• Title/Summary/Keyword: Carbon film

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Removal of Phenols by Granular Activated Carbon in Aqueous Solution (수용액에서 입상활성탄에 의한 페놀류의 제거)

  • 권성헌;강원석
    • Journal of Environmental Science International
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    • v.7 no.4
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    • pp.541-548
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    • 1998
  • Aqueous phase adsorption of phenols by granular activated carbon was studied in a batch adsorption vessel. Adsorption Isotherms of phenol(Ph), p-chlorophenol(PCP) and p-nitrophenol (PNP) from aqueous solution on granular activated carbon have been obtained. The experimental data were analyzed by the surface and pore diffusion models. Both models could be applied to predict the adsorption phenomena. However, the pore diffusion model was slightly better than the surface diffusion model In representing the experimental data for the initial concentration changes. Therefore, the pore diffusion model was used to predict the change of operating variables such as the agitation speed and Particle size of adsorbent which have influence on the film resistance and intraparticle diffusion.

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Effects of Iron-Reducing Bacteria on Carbon Steel Corrosion Induced by Thermophilic Sulfate-Reducing Consortia

  • Valencia-Cantero, Eduardo;Pena-Cabriales, Juan Jose
    • Journal of Microbiology and Biotechnology
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    • v.24 no.2
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    • pp.280-286
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    • 2014
  • Four thermophilic bacterial species, including the iron-reducing bacterium Geobacillus sp. G2 and the sulfate-reducing bacterium Desulfotomaculum sp. SRB-M, were employed to integrate a bacterial consortium. A second consortium was integrated with the same bacteria, except for Geobacillus sp. G2. Carbon steel coupons were subjected to batch cultures of both consortia. The corrosion induced by the complete consortium was 10 times higher than that induced by the second consortium, and the ferrous ion concentration was consistently higher in iron-reducing consortia. Scanning electronic microscopy analysis of the carbon steel surface showed mineral films colonized by bacteria. The complete consortium caused profuse fracturing of the mineral film, whereas the non-iron-reducing consortium did not generate fractures. These data show that the iron-reducing activity of Geobacillus sp. G2 promotes fracturing of mineral films, thereby increasing steel corrosion.

Partial Discharge Properties of PET Film with Carbon Black

  • Lee, Young-Hwan;Lee, Jong-Chan;Park, Yong-Sung;Park, Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.1
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    • pp.1-4
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    • 2004
  • This paper presents an investigation of the phase-resolved partial discharge (PD) pattern of PET (Poly Ethylene Telephthalate) films with carbon black particles. The phase-resolved PD pattern and statistical parameter from PET samples according to the number of included semiconductor particles were measured. The measurement system consisted of a conventional PD detector using a digital signal processing technique. The partial discharge patterns of the PET films that include the semiconductor particles were investigated to simulate an actual situation that may exist in the cable. In addition, difference of PD patterns between semiconducting particles in PET films and artificial voids was studied. The relationship between the numbers of semiconductor particles in PET films was discussed through the difference of Ψ-q-n distribution and statistical analysis.

Thermal Stimulated Conductivity in Cellulose Triacetate-Multiwalled Carbon Nanotube Polymer Films

  • Basavaraja, C.;Jo, Eun-Ae;Kim, Bong-Sung;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2207-2210
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    • 2010
  • This paper describes the preparation and study of thermally stimulated discharge conductivity (TSDC) study of cellulose triacetate (CTA) - multiwalled carbon nanotubes (MWNTs) film thermoelectrets. TSDC has been carried out in the temperature range 308 - 503 K and at four different polarizing fields. The conductivity of the polymer blends increased with increase in temperature showing a semi-conducting behavior. The apparent activation energy also showed a pronounced effect with the increase in the content of MWNTs.

