• 제목/요약/키워드: Catalyst management

Search Result 100, Processing Time 0.022 seconds

Modification of Asphalt by in-situ Polymerization (내부중합에 의한 아스팔트바인더 개질 연구)

  • Lee, Sang-Yum;Mun, Sung-Ho;Jin, Jung-Hoon;Hong, Young-Keun
    • Elastomers and Composites
    • /
    • v.46 no.3
    • /
    • pp.257-261
    • /
    • 2011
  • We introduce a novel method that could modify neat asphalt. A polymer-forming monomer, dimethylphenol( DMP) was added to the neat asphalt and polymerization was occurred autonomously, without adding any external catalyst for the polymerization, only with oxygen molecules in the air. The polymer produced in the asphalt was polyphenyleneoxide( PPO) and it enhanced the mechanical properties of the asphalt. Compared with the neat asphalt, the tenacity and toughness of the DMP-modified asphalt were two and half times and three times high, respectively.

A Study on the Influence of the Packaging System-related Institutional Approach on Logistics Efficiency (Focusing on Retail Ready Packaging System)

  • Jung, Sung-Tae
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
    • /
    • v.26 no.3
    • /
    • pp.155-163
    • /
    • 2020
  • This paper conducted a study on the operation plan of the packaging system to enhance the logistics efficiency between the manufacturer and the distributor, whose prior research in the relevant field was insignificant. By identifying problems and improvements in the operation of the packaging system between domestic manufacturers and distributors through the Retail Ready Packaging. The institutional aspects were investigated to confirm that the mediation role of government and social organizations was required to resolve issues (χ2 = 148.916, p < 0.001), and that guidelines that gathered diverse opinions for the rational operation of the packaging system were essential, while institutional aspects are needed to be supplemented to be willing to improve logistics efficiency (χ2 = 95.781, p < 0.001). In this study, even though the difference in perception between manufacturers and distributors is clear and the issue related to the operation of the packaging system is ongoing, if there is no effort to grasp the issue, the opinions between manufacturers and distributors will be left at odds and could become a social problem. Unnecessary interference from government and social organizations should be excluded, but the level of mediation to support win-win management in order to promote logistics standardization and reduce CO2 and national logistics costs can be explained as a catalyst for improving logistics efficiency through reasonable operation of the packaging system.

Experimental and Numerical Assessment of the Effects of Various Coolant Temperature in Gasoline Vehicle on Fuel Consumption and Emissions (냉각수온 변화가 가솔린 차량의 연비 및 배출가스에 미치는 영향에 관한 실험 및 수치적 평가)

  • Jeong, SooJin;Kim, SeoKyu;Lee, GumSu;Jeong, Jinwoo;Kim, MyungHwan
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.25 no.3
    • /
    • pp.297-308
    • /
    • 2017
  • One of the major engine thermal management system(TMS) strategies for improving fuel economy is to operate the engine in high temperatures. Therefore, this work performed a numerical and experimental study to examine the effect of several different STOs(Starting Temperature of Opening) of wax-thermostat, ranging from $85^{\circ}C$ to $105^{\circ}C$, of gasoline engine on fuel economy and emission characteristics. In this study, a gasoline car equipped with waxthermostat was tested and simulated under FTP-75 and HWFET mode. CRUISE $M^{TM}$ was used to simulate vehicle dynamics, transient engine performance and TMS. The test results showed fuel savings for both drive cycles due to higher STO of $100^{\circ}C$, which is slightly worse than that of $90^{\circ}C$ and amounts between 0.34 and 0.475 %. These controversial results are attributed to experimental errors and uncertainty. The computational results for three STOs, $85^{\circ}C$, $95^{\circ}C$ and $105^{\circ}C$, showed that fuel savings attributed to the application of higher STOs of $95^{\circ}C$ and $105^{\circ}C$ are relatively small and range from 0.306 to 0.363 %. It is also found that the amount of HC and CO emissions from the tailpipe tends to decrease with higher engine coolant temperature because of faster catalyst light-off and improved combustion.

