• 제목/요약/키워드: Carbon concentration

검색결과 3,787건 처리시간 0.035초

Adsorption behaviour of film-forming amine on pre-oxidized carbon steel surface

  • Genxian, Lin;Yun, Sun;Canshuai, Liu;Jun, Fang;Lijun, Song;Bin, Liu
    • Nuclear Engineering and Technology
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    • 제54권4호
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    • pp.1185-1194
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    • 2022
  • The maintenance of condenser main pipe is the key to achieve film-forming amine maintenance effectiveness. In this work, oxygen content, pH and temperature of the solution were controlled to simulate the condition of condenser main pipe, and magnetite coated carbon steel sample was prepared by pre-oxidization. CAM was used to characterize the hydrophobicity of film formed samples. Hydrophobic film was formed on pre-oxidized carbon steel samples when octadecylamine concentration reaches 20 mg/kg. SEM, EDS, EIS, and PD were used to characterize the influence of octadecylamine concentration on maintenance effectiveness. It was found that the maintenance effectiveness was enhanced and the corrosion rate was suppressed with the increase of octadecylamine concentration. FIB and TEM were used to detect the adsorbed octadecylamine film thickness founding that octadecylamine adsorbed onto the surface of pre-oxidized carbon steel by multi-layer adsorption mechanism.

분말활성탄 혼입률에 따른 수성도료의 특성 (Properties of Water-Based Paint According to the Mixing Ratio of Powdered Activated Carbon)

  • 최병철;경인수;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 가을 학술논문 발표대회
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    • pp.48-49
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    • 2020
  • Recently, as people's interest in environmental pollution increases, interest in indoor air pollution as well as outdoors is increasing. Accordingly, this study prepares functional paints by mixing powder activated carbon, which is a porous material, into aqueous paints, and examines the adsorption performance of volatile organic compounds (VOCs) and formaldehyde (HCHO). As a result of the experiment, the concentration of volatile organic compounds (VOCs) and formaldehyde (HCHO) tended to decrease as powder activated carbon was incorporated. It is believed that physical adsorption was achieved by the micropores of powdered activated carbon. However, in the adsorption test method, it is judged that the concentration was affected by the inflow of outside air as the chamber cover was opened to put the test object in the empty chamber where a certain concentration was maintained.

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적외선과 초음파 센서로 측정한 순천만 이산화탄소 변동 (Carbon Dioxide Fluctuation in Suncheon Bay Measured by Infrared and Ultrasonic sensors)

  • 김상진;김민성;이경훈;권병혁;윤홍주
    • 한국전자통신학회논문지
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    • 제16권1호
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    • pp.157-164
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    • 2021
  • 순천만 갯벌에서 3차원 초음파풍속계로 바람과 기온을 측정하고, 적외선 센서를 이용하여 이산화탄소 농도를 측정하였다. 일반적으로 기온이 증가하면 대기 중의 이산화탄소 농도가 증가하고, 기온이 감소하면 이산화탄소도 감소한다. 그러나 일몰 직후에는 광합성이 줄어들기 때문에, 기온이 감소함에도 이산화탄소 농도는 증가하였다. 또한 갯벌이 해수로 덮이게 되는 고조기에는 기온 증가에도 불구하고 대기 난류가 강하게 나타나 이산화탄소 농도가 감소하였다. 이산화탄소의 농도 변화에 미치는 갯벌 생태계의 광합성과 호흡 그리고 대기 난류의 영향에 대한 정량적 평가가 필요하다.

남강 및 금호강에서 유기탄소 존재형태와 분해속도와의 관계 (The Relationship between the Fractionation Characteristics and Decomposition Rate of Organic Carbon in Nam River and Geumho River)

