• 제목/요약/키워드: Cell surface properties

검색결과 774건 처리시간 0.034초

펄스 레이저 증착법으로 layer-by-layer 성장시킨 $YBa_{2}Cu_{3}O_{7}$ 박막의 초전도특성 (Superconducting properties of layer-by-layer grown $YBa_{2}Cu_{3}O_{7}$ thin film prepared by pulsed laser deposition)

  • 김인선;임해용;김동호;박용기;박종철
    • 센서학회지
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    • 제7권1호
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    • pp.61-66
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    • 1998
  • C-축으로 배향된 고품질 $YBa_{2}Cu_{3}O_{7}$ 박막을 펄스레이저 증착법으로 $SrTiO_{3}$(100) 기판위에 제작하였다. STO 기판을 고온 산소열처리로 원시세포 높이의 테라스가 발달한 atomic-flat한 표면상태로 가공하였으며, 이 기판위에 최적의 조건에서 증착된 $YBa_{2}Cu_{3}O_{7}$ 박막은 원시세포단위로 층상으로 적층 성장됨을 알 수 있었다. 이러한 박막은 임계온도${\ge}90$ K, 전이폭${\le}0.6$ K, 상온비저항${\sim}300{\mu}{\Omega}cm$, 잔류저항${\sim}0$ 및 임계전류밀도${\sim}4.6{\times}10^{6}A/cm^{2} $의 초전도 특성을 나타내었다.

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Trans-differentiation Induction of Human-mesenchymal Stem Cells Derived from Different Tissue Origin and Evaluation of their Potential for Differentiation into Corneal Epithelial-like Cells

  • Moon, Sun-Woung;Lee, Hyeon-Jeong;Lee, Won-Jae;Ock, Sun-A;Lee, Sung-Lim
    • 한국수정란이식학회지
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    • 제33권2호
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    • pp.85-97
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    • 2018
  • The trans-differentiation potential of mesenchymal stem cells (MSCs) is employed, but there is little understanding of the cell source-dependent trans-differentiation potential of MSCs into corneal epithelial cells. In the present study, we induced trans-differentiation of MSCs derived from umbilical cord matrix (UCM-MSCs) and from dental tissue (D-MSCs), and we comparatively evaluated the in vitro trans-differentiation properties of both MSCs into corneal epithelial-like cells. Specific cell surface markers of MSC (CD44, CD73, CD90, and CD105) were detected in both UCM-MSCs and D-MSCs, but MHCII and CD119 were significantly lower (P < 0.05) in UCM-MSCs than in D-MSCs. In UCM-MSCs, not only expression levels of Oct3/4 and Nanog but also proliferation ability were significantly higher (P < 0.05) than in D-MSCs. In vitro differentiation abilities into adipocytes and osteocytes were confirmed for both MSCs. UCM-MSCs and D-MSCs were successfully trans-differentiated into corneal epithelial cells, and expression of lineage-specific markers (Cytokeratin-3, -8, and -12) were confirmed in both MSCs using immunofluorescence staining and qRT-PCR analysis. In particular, the differentiation capacity of UCM-MSCs into corneal epithelial cells was significantly higher (P < 0.05) than that of D-MSCs. In conclusion, UCM-MSCs have higher differentiation potential into corneal epithelial-like cells and have lower expression of CD119 and MHC class II than D-MSCs, which makes them a better source for the treatment of corneal opacity.

한외여과막을 이용한 자동차 세척배수의 처리 (Ultrafiltration Treatment for Car Washing Effluent)

  • 장규만
    • 멤브레인
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    • 제9권4호
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    • pp.202-208
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    • 1999
  • 오일과 세척제가 다량함유되어 있는 자동차 세척배수를 한외여과막으로 처리하였다 세차배수 처리에 적절한 분리막과 투과현상을 평가하기 위하여 분획분자량이 10, 30 및 100k dalton인 한회여과막과 dead-end 방식의 stirred cell (Amicon 8050)을 사용하여 투과유고과 제거율을 측정하였다 분획분자량이 작은 막에 경우 막오염현상이 미약하였으나 분획분자량이 큰 YM100 (100k dalton)인 경우에는 분리막 표면에 오일층을 형성 뿐만 아니라 막 세공 중 일부는 운전압력 조건에 따라서 변형이 가능한 오일 입자가 막을 가능성이 있다 그러나 오일 및 입자 배제율 95% 이상이며 세척제를 포함한 투과수를 재활용할 수 있어 수질오염을 최소화할 수 있을 것으로 판단된다. 또한 분획분자량이 50k dalton인 중공사형 한외여과막을 이용한 세차배수의 연속적 처리실험을 하였으며 케이크 여과모델이 잘 적용굄을 확인할수하였다.

