• Journal of Microbiology and Biotechnology
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• v.33 no.3
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• pp.310-318
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• 2023

Microalgae are attracting much attention as promising, eco-friendly producers of bioenergy due to their fast growth, absorption of carbon dioxide from the atmosphere, and production capacity in wastewater and salt water. However, microalgae can only accumulate large quantities of lipid in abiotic stress, which reduces productivity by decreasing cell growth. In this study, the strategy was investigated to increase cell viability and lipid production by overexpressing S-adenosylmethionine (SAM) synthetase (SAMS) in the microalga Chlamydomonas reinhardtii. SAM is a substance that plays an important role in various intracellular biochemical reactions, such as cell proliferation and stress response, and the overexpression of SAMS could allow cells to ithstand the abiotic stress and increase productivity. Compared to wild-type C. reinhardtii, recombinant cells overexpressing SAMS grew 1.56-fold faster and produced 1.51-fold more lipids in a nitrogen-depleted medium. Furthermore, under saline-stress conditions, the survival rate and lipid accumulation were 1.56 and 2.04 times higher in the SAMS-overexpressing strain, respectively. These results suggest that the overexpression of SAMS in recombinant C. reinhardtii has high potential in the industrial-scale production of biofuels and various other high-value-added materials.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.06a
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• pp.77-78
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• 2020

In Korea, more than 30,000 tons of waste Styrofoam are produced every year. Styrofoam is spent more than 500 years decomposing during the reclamation process, so it needs to be recycled. The recycling rate of waste styrofoam continues to be the third highest in the world, but it is lower than that of Germany and Japan. Therefore, measures are needed to increase the recycling rate of waste Styropol. Another problem is that cement is mainly used in existing lightweight foam concrete. However, large amounts of CO2 from cement-producing processes cause environmental pollution. Currently, Korea is increasing its greenhouse gas reduction targets to cope with energy depletion and climate change, and accelerating efforts to identify and implement reduction measures for each sector. In 2013 alone, about 600 million tons of carbon dioxide was generated in the cement industry. Therefore, this study replaces CO2 generation cement with furnace slag fine powder, uses crude steel cement for initial strength development of bubble concrete, and manufactures hardening materials to study its properties using waste styrofoam. As a result of the experiment, the hardening agent replaced by micro powder of furnace slag was less intense and more prone to absorption than cement using ordinary cement. Further experiments on the segmentation and strength replenishment of furnace slag are believed to contribute to the manufacture of environmentally friendly lightweight foam concrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.207-208
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• 2022

Since 1960, the green area has decreased due to rapid urbanization and the artificial surface has increased, and the repair and water function of the previous surface has decreased due to the decrease in rainwater absorption capacity. In addition, the risk of carbon dioxide and fine dust is emerging due to the use of fossil fuels due to urbanization. As a result, permeable blocks, an eco-friendly product, are in the spotlight. Therefore, this study was conducted to examine the strength properties of the permeable block using a hydroball. As a result of the experiment, the flexural strength and compressive strength tended to decrease as the hydroball replacement rate increased. It is judged that the hydroball absorbs a large amount of moisture during the mixing process and lacks moisture required for curing, resulting in a decrease in strength. According to KS F 4419, since the hydroball replacement rate is satisfied up to 20%, further research is needed to analyze the adsorption performance of air pollutants in the future and evaluate their utilization as a permeable block in the future.

• Nuclear Engineering and Technology
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• v.56 no.8
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• pp.3043-3066
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• 2024

In various small modular reactor (SMR) designs currently under development, the conventional concrete containment building has been replaced by a metal containment vessel (MCV). In these systems, the gap between the MCV and the reactor pressure vessel is filled with gas or vacuumed weakly, effectively suppressing conduction and convection heat transfer. However, thermal radiation remains the major mode of heat transfer during normal operation. The objective of this study was to investigate the heat-transfer mechanisms in integral pressurized water reactor (IPWR)-type SMRs under various gas-filled conditions using computational fluid dynamics. The use of thermal radiation shielding (TRS) with a much lower emissivity material than the MCV surface was also evaluated. The results showed that thermal radiation was always the dominant contributor to heat loss (48-97%), while the conjugated effects of the gas candidates on natural convection and thermal radiation varied depending on their thermal and radiative properties, including absorption coefficient. The TRS showed an excellent insulation performance, with a reduction in the total heat loss of 56-70% under the relatively low temperatures of the IPWR system, except for carbon dioxide (13%). Consequently, TRS can be utilized to enhance the thermal efficiency of SMR designs by suppressing the heat loss through the MCV.

