• Korean Journal of Materials Research
• /
• v.34 no.5
• /
• pp.254-260
• /
• 2024

This study is to manufacture a titanium dioxide (TiO₂) photocatalyst by recycling sludge generated using titanium tetrachloride (TiCl₄) as a coagulant. Compared to general sewage, a TiCl₄ coagulant was applied to dyeing wastewater containing a large amount of non-degradable organic compounds to evaluate its performance. Then the generated sludge was dried and fired to prepare a photocatalyst (TFS). Scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), and nitrogen oxide reduction experiments were conducted to analyze the surface properties and evaluate the photoactive ability of the prepared TFS. After using titanium tetrachloride (TiCl₄) as a coagulant in the dyeing wastewater, the water quality characteristics were measured at 84 mg/L of chemical oxygen demand (COD), 10 mg/L of T-N, and 0.9 mg/L of T-P to satisfy the discharge water quality standards. The surface properties of the TFS were investigated and the anatase crystal structure was observed. It was confirmed that the ratio of Ti and O, the main components of TiO₂, accounted for more than 90 %. As a result of the nitric oxide (NO) reduction experiment, 1.56 uMol of NO was reduced to confirm a removal rate of 20.60 %. This is judged to be a photocatalytic performance similar to that of the existing P-25. Therefore, by applying TiCl₄ to the dyeing wastewater, it is possible to solve the problems of the existing coagulant and to reduce the amount of carbon dioxide generated, using an eco-friendly sludge treatment method. In addition, it is believed that environmental and economic advantages can be obtained by manufacturing TiO₂ at an eco-friendly and lower cost than before.

• Carbon letters
• /
• v.15 no.1
• /
• pp.38-44
• /
• 2014

This paper reports the effect of adding reduced graphene oxide (RGO) as a conductive material to the composition of an electrode for capacitive deionization (CDI), a process to remove salt from water using ionic adsorption and desorption driven by external applied voltage. RGO can be synthesized in an inexpensive way by the reduction and exfoliation of GO, and removing the oxygen-containing groups and recovering a conjugated structure. GO powder can be obtained from the modification of Hummers method and reduced into RGO using a thermal method. The physical and electrochemical characteristics of RGO material were evaluated and its desalination performance was tested with a CDI unit cell with a potentiostat and conductivity meter, by varying the applied voltage and feed rate of the salt solution. The performance of RGO was compared to graphite as a conductive material in a CDI electrode. The result showed RGO can increase the capacitance, reduce the equivalent series resistance, and improve the electrosorption capacity of CDI electrode.

• KIEAE Journal
• /
• v.12 no.6
• /
• pp.39-47
• /
• 2012

Recently, the green building and energy connection system are establishing. But, National certification system for environment-Friendly Buildings is indicated hangup about energy efficiency of building. Commissioning, energy conservation, renewable energy, carbon dioxide emissions, it is determined that the energy associated with LEED and GBCC four items of the comparative analysis showed the following results. First, on the practical performance of the system after the completion of commissioning of the energy associated with the system completed until after the final performance for secure operation from the planning stage to verify and document systematically how to perform, but the domestic review and verification is incomplete. Second, the use of energy-saving and renewable energy is directly related to the energy consumption of the building, but GBCC the strengthening of standards on how to evaluate it is deemed necessary. Finally, the evaluation of the reduction of carbon dioxide emissions, LEED Unlike GBCC the life-cycle of the system without considering the global warming index only because a substantial step in the operating efficiency can not be assessed. Based on this study GBCC energy savings through efficiency to actively carry out research through a systematic analysis of the basic guidelines to proceed.

• Journal of IKEEE
• /
• v.23 no.3
• /
• pp.988-993
• /
• 2019

Over the past decades, the semiconductor industry has continuously scaled down the size of semiconductor devices to increase those performance and to integrate them at higher density on the chip. However, facing the reduction of gate control, higher leakage current, and short channel effect, there is a growing interest in next-generation semiconductors which can overcome these problems. In this paper, we discuss digital circuit design techniques using CNTFET(Carbon NanuTube Field Effect Transistor), which are attracting attention as candidates for the next generation of semiconductors. Since the structure of CNTFETs are clearly different from the structure of the structure of conventional MOSFETs, we will discuss how to utilize existing digital circuit methodology when designing digital circuits using the CNTFETs, and then simulate the performance differences between the two devices.

• Structural Engineering and Mechanics
• /
• v.77 no.6
• /
• pp.735-744
• /
• 2021

In recent years, the use of new materials and technologies with the aim of developing high-performing and cost-effective structures has greatly increased. Application of high-strength concrete (HSC) has been found effective in reducing the dimensions of frame members; nonetheless, such reduction in dimensions of structural elements in the most cases may result in the lack of accountability in the tolerable drift capacity. On this basis, strengthening of frame members using fiber reinforced polymers (FRPs) may be deemed as an appropriate remedy to address this issue, which albeit requires comprehensive and systematic investigations. In this paper, the performance of properly-designed, two-dimensional frames made of high-strength concrete and strengthened with Carbon Fiber Reinforced Polymers (CFRPs) is investigated through detailed numerical simulation. To this end, nonlinear dynamic time history analyses have been performed using the Seismosoft software through application of five scaled earthquake ground motion records. Unstrengthened (bare) and strengthened frames have been analyzed under seismic loading for performance assessment and comparison purposes. The results and findings of this study show that use of CFRP can be quite effective in seismic response improvement of high-strength-concrete structures.

