• 한국염색가공학회지
• /
• 제18권3호
• /
• pp.1-9
• /
• 2006

In order to dye polyester/cotton blend fabric by one-bath dyeing process with single disperse dye, a novel hetero-bifunctional bridge compound(DBDCBS) was synthesized and utilized. The DBDCBS was designed to contain two different reactive groups such as ${\alpha},{\beta}$-dibromopropionylamido and dichloro-s-triazinyl groups. The ${\alpha},{\beta}$-dibromopropionylamido group shows considerable reactivity towards amines or amino groups at acidic condition and high temperature. In contrast, the dichloro-s-triazinyl group has reactivity towards hydroxyl groups at alkaline condition and room temperature. In order to examine whether as a bridge the compound could combine dyes containing amino groups with cellulosic substrates, disperse dyes containing amino group were tried to dye the cotton fibers pretreated with the DBDCBS compound. By the results, polyester/cotton blends were dyed by one-bath dyeing process with single disperse dye,1,4-diaminoanthraquinone.

• 한국염색가공학회지
• /
• 제14권3호
• /
• pp.34-43
• /
• 2002

Abstract-Many studies have been carried out to improve the dyeability of anionic dyes onto cellulosic fibers. Modification of control using cationic compounds has been most widely used. In this study, an effort was made to cationize cotton fabrics using cellulose-reactive allylamine polymer, namely triazinyl N,N'-dimethyl-N,N'-diallyl ammonium chloride in the previous work. The results showed that the dye-uptake of treated cotton fabrics with acid dyes and reactive dyes markedly increased in the various dyeing conditions. In addition, the dyeing rate of cationized cotton was also faster than that of untreated counterpart. Furthermore, the antimicrobial property was also investigated to determine the effects of cationization.

• 패션비즈니스
• /
• 제12권4호
• /
• pp.131-142
• /
• 2008

One of the major fashion trends is the naturalism and ecology-conscious trend. The natural looks required in the trend require somewhat random distribution of yarn linear density, which results in irregular appearance along the yarn. This is a technically challenging work of producing yarns that look natural far from being artificial yet maintaining the intricately aesthetic randomness without causing process disturbances. This study focused on the characteristics of fabrics made of natural cellulosic fibers including hemp, ramie, flax, and polyester fabrics. Image analysis of the fabric samples included area measurement of yarn specimen, FFT and inverse FFT. Measurements of bending resistance, thickness, air permeability, and weight were also implemented to interpret the structural differences.

• 펄프종이기술
• /
• 제40권4호
• /
• pp.10-15
• /
• 2008

Flocculation phenomena of the stock mixed with cellulosic fibers, fillers and polymers were investigated by a new turbidity measurement system consisted of a probe-type turbidimeter, data acquisition system and computer. The probe-type turbidimeter allowed to measure the real time flocculation of the stock induced by single polymer and microparticle systems. Flocculation phenomena were evaluated by average and final relative turbidity indices. Turbidity and flocculation showed inverse relationship, i.e. the turbidity decreased with the formation of flocs. Relative turbidity of the stock treated with microparticle system was lower than that of the stock containing single polymer system, which indicated that the microparticle system showed greater floc forming efficiency than single polymer system.

• 대한가정학회지
• /
• 제19권4호
• /
• pp.9-15
• /
• 1981

damages of cotton cloth and characteristics of fabroid degradation were studied by Chaetomium globosum and Aspergillus niger which presupposed as powerful erosive fungi to cellulose fiber by means of tensile strength. The results obtained are as follows: 1. the growth(rate) of fungi in malt extract agar was superior to potato agar for two weeks. 2. Chaetomium globosum showed mostly severe damage t the cotton cloth in malt extract agar media at pH 4.5. 3. Tensile strength was reduced with time by Aspergillus niger-coenzyme and Chaetomium globosum-coenzyme reaction. In comparison with Chaetomium globosum and Aspergillus niger, the former weaken tensile strength about 15.8% and the latter enfeebled 10.0% after 124 hours. 4. after 30 days the breeding of fungi in pH 4.5 malt extract agar media, critical damage of cotton cloth was observe, I. e., 92.4% damage by chaetomium globosum and 74.9% lose by aspergillus nige respectively.

• Fibers and Polymers
• /
• 제7권3호
• /
• pp.241-244
• /
• 2006

In this paper, the effect of cellulase treatment was evaluated by means of phenol-sulphuric acid method. This method was performed by determining sugar liberation in the treatment bath with the amount expressed in glucose equivalent. As compared with conventional method, the measurement of amount of sugar liberated gave a more reliable and accurate result than the weight loss method. It was found that although the weight loss of cellulose became negligible when the treatment was done under agitation-free condition, the amount of sugar liberated was still readily measurable.