• Korean Chemical Engineering Research
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• v.53 no.1
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• pp.57-63
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• 2015

Absorption characteristics of 2-methylpiperidine (2MPD), 3-methylpiperidine (3MPD) and 4-methylpiperidine (4MPD) absorbents were studied by a vapor-liquid equilibrium (VLE) apparatus and a differential reaction calorimeter (DRC). Using a VLE apparatus, the $CO_2$ loading capacity of each absorbent was estimated. After reaching the absorption equilibrium, nuclear magnetic resonance spectroscopy (NMR) had been conducted to characterize the species distribution of the ($H_2O$-piperidine-$CO_2$) system. Using a DRC, the reaction of heat was confirmed in accordance with the absorption capacity. The unique characteristics of 2MPD, 3MPD and 4MPD absorbents appeared by the position of methyl group. The 2MPD possessing the methyl group at the ortho position showed its hindrance effect during the absorption process; however, piperidine derivatives possessing the meta position and para position did not show its characteristics in $H_2O$-piperidine-$CO_2$ system.

• Korean Chemical Engineering Research
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• v.45 no.3
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• pp.258-263
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• 2007

Ammonia water was investigated as a new absorbent of the chemical absorption process for the removal of $CO_2$ in flue gas. The suitable range of ammonia water concentration and $CO_2$ loading ($mol\;CO_2/mol\;NH_3$) were decided in the point of view of $CO_2$ absorption capacity and $NH_4HCO_3$ precipitation. The absorption capacity of $CO_2$ and the precipitation of $NH_4HCO_3$ in liquid phase were calculated by the Pitzer model for electrolyte solution. The $CO_2$ absorption capacity of the ammonia water over $5\;molNH_3/kgH_2O$ was higher than that of conventional amine absorbent. The $CO_2$ loadings where precipitation occurred were decided at various absorbent concentrations. Theses values were higher than 0.5 in the concentration range of $5-14\;molNH_3/kgH_2O$ at 293, 313 K. The absorber for the removal of $CO_2$ in flue gas could be operated without $NH_4HCO_3$ precipitation by using high concentration of ammonia water below these $CO_2$ loading values. The optimum temperature of the ammonia water absorbent for removal of $CO_2$ in flue gas was 297-312 K depending on the concentration of ammonia water.

• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.335-342
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• 2018

Various technologies to cope with the energy and environmental issues related to the chemical and electric power industry are in development and demonstration stage. Especially, the absorption process of carbon dioxide ($CO_2$) using amine solution is a key technology of the $CO_2$ capture and storage (CCS). In this study, we identify the major risk factors and suggest strategies for safety improvement by analyzing and assessing commercial the amine-based $CO_2$ separation process. HAZOP method was used to assess the risk for the process. We provide facilities and operational strategies to mitigate or eliminate major risk factors by assessing the relative ranks of identified risk factors using a risk matrix.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.3
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• pp.483-490
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• 2019

Assessing the effect of forest fires and measuring the gas concentration around a fire has received little attention. Therefore, the concentrations of various gases in areas surrounding a fire need to be measured by the development of a suitable device. Unlike conventional portable devices, the AQS (Air Quality System) proposed in this paper is a portable instrument that measures five types of gases simultaneously, including CO, CO2, NOx, VOCs, and NH3, and has high durability through sensor protection algorithms. A PC-based program with an AQS connection was developed to monitor the real-time changes in the gas concentration. The reliability of the developed device was proven through a comparison of the results with other commercial gas analyzers. Measurements of the concentration due to indoor and outdoor fires were performed around a fire area to review the applicability and the predicted results were obtained.

• Membrane Journal
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• v.33 no.4
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• pp.168-180
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• 2023

H₂ generation from renewable sources is crucial for ensuring sustainable production of energy. One approach to achieve this goal is biohydrogen production by utilizing renewable resources such as biomass and microorganisms. In contrast to commercial methods, biohydrogen production needs ambient temperature and pressure, thereby requiring less energy and cost. Biohydrogen production can reduce greenhouse gas emissions, particularly the emission of carbon dioxide (CO₂). However, it is also associated with significant challenges, including low hydrogen yields, hydrodynamic issues in bioreactors, and the need for H₂ separation and purification methods to obtain high-purity H₂. Various technologies have been developed for hydrogen separation and purification, including cryogenic distillation, pressure-swing adsorption, absorption, and membrane technology. This review addresses important experimental developments in dense polymeric membranes for biohydrogen purification.

• Clean Technology
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• v.20 no.2
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• pp.146-153
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• 2014

In this study, the effect of alkanolamine additives, 2-amino-2-methyl-1-propanol (AMP) and 2-amino-2-methyl-1,3-propanediol (AMPD) on $CO_2$ absorption rate of $K_2CO_3$ solution and the formation of $KHCO_3$ crystals was investigated. The normalized $CO_2$ flux and the equilibrium $CO_2$ partial pressure were measured for 5 wt% additives and 30 wt% $K_2CO_3$ mixtures using a wetted-wall column unit at $40^{\circ}C$ and $60^{\circ}C$. Both additives showed the increased $CO_2$ absorption rate and lowered the equilibrium $CO_2$ partial pressure acting as promoters. Besides, AMPD which has two hydroxyl groups enhanced the formation of $KHCO_3$ solid product separated from the $CO_2$-rich solution from the results of batch cooling crystallization experiments.