• Title/Summary/Keyword: Cell temperature

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Effect of Cell Size on the High Temperature Oxidation Properties of Fe-Cr-Al Powder Porous Metal Manufactured by Electro-spray Process (정전 분무 공정으로 제조된 Fe-Cr-Al 분말 다공체 금속의 고온 산화 특성에 미치는 기공 크기의 영향)

  • Oh, Jae-Sung;Kong, Young-Min;Kim, Byoung-Kee;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.55-61
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    • 2014
  • Fe-Cr-Al powder porous metal was manufactured by using new electro-spray process. First, ultra-fine fecralloy powders were produced by using the submerged electric wire explosion process. Evenly distributed colloid (0.05~0.5% powders) was dispersed on Polyurethane foam through the electro-spray process. And then degreasing and sintering processes were conduced. In order to examine the effect of cell size ($200{\mu}m$, $450{\mu}m$, $500{\mu}m$) in process, pre-samples were sintered for two hours at temperature of $1450^{\circ}C$, in $H_2$ atmospheres. A 24-hour thermo gravimetric analysis test was conducted at $1000^{\circ}C$ in a 79% $N_2$ + 21% $O_2$ to investigate the high temperature oxidation behavior of powder porous metal. The results of the high temperature oxidation tests showed that oxidation resistance increased with increasing cell size. In the $200{\mu}m$ porous metal with a thinner strut and larger specific surface area, the depletion of the stabilizing elements such as Al and Cr occurred more quickly during the high-temperature oxidation compared with the 450, $500{\mu}m$ porous metals.

Performance Analysis of Off-Gas/Syngas Combustor for Thermal Management of High Temperature Fuel Cell System (고온형 연료전지 열관리를 위한 배기가스 연소기 성능시험)

  • Lee, Sang-Min;Lee, Youn-Hwa;Ahn, Kook-Young;Yu, Sang-Seok
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.3
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    • pp.193-200
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    • 2010
  • Anode off-gas of high temperature fuel cell still contains combustible components such as hydrogen, carbon monoxide and hydrocarbon. In this study, a catalytic combustor has been applied to the high temperature fuel cell so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study is designed to perform the experimental investigation on the combustion characteristics of the three commercial catalysts with a different composition. Screening tests with three catalysts are preceded before the performance examination since it is necessary to determine the most suitable catalyst for design configuration of the catalytic combustor. The performance analysis shows that methane conversion rate strongly depends on gas hourly space velocity (GHSV) as well as inlet gas temperature. Additionally, the GSHV optimization results show that the optimum GHSV will be in the range between 18,000 $hr^{-1}$ and 36,000 $hr^{-1}$. It is also shown that the minimum inlet temperature of catalytic reaction of methane is from $100^{\circ}C$ to $150^{\circ}C$.

Numerical Studies of a Separator for Stack Temperature Control in a Molten Carbonate Fuel Cell (용융탄산염 연료전지 스택 온도 조절을 위한 분리판에 관한 수치 해석 연구)

  • Kim, Do-Hyung;Kim, Beom-Joo;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.305-312
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    • 2011
  • The use of a separator to control stack temperature in a molten carbonate fuel cell was studied by numerical simulation using a computational fluid dynamics code. The stack model assumed steady-state and constant-load operation of a co-flow stack with an external reformer at atmospheric pressure. Representing a conventional cell type, separators with two flow paths, one each for the anode and cathode gas, were simulated under conditions in which the cathode gas was composed of either air and carbon dioxide (case I) or oxygen and carbon dioxide (case II). The results showed that the average cell potential in case II was higher than that in case I due to the higher partial pressures of oxygen and carbon dioxide in the cathode gas. This result indicates that the amount of heat released during the electrochemical reactions was less for case II than for case I under the same load. However, simulated results showed that the maximum stack temperature in case I was lower than that in case II due to a reduction in the total flow rate of the cathode gas. To control the stack temperature and retain a high cell potential, we proposed the use of a separator with three flow paths (case III); two flow paths for the electrodes and a path in the center of the separator for the flow of nitrogen for cooling. The simulated results for case III showed that the average cell potential was similar to that in case II, indicating that the amount of heat released in the stack was similar to that in case II, and that the maximum stack temperature was the lowest of the three cases due to the nitrogen gas flow in the center of the separator. In summary, the simulated results showed that the use of a separator with three flow paths enabled temperature control in a co-flow stack with an external reformer at atmospheric pressure.