Pilot-Scale Testing of a Vibrating Electrostatic Separator for Fly Ash Decarbonization

  • Yoon, Roe-Hoan;Eric Yan;Han, Oh-Hyung;Park, Byung-Wook
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.644-649
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    • 2001
  • A new electrostatic separator has been developed for the removal of unburned carbon from fly ash. In this separator, a flowing film of fly ash is created on the surface of a vibrating electrode. Conducting particles such as unburned carbon acquire electrostatic charges and jump out of the flowing film so that they can be removed from the non-conducting fly ash particles moving forward. The new separator has been tested successfully using a pilot-scale test unit at 0.5 tons/hr capacity. Based on the successful test results, a larger unit is being constructed at the present time.

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LOW TEMPERATURE DEPOSITION OF SILICON OXIDE FILMS BY UV-ASSOSTED RF PLASMA-ENHANCED CVD

  • Hozumi, Atsushi;Sugimoto, Nobuhisa;Sekoguchi, Hiroki;Takai, Osamu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.773-780
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    • 1996
  • Silicon oxide films were prepared by using five kinds of organosilicon compound as gas sources without oxygen by rf plasma-enhanced CVD (PECVD). UV light was irradiated on a substrate vertically during deposition to enhance film oxidation and ablation of carbon contamination in a deposited films. Films prepared with UV irradiation contained less carbon than those prepared without UV irradiation. The oxidation of the films was improved by UN irradiation. The effect of UV irradiation was, however, not observed when the films were prepared with tetramethy lsilane (TMS) which contained no oxygen atom. Dissociated oxygen atoms from an organosilicon compound were excited in the plasma with UV irradiation around the substrate surface and affected the enhancement of film oxidation and ablation of carbon in the films.

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Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization

  • Lee, Kyeong-Jong;Yoon, Il;Lee, Shim-Sung;Lee, Bu-Yong
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.399-403
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    • 2002
  • The complex of iron(II) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen)3]($PF_6$)2${\cdot}$CH3CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of $>[Fe(3-Br-phen)3]^{2+}$ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-$>[Fe(3-Br-phen)3]^{2+}$ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.

Effects of High Neutral Beam Energy on the Properties of Amorphous Carbon Films

  • Lee, Dong-Hyeok;Jang, Jin-Nyeong;Gwon, Gwang-Ho;Yu, Seok-Jae;Lee, Bong-Ju;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.477-477
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    • 2012
  • The effects of argon neutral beam (NB) energy on the amorphous carbon (a-C) films were investigated, while the a-C films were deposited by neutral particle beam assisted sputtering (NBAS) system. The deposition characteristics of these films were studied as a function of NB energy (or reflector bias voltage). The film structures were investigated by Raman spectroscopy. The hardness was measured by nano-indentation tests and the optical band gap was measured by UV-visible spectroscopy.

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Gas sensing characteristics of carbon nanotube gas sensor using a diaphragm structure (다이아프램 구조를 이용한 탄소나노튜브 가스 센서의 가스 감응 특성)

  • Cho, Woo-Sung;Moon, Seung-Il;Kim, Young-Cho;Park, Jung-Ho;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.15 no.1
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    • pp.13-19
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    • 2006
  • The micro-gas sensor based on carbon nanotubes (CNTs) was fabricated and its gas sensing characteristics on nitrogen dioxide ($NO_{2}$) have been investigated. The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_{2}$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

A Study on Tribological Properties of Diamond-like Carbon Thin Film for the Application to Solid Lubricant of MEMS Devices (MEMS 소자의 고체윤활박막으로 활용하기 위한 다이아몬드상 카본 박막의 트라이볼로지 특성 분석)

  • Choi, Won-Seok;Hong, Byung-You
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.11
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    • pp.1010-1013
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    • 2006
  • Hydrogenated Diamond-like carbon (DLC) films were Prepared by the radio frequency plasma enhanced chemical vapor deposition (RF PECVD) method on silicon substrates using methane $(CH_4)$ and hydrogen $(H_2)$ gas for the application to solid lubricant of MEMS devices. We have checked the influence of varying RF power on tribological properties of DLC film. We have checked their performance as two kinds of method such as FFM (Friction Force Microscope) and BOD (Ball-on Disk) measurement. The friction coefficients and the contact number of cycles to steady state decreased as the increase of RF power with FFM and BOD measurement, respectively.