• 한국생활과학회지
• /
• 제7권2호
• /
• pp.75-80
• /
• 1998

In this paper, deying properties and colorfastness of ramie, flax, and cotton fabrics for direct dyes were compared. When dyed in a same dyeing bath ratio, in case of green dyes, colorfastness to light was similar for three fabrics but in case of red dyes, cotton had a lower level. For colorfastness to laundering, three fabrics were similar and there were no consistent differences. The degree of stain about white fabric cotton was highest in case of red dyes. The degree of stain about white fabric wool showed the high resistance of stain and little stain was seen. This result represented that the used dyes were proper direct dyes for cellulosic fibers. For the difference of shade, the cotton was cosistently brighter and the shade of ramie was darker than of cotton and flax. This might mean that optical effects arouse from the comparatively large cross-sectional size of the ramie fiber and its highly ordered structure.

• 펄프종이기술
• /
• 제42권1호
• /
• pp.41-47
• /
• 2010

Increasing ash content of the paper is one of the most effective methods for saving raw materials and steam consumption and improving optical properties and better print quality. However, the increase of filler loading or filler content using a conventional wet end system is limited due to severe loss in strength properties, affecting runnability and product quality. This is because the filler has no ability to make bonding with cellulosic fibers. Therefore, if the technology to give filler the bonding ability is developed, the ash content of the paper can be increased more than ever. This study was carried out to modify PCC by coating its surface with starch contributing to better bonding with fibers. To prepare the modified PCC, cationic starch was selected as a polymer and then pretreatment was done by mixing PCC and cationic starch. Consequently, the pretreated PCC contributed to higher tensile strength, stiffness and opacity than the conventional filler, such as GCC and untreated PCC. However, CIE whiteness and ISO brightness decreased slightly compared to conventional fillers.

• 펄프종이기술
• /
• 제45권1호
• /
• pp.75-82
• /
• 2013

The traditional Hanji-making was confronted with lots of industrial disadvantages and economic problems, due to the original hand-made process. Recently, the studies on the automation of overall Hanji manufacturing process is carried out by applying the commercial chemical pulping method in order to expand industrial application or efficiency of non-wood fibrous materials. However, the application of commercial pulping methods to the bast tissues of paper mulberry leads to the chemical and mechanical deterioration of cellulosic fibers. In this study, the optimal cooking method using the bast parts of paper mulberry produced by an auto-scraping device was applied to minimize the damage of fiber strength for the paper yarn manufacture. The pre-steaming treatment and alkaline pulping systems were evaluated in removal efficiency of lignin and pectin materials within the bast tissue of paper mulberry. With the application of pre-steaming treatment and 2 stage pulping system using potassium carbonate and then sodium hydroxide, kappa values were decreased two times more in lignin removal than the single stage of pulping method. It was also identified from SEM images and ATR-FTIR spectra that the pectin components within cellular structure of bast tissue were easily removed and the debarked bast parts by a auto-scraping device were easily defiberized by 2-stage pulping sequence using potassium carbonate/sodium hydroxide pulping system.

• 펄프종이기술
• /
• 제34권3호
• /
• pp.17-24
• /
• 2002

An unsteady-state moisture diffusion through cellulosic fibers in paper was characterized from the moisture sorption experiment and the mathematical modeling. The sorption experiment was conducted by exposing thin dry paper specimens to a constant temperature-humidity environment. Oven dried blotting papers and filter papers were used as test samples and the gains of their weights were constantly monitored and recorded as a function of sorption time. For a mathematical approach, the moisture transport was assumed to be an one-dimensional diffusion in thickness direction through the geometrically symmetric structure of paper. The model was asymptotically simplified with a short-term approximation. It gave us a new insight into the moisture uptake phenomena as a function of square root of sorption time. The fiber-phase moisture diffusivities(FPMD) of paper samples were then determined by correlating the experimental data with the unsteady-state diffusion model obtained. Their values were found to be on the order of magnitude of $10^{-6}-10^{-7}cm^2$/min., which were equivalent to the hypothetical effective diffusion coefficients at the limit of zero porosity. The moisture sorption curve predicted from the model fairly agreed with that obtained from the experiment at some limited initial stages of the moisture uptake process. The FPMD value of paper significantly varied depending upon the current moisture content of paper. The mean FPMD was about 0.7-0.8 times as large as the short-term approximated FPMD.