of a possible fracture with pulp exposure after restroration of largest abration defects, endodontic therapy was performed. The pulp chamber was filled with calcium hydroxide, zinc oxide cement and gutta percha. We also installed the Crown prosthesis was installed in fractured canine tooth to protect the tooth and to improve the cosmetics and function of the tooth. The lion could eat in one day and there were no any signs of dental problem. It is the obvious prophylactic procedure for wild animal is the inclusion of an oral examination at every opportunity to handle the animal. It is considered that crown prosthesis after endodontic therapy was useful for maintaining normal physiological function and for provention of additional fracture or complication.

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Rapid Corrosion Test on Reinforcing Steels in Chlordie-Penetrating Structures with Various Crack Patterns (염화물 침투 콘크리트의 균열 특성에 따른 철근 부식에 관한 연구)

  • 류금성;유환구;김국환;이상국;정영수
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.718-723
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    • 2000
  • Reinforced concrete is in general, known as high durability construction material under normal environments due to strong alkalinity of cement. It is, however, well known that moderate or minor cracks in reinforced concrete should be most serious causes to deteriorate the durability of RC structures. Futhermore, chloride contents penetrating through unexpected cracks in reinforced concrete bridges get to weaken corrosion resistance of reinforcement steel in concrete and then to accelerate the deterioration of concrete durability. The objective of this experimental research is 1) to evaluate the effect of various corrosion protection systems for reinforced concrete specimens with moderate or minor cracks which are exposed to cyclic wet and dry seawater, and then 2) to develop effective corrosion protection systems for reinforced concrete bridges under the exposure of various detrimental environments such as seawater, deicing and etc.

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Prediction Model for the Change of Temperature and R.H. inside Reinforced Concrete (철근콘크리트 내부 온습도 경시변화 추정 모델 구축)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.83-84
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    • 2016
  • Surplus water inside a concrete other than moisture that is used for hydration of the cement affects the physical properties of the concrete (modulus of elasticity, compressive strength, drying shrinkage, and creep) by drying. Changes in temperature and humidity inside a concrete has correlation with the movement speed and reaction rate of deterioration factors such as carbon dioxide and chloride ions. In this study, comparison was performed between temperature and relative humidity inside the concrete and meteorological data for exposure environment through measurement at the site for two years. Surface temperature of the concrete (depth 1cm) was measured higher by 6℃ during the summers, while it was measured lower by 2℃ during the winters due to solar radiation, wind, and radiation cooling. As for relative humidity, change was large in the depth of 1cm, while more than 85% was maintained in the depth of 10cm.

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Investigation of Internal Temperature and Relative Humidity of Concrete Immediately After Mix and Placement (양생직후 초기재령의 콘크리트 내부 온도와 상대습도의 측정 및 분석)

  • Park, Cheol-Woo;Park, Young-Hoon;Park, Yong-Gul
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.1065-1068
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    • 2008
  • Concrete is still one most common construction materials even in railway structures. As structures become massive and mega-sized, the importance of early age concrete quality control becomes more significant. Among various factors, relative humidity and temperature are the primary factors governing the early age quality. Temperature raise due to cement hydration causes stress, which can develop to cracking with internal and/or external restraints. Exposure conditions including ambient temperature, humidity and wind also significantly affect the cracking behavior of early age concrete. Among many of studies on the early age concrete behavior, investigation on the variation of temperature and relative humidity internal of concrete is not common. That is in part because the difficulties in measuring the relative humidity and temperature inside the concrete. This study used a digital sensor with an appropriate logger to measure internal temperature and relative humidity. This direct measuring method is expected to provide more reliable and comprehensive data acquisition on the early age behavior of concrete.

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Effect of limestone powder replacement ratio and fineness on high temperature mechanical properties of concrete (석회석 미분말 혼입량과 분말도가 콘크리트의 고온 역학적 특성에 미치는 영향)

  • Choi, Youn sung;Kim, Gyu Yong;Eu, Ha Min;Lee, Yae Chan;Suh, Dong Kyun;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.271-272
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    • 2023
  • In this study, limestone powder used to replace cement at a weight ratio of 10%, 15%, and 20% was tested at 3000, 4000, and 5000 levels of fineness. The mechanical properties of the concrete were investigated before and after exposure to high temperatures (100, 300, and 500℃), and the effects of limestone powder fineness and replacement ratio on the mechanical properties of the concrete were analyzed.

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Evaluation of Chemical Resistance Performance of Synthetic Rubber and Cement Based Injection Repair Materials Used in Underground Concrete Structures (지하 콘크리트 구조물에 적용되는 합성고무계 및 시멘트계 주입형 보수재료의 화학 저항성능평가)

  • Kim, Soo-Yeon;Lee, Yeon-Sil;Song, Je-Young;Kim, Byoungil;Oh, Sang-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.148-155
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    • 2017
  • In this study, by using the international standards ISO TS 16774, Part 2 Test method for chemical resistance as a quality control method of injection type repair material used for leakage crack of underground concrete structure, the performance requirement against of chemical environment of underground concrete structures for repair materials was tested. For this testing 3 types for each of the 2 classes of repair materials(synthetic rubber, cement), with a total of 9 types repair materials, were selected and examined. As a result, the test results showed that the smallest performance deterioration by the change in the mass was with the synthetic rubber(RG) type as opposed to the cement type system, showing that the synthetic rubber type had the strongest relative resistance to chemical exposure. Furthermore, it is necessary to investigate the material with high resistance to chemical substances and to examine the material which can increase resistance to sodium hydroxide and sodium chloride in cement system. These results can be used as a basic index for the selection of repair materials with the strongest resistance to chemical environment found in concrete structures. In addition, it is expected that the test results derived in this study can be used as reference data that can be reflected in the quality improvement of the maintenance material to be developed later.

Shear bond strength between universal adhesives with various pH and dual-cured resin cements (다양한 pH를 가지는 Universal adhesives와 이원 중합 레진 세멘트 간의 전단결합강도)

  • Kwon, Sung-Joo;Park, Jeong-Kil;Son, Sung-Ae
    • Korean Journal of Dental Materials
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    • v.45 no.4
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    • pp.301-310
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    • 2018
  • The purpose of this study is to evaluate the compatibility of universal adhesives with two dual-cured resin cements. Eighty human molars were divided into eight groups. Tooth was embedded in self-curing acrylic resin and sectioned horizontally to exposure dentine surface. After polishing with 600-grit SiC paper, adhesives were applied. All-Bond Universal (Bisco), G-premio bond (GC), Scotch-bond universal (3M ESPE), Scotch-bond Multipurpose (3M ESPE) were used in this study. Calibra (Dentsply) as a conventional dual-curing resin cement and RelyX Ultimate (3M ESPE) as an amine free resin cement were used. The adhesives and the cements were applied according to the manufacturer's instructions. Final specimens were cylinder (diameter 2mm, height 3mm) shape. After storing in distilled water at $37^{\circ}C$ for 7 days the shear bond strength (SBS) test was performed. There was no significant difference in shear bond strength between the adhesives when RelyX Ultimate was used (p>0.05). However, when Calibra used with Scotch-bond Multipurpose and All-Bond Universal were used, statistically higher SBS was observed, as compared to the groups which Calibra cements with G-premio bond and Scotch-bond universal adhesive (p<0.05) were used. Within the limitations of this study, RelyX Ultimate resin cement was compatible with universal adhesives of various pH. All-Bond Universal adhesive was compatible with a resin cement containing the tertiary amine.