Browse > Article
http://dx.doi.org/10.9713/kcer.2015.53.1.57

The Effect of Functional Group Position of the Piperidine Derivatives on the CO2 Absorption Characteristics in the (H2O-Piperidine-CO2) System  

Choi, Jeong Ho (Greenhouse Gas Laboratory, Korea Institute of Energy Research)
Yun, Soung Hee (Greenhouse Gas Laboratory, Korea Institute of Energy Research)
Kim, Yeong Eun (Greenhouse Gas Laboratory, Korea Institute of Energy Research)
Yoon, Yeo Il (Greenhouse Gas Laboratory, Korea Institute of Energy Research)
Nam, Sung Chan (Greenhouse Gas Laboratory, Korea Institute of Energy Research)
Publication Information
Korean Chemical Engineering Research / v.53, no.1, 2015 , pp. 57-63 More about this Journal
Abstract
Absorption characteristics of 2-methylpiperidine (2MPD), 3-methylpiperidine (3MPD) and 4-methylpiperidine (4MPD) absorbents were studied by a vapor-liquid equilibrium (VLE) apparatus and a differential reaction calorimeter (DRC). Using a VLE apparatus, the $CO_2$ loading capacity of each absorbent was estimated. After reaching the absorption equilibrium, nuclear magnetic resonance spectroscopy (NMR) had been conducted to characterize the species distribution of the ($H_2O$-piperidine-$CO_2$) system. Using a DRC, the reaction of heat was confirmed in accordance with the absorption capacity. The unique characteristics of 2MPD, 3MPD and 4MPD absorbents appeared by the position of methyl group. The 2MPD possessing the methyl group at the ortho position showed its hindrance effect during the absorption process; however, piperidine derivatives possessing the meta position and para position did not show its characteristics in $H_2O$-piperidine-$CO_2$ system.
Keywords
Carbon Dioxide; Piperidine; Greenhouse Gas; Aqueous Absorbents; Alkanolamine;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 Thiruvenkatachari, R., Su, S., An, H. and Yu, X. X., "Post Combustion $CO_2$ Capture by Carbon Fiber Monolithic Adsorbents," Prog. Energy Combust. Sci., 35, 438-455(2009).   DOI
2 Wall, T. F., "Combustion Processes for Carbon Capture," Proc. Combust. Inst., 31, 31-47(2007).   DOI
3 UME, C. S. and Alper, E., "Reaction Kinetics of Carbon Dioxide with 2-amino-2-hydroxymethyl-1,3-propanediol in Aqueous Solution Obtained from the Stopped Flow Method," Turk. J. Chem., 36, 427-435(2012).
4 Yu, C. H., Huang, C. H. and Tan, C. S., "A Review of $CO_2$ Capture by Absorption and Adsorption," Aerosol Air Qual. Res., 12, 745-769(2012).
5 Wang, M., Lawal, A., Stephenson, P., Sidders, J., Ramshaw, C. and Yeung, H., "Post-combustion $CO_2$ Capture with Chemical Absorption: A State-of-the-art Review," Chem. Eng. Res. Des., 89, 1609-1624(2011).   DOI   ScienceOn
6 Cho, Y. M., Nam, S. C., Yoon, Y. I., Moon, S. J. and Beak, I. H., "Degradation of Aqueous Monoethanolamine Absorbent," Appl. Chem. Eng., 21, 195-199(2010).