• Journal of Ocean Engineering and Technology
• /
• v.36 no.3
• /
• pp.168-180
• /
• 2022

The IMO has decided to proceed with the early introduction of EEDI Phase 3, a CO₂ emission regulation to prevent global warming. Measures to reduce CO₂ emissions for ships that can be applied immediately are required to achieve CO₂ reduction. We set six different CO₂ emission scenarios according to the type of ship and fuel, and designed a monoethanolamine-based CO₂ capture process for ships using a rate-based model of Aspen Plus v10. The simulation model using Aspen Plus was validated using pilot plant operation data. A ship inevitably tilts during operation, and the performance of a tilted column decreases as its height increases. When configuring the conventional CO₂ capture process, we considered that the required column heights were so high that performance degradation was unavoidable when the process was implemented on a ship. We applied a parallel column concept to lower the column height and to enable easy installation and operation on a ship. Simulations of the parallel column confirmed that the required column height was lowered to less than 3 TEU (7.8 m).

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.15 no.3
• /
• pp.105-111
• /
• 2009

In this work, source reduction of poly ethylene terephthalate (PET) packaging are discussed as aspect of sustainability, such as reuse, refill and recycling through the various treatment methods and historical studies for municipal solid waste (MSW) disposal. Since PET has good chemical, physical and mechanical properties, and provides good oxygen and carbon dioxide barrier properties, PET is one of the most widely used thermoplastic polyester in the U.S. and around the world. As the demand for non-renewable PET is increasing, several approaches have been developed to meet economical feasibility and environmental responsibility without degrading material performance. Several companies, such as Coca-Cola Co., Easterform Packaging Co. and Kraft, have tried to develop lightweight PET bottle, and some of lightweight PET bottles are already commercialized. Reuse and refilling for PET container is well developed in Europe, such as Denmark, German and Netherland by supportive legislation and policies. Recycling process is the best way to economically reduce PET waste. In consequence, advanced technique and further development must be provided due to increasing PET packaging waste.

• Tribology and Lubricants
• /
• v.17 no.4
• /
• pp.312-320
• /
• 2001

In magnetic hard disk drives, higher areal recording density requires reduction of head-disk spacing. To overcome the increase of stiction associated with reduction of head-disk spacing, a padder slider, which adds pads to slider's air bearing surface, can be one of the practical solution for sub 20 nm flying height, and even for near contact recording. This study investigated the tribological characteristics of a padder slider. A padder slider took off slowly but showed less friction force than a normal slider. The hot/dry CSS test and drag test indicated that pad wear of a padder slider was negligible. The tribological performance of disk is an important factor to be considered. In particular, less carbon overcoat layer of the disk will result in higher stiction and wear in slider/disk interface. In conclusion, a padder slider shows encouraging tribological performances for practical use in HDD.

• Bulletin of the Korean Chemical Society
• /
• v.27 no.5
• /
• pp.672-678
• /
• 2006

A new approach to fabricate an enzyme electrode was described based on the immobilization of horseradish peroxidase (HRP) on dithiobis-N-succinimidyl propionate (DTSP) self-assembled monolayer (SAM) formed on gold-nanoparticles (Au-NPs) which were electrochemically deposited onto glassy carbon electrode (GCE) surface. The overall surface area and average size of Au-NPs could be controlled by varying deposition time and were examined by Field Emission-Scanning Electron Microscope (FE-SEM). The $O_2$ reduction capability of the surface demonstrated that Au-NPs were thermodynamically stable enough to stay on GCE surface. The immobilized HRP electrode based on Au-NPs/GCE presented faster, more stable and sensitive amperometric response in the reduction of hydrogen peroxide than a HRP immobilized on DTSP/gold plate electrode not containing Au-NPs. The effects of operating potential, mediator concentration, and pH of buffer electrolyte solution on the performance of the HRP biosensor were investigated. In the optimized experimental conditions, the HRP immobilized GCE incorporating smaller-sized Au-NPs showed higher electrocatalytic activity due to the high surface area to volume ratio of Au-NPs in the biosensor. The HRP electrode showed a linear response to $H_2O_2$ in the concentration range of 1.4 $\mu$M-3.1 mM. The apparent Michaelis-Menten constant ($K _M\; ^{app}$) determined for the immobilized HRP electrodes showed a trend to be decreased by decreasing size of Au-NPs electrodeposited onto GCE.

• Elastomers and Composites
• /
• v.49 no.2
• /
• pp.95-102
• /
• 2014

The noise between floors of apartment has been hot issue nowadays. In order to improve the noise insulation performance, we proposed the antivibration rubber system which can be applied to the floor system for sound insulation. Among various types of elastomer, butyl rubber showed the good aging characteristic, low rebound resilience and high damping factor. Thus, the butyl rubber was selected as a basic rubber for antivibration rubber system. The effects of type and loading amounts of carbon black on antivibration properties of butyl rubber were studied. The increase of surface area and the content of carbon black resulted in high bound rubber fraction, high mechanical property, low rebound resilience, and high damping factor of butyl rubber. Based on the results of this study, the new antivibration rubber was prepared and applied to the floor system for sound insulation. The impact sounds of floor system proposed in this study were 40 dB and 43 dB in cases of light weight and heavy weight impact sound, respectively.