Adsorptive Desulfurization of Diesel for Fuel Cell Applications: A Screening Test

  • Ho, Hoang Phuoc;Kim, Woo Hyeong;Lee, So-Yun;Son, Hong-Rok;Kim, Nak Hyeon;Kim, Jae-Kon;Park, Jo-Yong;Woo, Hee Chul
    • Clean Technology
    • /
    • v.20 no.1
    • /
    • pp.88-94
    • /
    • 2014
  • During the past decades much attention has been paid to the desulfurization of diesel oil which is important as a source for the fuel cells to prevent the sulfur poisoning of both diesel steam reforming catalyst and electrode of fuel cell. Although alternative desulfurization techniques have been investigated, desulfurization for ultra-low sulfur diesel (ULSD) is still challenged. Therefore, this research focuses on the desulfurization of commercial ULSD for the application to molten carbonate fuel cell (MCFC). Herein, the performances of several kinds of commercial adsorbents based on activated carbons, zeolites, and metal oxides for desulfurization of ULSD were screened. The results showed that metal oxides based materials can feasibly reduce sulfur concentration in ULSD to a level of 0.1 ppmw while activated carbons and zeolites did not reach this level at current conditions.

A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions (Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구)

  • Kim, Dayoung;Hwang, Myungwhan;Woo, Insung
    • Journal of the Korea Safety Management & Science
    • /
    • v.16 no.2
    • /
    • pp.237-246
    • /
    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.

A Study on Catalytic Process in Pilot Plant for Abatement of PFC Emission (PFC 배출 저감을 위한 파일롯 규모 촉매 공정 연구)

  • Lee, Young-Chun;Jeon, Jong-Ki
    • Clean Technology
    • /
    • v.18 no.2
    • /
    • pp.216-220
    • /
    • 2012
  • The objective of the present study was to evaluate catalytic performance of a commercial catalyst (Co/$ZrO_2-Al_2O_3$) for the decomposition of perfluorinated chemicals in a pilot scale reactor containing 30 L of catalysts. At a reaction condition of GHSV $1,800h^{-1}$, $T_{95}$ of $SF_6$ was increased from 580 to $610^{\circ}C$ with increasing of $SF_6$ concentration from 1,000 to 10,000 ppm. $T_{95}$ of $SF_6$ in catalytic decomposition was much smaller than that of thermal decomposition ($1,600^{\circ}C$). The 99% conversion of $SF_6$ was maintained for 72 hours a reaction temperature of $650^{\circ}C$. In order to maintain the $SF_6$ conversion more than 99%, it is necessary to operate at a reaction condition of GHSV less than $2,000h^{-1}$. An operating temperature of $710^{\circ}C$ was required to achieve >95% destruction of the $CF_4$, which was much higher than that of catalytic decomposition of $SF_6$.

Synthesis of Amino-type Anion Exchanger from Acrylic Acid Grafted Polypropylene Nonwoven Fabric and Its Ion-Exchange Property (아크릴산 그라프트 폴리프로필렌 부직포로부터 아민형 음이온 교환체의 합성 및 이온교환특성(I))

  • Park, Hyun-Ju;Na, Choon-Ki
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.5
    • /
    • pp.527-534
    • /
    • 2006
  • The purpose of this study is the development of more effective filter-type polymer adsorbent for removal of anionic pollutants from wastewater. In order to synthesize the polymer adsorbent that possesses anionic exchangeable function, carboxyl(-COOH) group of PP-g-AA nonwoven fabric was converted into amine($-NH_2$) group by the chemical modification using diethylene triamine(DETA). FT-IR data indicate that amine group was introduced into PP-g-AA through amidation of grafted acrylic acid by reaction with DETA. The degree of amination increased with increase in the reaction time and temperature of the chemical modification process, and was significantly improved by the pre-swelling treatment of PP-g-AA with solvent and addition of metal chlorides as a catalyst in following order as $NH_4OH>MeOH{\geq}HCl{\geq}H_2O\;and\;AlCl_3>FeCl_3{\geq}SnCl_2{\gg}ZnCl_2{\geq}FeCl_2$, respectively. However, the addition of catalyst limited the reusability of DETA, hence was less useful from the viewpoint of cost effectiveness and waste management. The anion exchange capacity of the aminated PP-g-AA(PP-g-AA-Am) increased with increase in the degree of amination, but it reached maximum value at the degree of amination as about $50{\sim}60%$. The anion exchange capacity of PP-g-AA-Am was higher than those of commercial anion resins.