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반투명 태양전지용 Al-Ti계 산화물 박막의 반사율 특성 개선에 관한 연구 (Study on Reflectance Improvement of Al-Ti Based Oxide Thin Films for Semitransparent Solar Cell Applications)

  • 이은규;정소운;방기수;이승윤
    • 한국전기전자재료학회논문지
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    • 제31권7호
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    • pp.437-442
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    • 2018
  • This work reports the preparation of Al-Ti based oxide thin films and their optical properties. Although the transmittance of a $TiO_2/Al2O_3$ bilayer structure was as high as 90% at wavelengths of 600 nm or larger, the reflectance of the bilayer reached its minimum at wavelengths of around 360 nm. The transmittance of an 89-nm-thick $TiO_2$ thin film rapidly increased and then decreased at a critical wavelength because of destructive interference. The wavelength corresponding to the reflectance minimum increased after an increase in $TiO_2$ film thickness. The smooth surface morphology of the AlTiO thin film was retained up to a film thickness of 65 nm, and the transmittance of the film was inversely proportional to film thickness, in accordance with the general tendency for optical films. The reflectance of the AlTiO film at visible light wavelengths was lower than that of the $TiO_2$ film, which implies that the AlTiO film is suitable for applications as an optical thin film layer in semitransparent solar cells.

삼상 계면대에서 활성 탄소섬유로 된 연료전지 전극의 흡착 특성 (Adsorption Properties of Fuel-Cell Electrode Produced from Activated Carbon Fibers in Three Phase Distribution)

  • 박수진;정효진;나창운
    • 폴리머
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    • 제27권1호
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    • pp.46-51
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    • 2003
  • 본 연구에서는 적절한 반응 삼상 계면대를 형성하기 위해서 카본블랙과 활성 탄소섬유를 혼합하여 연료전지의 전극을 제조하고, 전극 삼상 계면대의 변화를 고찰하였다. 활성 탄소섬유의 직량비에 따른 백금의 담지량과 백금 입자크기는 각각 원자흡광분석기와 X-선 회절기를 사용하여 분석하였다. 또한 비표면적( $S_{BET}$), 미세기공도 및 기공크기분포(PSD)를 포함하는 전극의 기공구조는 BET를 이용하연 고찰하였으며, 주사전자현미경을 이용하여 전극 삼상 계면대의 형태를 관찰하였다. 실험 결과, 백금의 담지율은 활성 탄소섬유의 첨가에는 큰 영향을 받지 않았다. 반면에, 전극 삼상 계면대는 30% 활성 탄소섬유를 카본블랙에 첨가하였을 경우 더 향상되었는데 이는 촉매의 활성점을 제공하는 미세기공 영역이 증가하였기 때문으로 사료된다.다.

H2S tolerance effects of Ce0.8Sm0.2O2-δ modification on Sr0.92Y0.08Ti1-xNixO3-δ anode in solid oxide fuel cells

  • Kim, Kab In;Kim, Hee Su;Kim, Hyung Soon;Yun, Jeong Woo
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.187-195
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    • 2018
  • $Sr_{0.92}Y_{0.08}Ti_{1-x}Ni_xO_{3-{\delta}}$ (SYTN) was investigated in the presence of $H_2S$ containing fuels to assess the feasibility of employing oxide materials as alternative anodes. Aliovalent substitution of $Ni^{2+}$ into $Ti^{4+}$ increased the ionic conductivity of perovskite, leading to improved electrochemical performance of the SYTN anode. The maximum power densities were 32.4 and $45.3mW/cm^2$ in $H_2$ at $900^{\circ}C$ for the SYT anode and the SYTN anode, respectively. However, the maximum power densities in 300 ppm of $H_2S$ decreased by 7% and by 46% in the SYT and the SYTN anodes, respectively. To enhance the sulfur tolerance and to improve the electrochemical properties, the surface of SYTN anode was modified with samarium doped ceria (SDC) using the sol-gel coating method. For the SDC-modified SYTN anode, the cell performance was mostly recovered in the pure $H_2$ condition after 500-ppm $H_2S$ exposure in contrast to the irreversible cell performance degradation exhibited in the unmodified SYTN anode.

Characteristics of Sr2Ni1.8Mo0.2O6-δ Anode for Utilization in Methane Fuel Conditions in Solid Oxide Fuel Cells

  • Kim, Jun Ho;Yun, Jeong Woo
    • Journal of Electrochemical Science and Technology
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    • 제10권3호
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    • pp.335-343
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    • 2019
  • In this study, $Sr_2Ni_{1.8}Mo_{0.2}O_{6-{\delta}}$ (SNM) with a double perovskite structure was investigated as an alternative anode for use in the $CH_4$ fuel in solid oxide fuel cells. SNM demonstrates a double perovskite phase over $600^{\circ}C$ and marginal crystallization at higher temperatures. The Ni nanoparticles were exsolved from the SNM anode during the fabrication process. As the SNM anode demonstrates poor electrochemical and electro-catalytic properties in the $H_2$ and $CH_4$ fuels, it was modified by applying a samarium-doped ceria (SDC) coating on its surface to improve the cell performance. As a result of this SDC modification, the cell performance improved from $39.4mW/cm^2$ to $117.7mW/cm^2$ in $H_2$ and from $15.9mW/cm^2$ to $66.6mW/cm^2$ in $CH_4$ at $850^{\circ}C$. The mixed ionic and electronic conductive property of the SDC provided electrochemical oxidation sites that are beyond the triple boundary phase sites in the SNM anode. In addition, the carbon deposition on the SDC thin layer was minimized due to the SDC's excellent oxygen ion conductivity.