7 Lee, J. H., Kwak, N. S., Lee, I. Y., Jang, K. R., Jang, S. G., Lee, K. J. and Han, G. S., "Test Bed Studies with Highly Efficient Amine $CO_2$ Solvent (Kosol-4)," Korean Chem,. Eng. Res., 51, 267-271 (2013).   과학기술학회마을   DOI   ScienceOn
8 Jin, Y. R., Jung, Y. H., Park, S. J. and Baek, I. H., "Study of $CO_2$ Absorption Characteristic and Synthesis of 1-(2-methoxyethyl)-3-methylimindazolium Methanesulfonate Ionic Liquid," Korean Chem,. Eng. Res., 50, 35-40(2012).   과학기술학회마을   DOI   ScienceOn
9 Mores, P., Rodriguez, N., Scenna, N. and Mussati, S., "$CO_2$ Capture in Power Plants: Minimization of the Investment and Operating Cost of the Post-combustion Process Using MEA Aqueous Solution," Inter. J. Greenhouse Gas Control., 10, 148-163(2012).   DOI
10 Stephanie, A. F., Jason, D. and Rochelle, G. T., "Degradation of Aqueous Piperazine in Carbon Dioxide Capture," Inter. J. Greenhouse Gas Control., 4, 756-761(2010).   DOI
11 Danckwerts, P. V., "The Reaction of $CO_2$ with Ethanolamines," Chem. Eng. Sci., 34, 443-446(1979).   DOI
12 Conway, W., Wang, X., Fernandes, D., Burns, R., Lawrance, G., Puxty, G. and Maeder, M., "Toward Rational Design of Amine Solutions for PCC Applications: The Kinetics of the Reaction of $CO_2$ (aq) with Cyclic and Secondary Amines in Aqueous Solution," Environ. Sci. Technol., 46, 7422-7429(2012).   DOI
13 Xie, H. B., Zhou, Y., Zhang, Y. and Johnson, J. K., "Reaction Mechanism of Monoethanolamine with $CO_2$ in Aqueous Solution from Molecular," J. Phys. Chem., 114, 11844-11852(2010).   DOI
14 Caplow, M., "Kinetics of Carbamate Formation and Breakdown," J. Am. Chem. Soc., 90, 6795-6803(1969).
15 Prakash, D., Vaidya, E. and Kenig, Y., "$CO_2$-Alkanolamine Reaction Kinetics: A Review of Recent Studies," Chem. Eng. Technol., 30, 1467-1474(2007).   DOI
16 Kim, Y. E., Nam, S. C., Lee, Y. T. and Yoon, Y. I., "Study of $CO_2$ Absorption Characteristics in Aqueous $K_2CO_3$ solution with Homopiperazine," Appl. Chem. Eng., 21, 284-290(2010).
17 Astarita, G., Savage, D. W. and Bisio, A., "Gas Treating with Chemical Solvents," J. Wiley., New York. 1983.
18 Mazinani, S., Samsami, A., Jahanmiri, S. and Sardarian, A., "Experimental Study of Carbon Dioxide Solubility in Aqueous Solutions of Citric Acid at $CO_2$ Low Partial Pressures," Chemical Engineering Transactions, 21, 205-210(2010).
19 Mu oz, D. M., Portugal, A. F., Lozano, A. E. de la Campa, J. G. and de Abajo, J., "New Liquid Absorbents for the Removal of $CO_2$ from Gas Mixtures," Energy & Environmental Science., 2, 883-891(2009).   DOI
20 Nogent, H. and Le Tacon, X., "The Differential Reaction Calorimeter: a Simple Apparatus to Determine Reaction Heat, Heat Transfer Value and Heat Capacity," J. Loss Prev. Process Ind., 15, 445-448(2002).   DOI
21 Nogent, H. and Le Tacon, X., "The Differential Reaction Calorimeter: Examples of Use," J. Loss Prev. Process Ind., 16, 133-139(2003).   DOI
22 Sartori, G. and Savage, D. W., "Sterically Hindered Amines for Carbon Dioxide Removal from Gases," Ind. Eng. Chem. Fundam., 22, 239-249(1983).   DOI
23 Astarita, G., Marrucci, G. and Gioia, F., "The Influence of Carbonation Ratio and Total Amine Concentration on Carbon Dioxide Absorption in Aqueous Monoethanolamine Solutions," Chem. Eng. Sci., 19, 99-103(1964).
24 Jiang, H., Zhang, S. and Xu, Y., "Molecular Complex Piperidine-$CO_2$," African. J. Pure. Appl. Chem., 3, 126-130(2009).
25 Robinson, K., McCluskey, A. and Attalla, M., "An FTIR Spectroscopic Study on the Effect of Molecular Structural Variation on the $CO_2$ Absorption Characteristics of Heterocyclic Amines," Chem. Phys. Chem., 12, 1088-1099(2011).   DOI
26 Oexmann, J. and Kather, A., "Minimising the Regeneration Heat Duty of Post-combustion $CO_2$ Capture by Wet Chemical Absorption: The Misguided Focus on Low Heat of Absorption Solvents," Inter. J. Greenhouse Gas Control., 4, 36-43(2010).   DOI