A Study of the Giftedness Expression Mechanism of Young-sil Jang through Gagne's DMGT Model (Gagne의 DMGT 모형을 통한 장영실의 영재성 발현 기제 연구)

  • Ji-Young Choi;Dong-Hyun Chea
    • Journal of the Korean Society of Earth Science Education
    • /
    • v.16 no.2
    • /
    • pp.234-246
    • /
    • 2023
  • This study uses Gagne's 'Differentiated Model of Giftedness and Talent (DMGT)' to collect and extract major life events of Jang Young-sil, and to investigate how giftedness was formed and developed in his life history, and what factors enabled him to demonstrate his talent in the field of science and technology. In addition, based on the framework of Gagne's Differentiation Model for Giftedness and Talent(DMGT), we analyzed the mechanism of giftedness manifestation of Jang Young-sil and sought to explore the direction of gifted education based on this. To sum up the results of the study, first, in Giftedness(G), it was found that Jang Young-sil had excellent scientific and technological skills. Second, motivation, determination, self-management, and personality factors that constitute the inner catalyst(IC) of the individual have had an impact on the development of giftedness. Third, it influenced the social environment and peer giftedness in environmental catalysis(EC). Fourth, the catalyst of chance or chance(C) was the factor that had the greatest influence on Jang Young-sil's manifestation of giftedness. Fifth, informal learning and non-institutional formal learning in the developmental process(LP) influenced the manifestation of giftedness. In this way, the talent development factors of people such as Jang Young-sil provide implications for the need to understand the manifestation mechanism of giftedness in the future, develop examination tools that can detect giftedness, and develop customized programs that can develop giftedness.

An Empirical Study on the Relationship Between the Success Factor and Performance of e-Business (e-비즈니스의 주요 성공요인와 성과와의 관련성에 관한 실증연구)

  • Kim, Chang-Su;Cho, Eun-Seok;Sung, Gi-Wook
    • Information Systems Review
    • /
    • v.8 no.3
    • /
    • pp.39-64
    • /
    • 2006
  • In the global economy, e-business has increasingly become a strong catalyst for company growth and an essential activity of business innovation. It would be meaningful to provide comprehensive research about the success factor of e-business to facilitate its continuous growth and set up its future strategic direction in global e-business circumstances. There is limited research focusing on what are the major success factors of e-business. In this paper, we first attempt to identify the major e-business success factors in terms of management and technical aspects, according to the literature review, case study, and interview. Secondly, this research carries out an empirical investigation of the success factors closely associated to the e-business. Thirdly, this study examines the relationship between the success factor and performance of e-business. Finally, on the basis of the research results, this paper highlights e-business strategic vision which should be critically considered as an organization adopts and implements e-business.

The Evolution of IT architecture in Universities: A Case study of Korean Domestic Universities (대학 정보기술 아키텍처 발전방향에 관한 연구: 국내 대학 사례를 중심으로)

  • Yoon, Sung-Chul;Suh, Hyun-Suk;Lee, Seog-Jun
    • Information Systems Review
    • /
    • v.4 no.2
    • /
    • pp.111-131
    • /
    • 2002
  • Strategic information systems assist organization with the significant opportunity to gain competitive advantage in executing its business plans and realizing its business goals. The universities establish long-range plan of information systems in an effort to provide just-in-time, useful, efficient and effective information services to their members such as professors, students, and staffs when carrying out various organizational activities. The university information systems started from the primitive computer-based application, extended to the administrative and educational e-transformation, even to the virtual university concept. Through an empirical analysis and complementary case examples, the current study carefully chose three Korean universities according to their chronological importance, that have undergone the information systems planning process years from 1995 to 2001. These universities then, were compared in terms of the information technology architecture: the information architecture, infra architecture, and information management architecture. These three areas of system were cross-examined under the consideration of the evolution of information technology architecture, and its impact on the development of university e-transformation. As part of a fulfillment plan to satisfy the needs of customers of current trend, it is evident that the university e-transformation provides a stepladder to highly competitive, first class university in the market, through achieving the educational advancement, research enhancement, and administrative efficiency. The result of the study analysis indicates that, of the three architectures examined, the weakness showed in the information management architecture. Therefore it is crucial for the university staffs, managers and professors to understand the significance of the successful implementation of the information system and its maintenance. Our study certainly will act as a catalyst for the promotion of the future university e-transformation projects.