The Expression of Immunomodulation-Related Cytokines and Genes of Adipose- and Bone Marrow-Derived Human Mesenchymal Stromal Cells from Early to Late Passages

  • Mun, Chin Hee;Kang, Mi-Il;Shin, Yong Dae;Kim, Yeseul;Park, Yong-Beom
    • Tissue Engineering and Regenerative Medicine
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    • 제15권6호
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    • pp.771-779
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    • 2018
  • BACKGROUND: Mesenchymal stromal cells (MSCs) are multipotent stem cells that can differentiate into several cell types. In addition, many studies have shown that MSCs modulate the immune response. However, little information is currently available regarding the maintenance of immunomodulatory characteristics of MSCs through passages. Therefore, we investigated and compared cytokine and gene expression levels from adipose (AD) and bone marrow (BM)-derived MSCs relevant to immune modulation from early to late passages. METHODS: MSC immunophenotype, growth characteristics, cytokine expressions, and gene expressions were analyzed. RESULTS: AD-MSCs and BM-MSCs had similar cell morphologies and surface marker expressions from passage 4 to passage 10. Cytokines secreted by AD-MSCs and BM-MSCs were similar from early to late passages. AD-MSCs and BM-MSCs showed similar immunomodulatory properties in terms of cytokine secretion levels. However, the gene expressions of tumor necrosis factor-stimulated gene (TSG)-6 and human leukocyte antigen (HLA)-G were decreased and gene expressions of galectin-1 and -3 were increased in both AD- and BM-MSCs with repeated passages. CONCLUSION: Our study showed that the immunophenotype and expression of immunomodulation-related cytokines of AD-MSCs and BM-MSCs immunomodulation through the passages were not significantly different, even though the gene expressions of both MSCs were different.

Improved Efficiency by Insertion of TiO2 Interfacial Layer in the Bilayer Solar Cells

  • Xie, Lin;Yoon, Soyeon;Kim, Kyungkon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.432.1-432.1
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    • 2016
  • We demonstrated that the power conversion efficiency (PCE) of bilayer solar cell was significantly enhanced by inserting interfacial layer between the organic bilayer film and the Al electrode. Moreover, the water contact angle shows that the bilayer solar cells suffer from the undesirable surface component which limits the charge transport to the Al electrode. The AFM measurement has revealed that the pre- and post-thermal annealing treatments results in different morphologies of the interfacial layer which is critical for the higher PCE of the bilayer solar cells. Furthermore we have investigated the electrical properties of the bilayer solar cells and obtained insights into the detailed device mechanisms. The transient photovoltage measurements suggests that the significantly enhanced Voc is caused by reducing the recombination at the interface between the organic films and the Al electrode. By inserting the TiO2 layer between the bilayer film and Al electrode, the open circuit voltage (Voc) was increased from 0.37 to 0.66V. Consequently, the power conversion efficiency (PCE) of bilayer solar cells was significantly enhanced from 1.23% to 3.71%. As the results, the TiO2 interfacial layer can be used to form an ohmic contact layer, serveing as a blocking layer to prevent the penetration of the Al, and to reduce the recombination at the interface.

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OKAYAMA PLANET SEARCH PROGRAM

  • SATO BUN'EI
    • 천문학회지
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    • 제38권2호
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    • pp.315-318
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    • 2005
  • We have carried out a precise Doppler survey of G-type giants aiming to unveil the properties of planetary systems in intermediate-mass stars ($1.5-5M_{\bigodot}$). G-type giants are promising targets for Doppler planet searches around massive stars, because they are slow-rotators and have many sharp absorption lines in their spectra and their surface activities are relatively low in contrast to their younger counterparts on the main-sequence (B-A stars). We are now monitoring radial velocities of about 300 late G-type (including early K-type) giants using HIgh Dispersion Echelle Spectrograph (HIDES) at Okayama Astrophysical Observatory. We have achieved a Doppler precision of about 6-7 m/s over a time span of 3 years using an iodine absorption cell. We found that most of the targets have radial velocity scatters of ${\sigma}{\~} 10-20 m\;s^{-1}$ over 1-3 years, with the most stable reaching levels of 6-8 m $s^{-1}$. Up to now, we have succeeded in discovering the first extrasolar planet around a G-type giant star HD 104985, and also found several candidates showing significant radial velocity variations, suggesting the existence of stellar and substellar companions. Observations have continued to establish their variability.