A Study of Monitoring and Operation for PEM Water Electrolysis and PEM Fuel Cell Through the Convergence of IoT in Smart Energy Campus Microgrid (스마트에너지캠퍼스 마이크로그리드에서 사물인터넷 융합 PEM 전기분해와 PEM 연료전지 모니터링 및 운영 연구)

  • Chang, Hui Il;Thapa, Prakash
    • Journal of the Korea Convergence Society
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    • v.7 no.6
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    • pp.13-21
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    • 2016
  • In this paper we are trying to explain the effect of temperature on polymer membrane exchange water electrolysis (PEMWE) and polymer membrane exchange fuel cell (PEMFC) simultaneously. A comprehensive studying approach is proposed and applied to a 50Watt PEM fuel cell system in the laboratory. The monitoring process is carried out through wireless LoRa node and gateway network concept. In this experiment, temperature sensor measure the temperature level of electrolyzer, fuel cell stack and $H_2$ storage tank and transmitted the measured value of data to the management control unit (MCU) through the individual node and gateway of each PEMWE and PEMFC. In MCU we can monitor the temperature and its effect on the performance of the fuel cell system and control it to keep the lower heating value to increase the efficiency of the fuel cell system. And we also proposed a mathematical model and operation algorithm for PEMWE and PEMFC. In this model, PEMWE gives higher efficiency at lower heating level where as PEMFC gives higher efficiency at higher heating value. In order to increase the performance of the fuel cell system, we are going to monitor, communicate and control the temperature and pressure of PEMWE and PEMFC by installing these systems in a building of university which is located in the southern part of Korea.

A Study on the Optimization of CP Based Low-temperature Tabbing Process for Fabrication of Thin c-Si Solar Cell Module (박형 태양전지모듈 제작을 위한 저온 CP 공정 최적화에 관한 연구)

  • Jin, Ga-Eon;Song, Hyung-Jun;Go, Seok-Whan;Ju, Young-Chul;Song, Hee-eun;Chang, Hyo-Sik;Kang, Gi-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.37 no.2
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    • pp.77-85
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    • 2017
  • Thin crystalline silicon (C-Si) solar cell is expected to be a low price energy source by decreasing the consumption of Si. However, thin c-Si solar cell entails the bowing and crack issues in high temperature manufacturing process. Thus, the conventional tabbing process, based on high temperature soldering (> $250^{\circ}C$), has difficulties for applying to thin c-Si solar cell modules. In this paper, a conductive paste (CP) based interconnection process has been proposed to fabricate thin c-Si solar cell modules with high production yield, instead of existing soldering materials. To optimize the process condition for CP based interconnection, we compared the performance and stability of modules fabricated under various lamination temperature (120, 150, and $175^{\circ}C$). The power from CP based module is similar to that with conventional tabbing process, as modules are fabricated. However, the output of CP based module laminated at $120^{\circ}C$ decreases significantly (14.1% for Damp heat and 6.1% for thermal cycle) in harsh condition, while the output drops only in 3% in the samples process at $150^{\circ}C$, $175^{\circ}C$. The peel test indicates that the unstable performance of sample laminated at $120^{\circ}C$ is attributed to weak adhesion strength (1.7 N) between cell and ribbon compared to other cases (2.7 N). As a result, optimized lamination temperature for CP based module process is $150^{\circ}C$, considering stability and energy consumption during the fabrication.

Numerical Study of Effects of Operating Conditions on the Performance of High Temperature PEMFC (작동 조건에 따른 고온 고분자 전해질 연료전지의 성능 변화에 대한 전산해석 연구)

  • Kim, Kyoung-Youn;Sohn, Young-Jun;Kim, Min-Jin;Yang, Tae-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.13 no.4
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    • pp.283-289
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    • 2010
  • A two-dimensional isothermal model has been employed for numerical simulations of a high temperature hydrogen fuel cell with proton exchange membrane. The model is validated with existing experimental data and used for examination on the effects of various operating conditions on the fuel cell performance. The present numerical results show that the cell performance increases with increasing exchange current density, ion conductivity of the membrane, inlet gas flow rate as well as operating pressure. Also, higher porosity of gas diffusion layer (GDL) results in higher cell performance due to enhancement of the diffusion through the GDL, where the cathode GDL porosity more influences on the performance as compared with the anode one.