  • 김호섭;김석규;오승영
    • 한국물환경학회지
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    • 제39권2호
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    • pp.131-141
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    • 2023
  • In this study, the relationship between organic carbon distribution characteristics and decomposition rate classified according to the particle size and biological degradation characteristics in water was investigated for the Nam river and Geumho river. The average concentrations of TOC in the Nam river and Geumho river were 2.7±1.2 mg/L and 5.0±1.2 mg/L, respectively, but the composition ratios for each type of organic carbon were similar. An average value of 80.9% of TOC was present as DOC and 72.8% of DOC consisted of Refractory-DOC (RDOC). In addition, the change in the RDOC composition ratio according to temporal and spatial distribution was the smallest. There was no difference in the decomposition rate of organic carbon except for TOC by the site (p≥0.108, one-way ANOVA), and the decomposition rates of Labile-POC (LPOC) and LDOC were similar at 0.139±0.102 and 0.137±0.149 day-1, respectively (p=0.110, paired t-test). The coefficient of variation (CV) of the decomposition rate of DOC (average 8.1%), which had the smallest composition ratio of organic carbon, was 1.1, showing the largest temporal variation. The TOC, POC, and DOC decomposition rates showed a significant correlation with the ratio of the initial concentration to the concentration after 25 days of decomposition (OC25/OC0) (r2=0.89~0.94, p<0.001), and the decomposition rates of LPOC and LDOC were significantly correlated with the ratio of the initial concentration to the concentration after 5 days of decomposition (LOC5/LOC0) (r2=0.67~0.75). This suggests that it is possible to estimate the decomposition rate through the concentration of each type of organic carbon.

활성탄과 가소제가 탄소복합필터의 경도에 미치는 영향 (Effect of Triacetin and Activated Carbon on the Hardness of Cellulose Acetate Filter containing Activated Carbon)

  • 신창호;김종열;김정열;김영호;이영택
    • 한국연초학회지
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    • 제22권2호
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    • pp.157-163
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    • 2000
  • Filter hardness is important to filter and cigarette manufactures because it is directly related to the ability of a plugmaker during making filter and to the acceptability of the filter by the consumer. In general, glycerol triacetate(Triacetin, TA) is the currently used common plasticizer in making filters from cellulose acetate tow and the effect of triacetin on hardness of filter which is made of mono cellulose acetate tow was well known. But unfortunately, the effect of triacetin on the hardness of cellulose acetate filter containing ativated carbon(carbon filter) was not reported so far. In this study, we manufactured filters with various carbon content at different triacetin concentrations and then analyzed the filter hardness and pressure drop. Filter hardness was directly increased with triacetin concentration but pressure drop was not affected and the effect of carbon content on filter hardness was smaller than that of triacetin concentration. However, pressure drop was directly increased with carbon content.

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Global Carbon Budget and Ocean Buffering against Rising Atmospheric CO2 Concentration

  • Kwon, O-Yul
    • 한국환경과학회지
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    • 제11권8호
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    • pp.773-781
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    • 2002
  • The natural carbon cycle has been perturbed since the mid-19th century by anthropogenic CO$_2$emissions from fossil fuel combustion and deforestation due to population growth and industrialization. The current study simulated the global carbon cycle for the past 42 years using an eight-box carbon cycle model. The results showed that since the terrestrial biospheric carbon sink was roughly offset by the deforestation source, the fossil fuel emission source was partitioned between the atmospheric and oceanic sinks. However, the partitioning ratio between the atmosphere and the ocean exhibited a change, that is, the carbon accumulation rate was faster in the atmosphere than in the ocean, due to a decrease in the so-called ocean buffering capacity. It was found that the ocean buffering capacity to take up excess CO$_2$decreased by 50% in terms of the buffer factor over the past 42 years. Accordingly, these results indicate that if the current CO$_2$emission trend continues, the future rate of increase in the atmospheric CO$_2$concentration will accelerate.

고정 파이프라인에서 분사된 액체 이산화탄소 용해특성 연구 (Study on the Dissolution Characteristics of Liquid $CO_2$ Released by Fixed Pipeline)

  • 김남진;김종보
    • 설비공학논문집
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    • 제16권9호
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    • pp.863-871
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    • 2004
  • The use of fossil fuels like coal, oil and natural gases around the world causes an increase of the carbon dioxide content in the atmosphere. In order to reduce the concentration of the greenhouse gas, the idea of carbon dioxide sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect. Therefore, in the present study, calculations of the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth by fixed pipeline are performed. The results show that carbon dioxide droplets change to carbon dioxide bubbles in gas phase around 500m in depth, and the droplets are completely dissolved below 500 m in depth if the liquide carbon dioxide is released both at 1,000 m in depth with the initial diameter of 0.007m or less and at 1,500m in depth with the diameter of 0.011m or less.

