• 제목/요약/키워드: Carbon flow

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양면정체유동버너를 이용한 탄소나노튜브 합성에 대한 연구 (Studies on Combustion Synthesis of Carbon Nanotubes Using a Double-faced Wall Stagnation Flow Burner)

  • 홍영택;우상길;권오채
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2154-2159
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    • 2007
  • The potential of using a double-faced wall stagnation flow burner in mass production of carbon nanotubes was evaluated experimentally and computationally. With nitrogen-diluted premixed ethylene-air flames established on the Nickel-coated stainless steel double-faced wall, the propensities of carbon nanotube formation were experimentally determined using SEM and FE-TEM images and Raman spectroscopy, while the flame structure was computationally predicted using a 3-dimensional CFD code with a reduced reaction mechanism. The uniformity and yields of synthesized carbon nanotubes were evaluated in terms of the flame stretch rates. Results show substantial increase of area on the wall surface where uniform carbon nanotubes are synthesized with using the double-faced wall stagnation flow burner due to enhanced uniformity of temperature distribution along the wall surface and support the potential of using a double-faced wall stagnation flow burner in mass production of carbon nanotubes.

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탄소나노튜브의 유체유발 진동 (Flow-induced Vibration of Carbon Nanotubes Conveying Fluid)

  • 송오섭;최종운;길보람
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2008년도 춘계학술대회논문집
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    • pp.242-249
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    • 2008
  • In this paper, flow-induced flutter instability of cantilever carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

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탄소나노튜브의 유체유발 진동 (Flow-induced Vibration of Carbon Nanotubes Conveying Fluid)

  • 최종운;길보람;송오섭
    • 한국소음진동공학회논문집
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    • 제18권6호
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    • pp.654-662
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    • 2008
  • In this paper, flow-induced flutter instability of cantilever carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

흡착/촉매 공정개선을 위한 사이클론 내 유동특성 및 활성탄 체류시간 산정 (Flow Characteristics and Residence Time of Activated Carbon in the Cyclone for Optimized Design of an Adsorption/Catalysis Reactor)

  • 최청렬
    • 대한기계학회논문집B
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    • 제31권5호
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    • pp.416-424
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    • 2007
  • In adsorption/catalytic process, numerical analysis has been performed to identify the flow characteristics of flue gas in the cyclone and to estimate the residence time of activated carbon using Computational Fluid Dynamics (CFD) technique. To consider flue gas and activated carbon particles simultaneously, Euler-Lagrangian model was employed so that residence time could be obtained from the numerical analysis directly. The numerical analysis has been performed with different three particle sizes and compared each flow characteristics with particle’ size. Fundamental flow patterns of flue gas and activated carbon particles, pressure distribution, residence time of flue gas, and activated carbon particles and distribution of activated carbon have been obtained from the numerical analysis.

[Retraction]Characterization of carbon black nanoparticles using asymmetrical flow field-flow fractionation (AsFlFFF)

  • Kim, Kihyun;Lee, Seungho;Kim, Woonjung
    • 분석과학
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    • 제32권3호
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    • pp.77-87
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    • 2019
  • High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

Development of Carbon Composite Bipolar Plates for Vanadium Redox Flow Batteries

  • Lee, Nam Jin;Lee, Seung-Wook;Kim, Ki Jae;Kim, Jae-Hun;Park, Min-Sik;Jeong, Goojin;Kim, Young-Jun;Byun, Dongjin
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3589-3592
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    • 2012
  • Carbon composite bipolar plates with various carbon black contents were prepared by a compression molding method. The electrical conductivity and electrochemical stability of the bipolar plates have been evaluated. It is found that the electrical conductivity increases with increasing carbon black contents up to 15 wt %. When the carbon black contents are greater than 15 wt %, the electrical conductivity decreases because of a poor compatibility between epoxy resin and carbon black, and a weakening of compaction in the carbon composite bipolar plate. Based on the results, it could be concluded that there are optimum carbon black contents when preparing the carbon composite bipolar plate. Corrosion tests show that the carbon composite bipolar plate with 15 wt % carbon black exhibits better electrochemical stability than a graphite bipolar plate under a highly acidic condition. When the optimized carbon composite bipolar plate is applied to vanadium redox flow cells, the performance of flow cells with the carbon composite bipolar plate is comparable to that of flow cells with the graphite bipolar plate.

교류 흐름 방식을 적용한 암모니아 공급 고체산화물 연료전지의 성능 분석 (Performance Analysis of Ammonia-Fed Solid Oxide Fuel Cell Using Alternating Flow)

  • 쿠엔;잡반티엔;이동근;이선엽;배용균;안국영;김영상
    • 한국수소및신에너지학회논문집
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    • 제33권5호
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    • pp.557-565
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    • 2022
  • The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.

유체유동에 의한 다중벽 탄소나노튜브의 안정성 해석 (Stability Analysis of Multi-wall Carbon Nanotubes Conveying Fluid)

  • 송오섭;윤경재
    • 한국소음진동공학회논문집
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    • 제20권6호
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    • pp.593-603
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    • 2010
  • In this paper, vibration and flow-induced flutter instability analysis of cantilever multi-wall carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia and van der Waals forces between two walls are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

유체유동효과를 고려한 다중벽 탄소나노튜브의 진동 및 안정성 해석 (Vibration Stability Analysis of Multi wall Carbon Nanotubes Considering Conveying Fluid Effect)

  • 윤경재;최종운;송오섭
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2012년도 춘계학술대회 논문집
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    • pp.219-224
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    • 2012
  • In this paper, vibration and flow-induced flutter instability analysis of cantilever multiwall carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

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증발가스 배출물 억제를 위한 자동차용 캐니스터의 3차원 유동장 해석 (Three-Dimensional Fluid Flow Analysis of Automotive Carbon Canister for Reducing Evaporative Emissions)

  • 정수진;김우승
    • 한국자동차공학회논문집
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    • 제9권6호
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    • pp.85-93
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    • 2001
  • Minimized canister flow restriction and maximized flow uniformity are desired to maximize a purge capability. With the impending ORVR(On Board Refueling Vapor Recovery) systems, the reduction of restriction and increase of flow uniformity in a carbon canister becomes even more critical to meet the stringent regulation. In this study, three-dimensional numerical simulations have been performed to investigate the three-dimensional internal flow patterns in a carbon canister during purge. The effects of the declined angle of the purge pipe and the number of partitions on the pressure drop and purge efficiency in a carbon packed bed are examined. Results show that the purge efficiency and space velocity distribution are affected in the upstream region of 40% of total canister bed by porosity of carbon granule and angle of purge pipe. It is also found that the purge efficiency decreases with increasing the number of partitions.

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