Thin Film (La0.7Sr0.3)0.95MnO3-δ Fabricated by Pulsed Laser Deposition and Its Application as a Solid Oxide Fuel Cell Cathode for Low-Temperature Operation

  • Noh, Ho-Sung;Son, Ji-Won;Lee, Heon;Kim, Hae-Ryoung;Lee, Jong-Ho;Lee, Hae-Weon
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.75-81
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    • 2010
  • The feasibility of using the thin film technology in utilizing lanthanum strontium manganite (LSM) for a solid oxide fuel cell (SOFC) cathode in a low-temperature regime is investigated in this study. Thin film LSM cathodes were fabricated using pulsed laser deposition (PLD) on anode-supported SOFCs with yttria-stabilized zirconia (YSZ) electrolytes. Although cells with a 1 ${\mu}m$-thick LSM cathode showed poor low-temperature cell performance compared to that of a cell with a bulk-processed cathode due to the lack of a triple-phase boundary length, the cell with 200 nm-thick gadolinia-doped ceria (GDC) inserted between the LSM and YSZ showed enhanced performance and more stable operation characteristics in a comparison of a cell without a GDC layer. We postulate that the GDC layer likely improved the cathode adhesion, therefore contributing to the improvement of the cell performance instead of serving as an interfacial reaction buffer.

Study on Reliability of Vapor Cell by Laser Packaging with Au/Au-Sn Heterojunction (Au/Au-Sn 이종접합 적용 레이저 패키징을 통한 Vapor Cell 신뢰성 연구)

  • Kwon, Jin Gu;Jeon, Yong Min;Kim, Ji Young;Lee, Eun Byeol;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.367-372
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    • 2020
  • As packaging processes for atomic gyroscope vapor cells, the glass tube tip-off process, anodic bonding, and paste sealing have been widely studied. However, there are stability issues in the alkali metal which are caused by impurity elements and leakage during high-temperature processes. In this study, we investigated the applicability of a vapor cell low-temperature packaging process by depositing Au on a Pyrex cell in addition to forming an Au-Sn thin film on a cap to cover the cell, followed by laser irradiation of the Au/Au-Sn interface. The mechanism of the thin film bonding was evaluated by XRD, while the packaging reliability of an Ne gas-filled vapor cell was characterized by variation of plasma discharge behavior with time. Furthermore, we confirmed that the Rb alkaline metal inside the vapor cell showed no color change, indicating no oxidation occurred during the process.

A study of Comparative Analysis of CPV and PV Module through Long-term Outdoor Testing (장기 Outdoor Test를 통한 CPV와 PV 모듈의 발전량 비교분석)

  • Kim, Minsu;Lee, Yuri;Cho, Minje;Oh, Soo Young;Jung, Jae Hak
    • Current Photovoltaic Research
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    • v.5 no.1
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    • pp.33-37
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    • 2017
  • Today, photovoltaic power generation mostly uses Si crystalline solar cell modules. The most vulnerable part of the Si solar cell module is that the power generation decreases due to the temperature rise. But, it is widely used because of low installation cost. In the solar market, where Si crystalline solar cell modules are widely used. The CPV (Concentrated Photovoltaic) module appeared in the solar market. The CPV module reduces the manufacturing cost of the solar cell by using non-Si in the solar cell. Also, there is an advantage that a rise in temperature does not cause a drop in power generation. But this requires high technology to install and has a disadvantage that the initial installation cost is expensive compared to normal Si solar cell module. So that we built a testbed to see these characteristics. The testbed was used to measure the amount of power generation in a long-term outdoor environment and compared with the general Si solar cell module.

Effects of the Methanol Concentration, Wind Velocity and Stack Temperature on the performance of Direct Methanol Fuel Cell (직접 메탄올 연료 전지의 성능에 대한 메탄올 농도, 풍속 및 스택 온도의 영향)

  • Kim, Yong-Ha;Kim, Seok-Il
    • Journal of Aerospace System Engineering
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    • v.1 no.2
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    • pp.21-26
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    • 2007
  • DMFC(Direct Methanol Fuel Cell) has been considered as an attractive option to produce electric power in many application. In this study, in order to estimate the effects of the methanol concentration, wind velocity and temperature on the performance of DMFC, a physical prototype of DMFC was designed and manufactured, and the stack voltage of DMFC was measured during the operation of DMFC. Expecially, the experimental results showed that a low stack temperature, a low wind velocity and an excess methanol concentration lead to the increase of the time to reach the maximum stack voltage.

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