1991~2004년 동아시아에서 관측한 일산화탄소의 지역적 배경 농도 (Regional Background Levels of Carbon Monoxide Observed in East Asia during 1991~2004)

  • 김학성;정용승
    • 한국지구과학회지
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    • 제27권6호
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    • pp.643-652
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    • 2006
  • 동아시아에서 일산화탄소의 지역적 배경 농도 수준을 분석하기 위해, 1991년부터 2004년까지 장기간 중국 Waliguan(WLG), 몽골이아의 Ulaan Uul(UUM), 한국의 태안반도(TAP), 일본의 Ryori(RYO)에서 관측한 일산화탄소 농도를 분석하였다. 연평균 일산화탄소 농도는 $WLG(135{\pm}22ppb),\;UUM(155{\pm}26ppb),\;RYO(171{\pm}36ppb),\;TAP(233{\pm}41ppb)$ 순서로 높은 농도를 보이고 있었다. WLG를 제외하고 전체적으로 봄철에 높고 여름철에 낮은 계절 변동의 특징은 동아시아 다른 지점들에서도 공통적으로 나타나고 있다. TAP는 WLG, UUM, RYO와 비교하여 전체 계절에 높은 일산화탄소 농도를 보이고 있으며 히스토그램에서 넓은 농도 분포를 보이는데 동아시아 대륙, 특히 중국의 가까운 풍하측에 위치하고 있어 광역적 대기 오염의 영향이 크기 때문이다. TAP는 중국 동부 지역을 경유하는 RPC가 봄, 가을, 겨울에서 높은 농도를 나타내었고, 여름철에는 저위도 북태평양으로부터의 OBG에 의해 낮은 일산화탄소 농도를 갖고 있는 해양성 기단의 영향을 받고 있다. NOAA 위성 영상과 GEOS-CHEM 모델 시뮬레이션은 중국 남동부 연안으로부터 황해를 거쳐 한반도와 동해로 확산하고 있는 광역적 대기오염 이동 사례를 확인하고 있다.

Tumbling Bed에서 화학증착법에 의해 증착되는 열분해탄소의 특성에 미치는 Silicon-Alloying의 효과 (The Effect of Silicon-Alloying on the Characteristics of the Pyrolytic Carbonds Deposited in Tumbling Bed by CVD)

  • 윤영진;이재영
    • 한국세라믹학회지
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    • 제20권2호
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    • pp.166-172
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    • 1983
  • In this study the sillicon-alloyed isotropic pyrolytic carbon was deposited in the tumbling bed from the pyrolysis of propane and silicon tetrachloride and investigated whether the silicon-alloyed isotropic pyrolytic carbon deposited in this study was usable as bionaterial or not. The silicon-allyed isotropic pyrolytic carbon was varied by controlling the process variables such as propane con-concentration and the argon flow rate flowing in to the silicon tetrachloride bubbler at a fixed reaction bed tempera-ture of 120$0^{\circ}C$ a rotation of reaction tube of 40 rpm a bed particle weight of 7.5 g and a total flow rate of 21/min; the propane concentration was varied from 10 to 70 and the argon flow rate flowing into the silicon tetrachloride bubble from 0 to 1000 cc/min. The results show that the silicon-alloyed isotropic pyrolytic carbon was obtained at all conditions investigated, . And then the alloyed silicon content is rangion from 7 to 14.5 wt%. The density and deposition rate of deposited silicon-alloyed isotropic carbon increased axxording to silicon content and propane concentration. And the apparent crystal-size(Lc) of pyrolytic carbon is not changed with silicon content. The density and apparant crystallite size are respec-tively in the range of 1.94 to 2.06 and 20 to 25$\AA$ It is shown that the silicon-alloyed isotropic pyrolytic carbon ob-tained in this experiment is usable as biomaterial.

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충청지역 블랙카본 농도 측정 및 PM10, PM2.5 농도와의 비교 분석 연구 (Measurement of Black Carbon Concentration and Comparison with PM10 and PM2.5 Concentrations monitored at the Chungcheong Province in Korea.)

  • 차영범;이시형;이정훈
    • 한국입자에어로졸학회지
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    • 제13권2호
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    • pp.97-104
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    • 2017
  • In order to characterize atmospheric aerosols in Chungcheong area, black carbon concentration, which is known to be closely related to global warming, was measured and compared with $PM_{10}$, $PM_{2.5}$ concentrations and various meteorological parameters such as wind velocity and wind direction. Multi Angle Absorption Photometer (MAAP), a filter-based equipment, was used for the black carbon measurement, and the $PM_{10}$, $PM_{2.5}$ concentrations, wind velocity and wind direction were provided by the local monitoring stations. Black carbon concentration was monitored to be high in spring and winter but low in fall. $PM_{10}$ concentration was observed to be high when westerly wind was strong.