• Title/Summary/Keyword: Carbon composite

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In vitro evaluation of nano zinc oxide (nZnO) on mitigation of gaseous emissions

  • Sarker, Niloy Chandra;Keomanivong, Faithe;Borhan, Md.;Rahman, Shafiqur;Swanson, Kendall
    • Journal of Animal Science and Technology
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    • v.60 no.11
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    • pp.27.1-27.8
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    • 2018
  • Background: Enteric methane ($CH_4$) accounts for about 70% of total $CH_4$ emissions from the ruminant animals. Researchers are exploring ways to mitigate enteric $CH_4$ emissions from ruminants. Recently, nano zinc oxide (nZnO) has shown potential in reducing $CH_4$ and hydrogen sulfide ($H_2S$) production from the liquid manure under anaerobic storage conditions. Four different levels of nZnO and two types of feed were mixed with rumen fluid to investigate the efficacy of nZnO in mitigating gaseous production. Methods: All experiments with four replicates were conducted in batches in 250 mL glass bottles paired with the ANKOM$^{RF}$ wireless gas production monitoring system. Gas production was monitored continuously for 72 h at a constant temperature of $39{\pm}1^{\circ}C$ in a water bath. Headspace gas samples were collected using gas-tight syringes from the Tedlar bags connected to the glass bottles and analyzed for greenhouse gases ($CH_4$ and carbon dioxide-$CO_2$) and $H_2S$ concentrations. $CH_4$ and $CO_2$ gas concentrations were analyzed using an SRI-8610 Gas Chromatograph and $H_2S$ concentrations were measured using a Jerome 631X meter. At the same time, substrate (i.e. mixed rumen fluid+ NP treatment+ feed composite) samples were collected from the glass bottles at the beginning and at the end of an experiment for bacterial counts, and volatile fatty acids (VFAs) analysis. Results: Compared to the control treatment the $H_2S$ and GHGs concentration reduction after 72 h of the tested nZnO levels varied between 4.89 to 53.65%. Additionally, 0.47 to 22.21% microbial population reduction was observed from the applied nZnO treatments. Application of nZnO at a rate of $1000{\mu}g\;g^{-1}$ have exhibited the highest amount of concentration reductions for all three gases and microbial population. Conclusion: Results suggest that both 500 and $1000{\mu}g\;g^{-1}$ nZnO application levels have the potential to reduce GHG and $H_2S$ concentrations.

Characteristics of a CFRP Cruiser's Windage Area by Stability Assessment (탄소섬유강화복합재료(CFRP) 레저선박의 횡요저항력 평가에 의한 상부구조물 풍압면적 특성)

  • Kim, Do-Yun;Lee, Chang-Woo;Lee, Dong-Kun;Oh, Dae-Kyun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.6
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    • pp.774-780
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    • 2014
  • This research aims to investigate the superstructure characteristics of the CFRP-yachts whose hulls are made of the light-weight material CFRP. CFRP-yachts, which belong to light-weight yachts, have a tendency of having very small superstructures compared to other vessels of the same length, and such a tendency is closely related to stability. In this research, a comparison of shape characteristics was made between common composite-plastic yachts and CFRP-yachts to find out the shape characteristics of CFRP-yacht. In the meantime, a case study was conducted concerning shape changes in superstructure to understand the effect of such changes on stability. For this purpose the shapes of a total of 10 GFRP-yachts and CFRP-yachts were comparatively analyzed, and the result showed the tendency of their hulls and superstructures. Whereas the case study on stability assessment involved various superstructure shapes of CFRP yachts, for assessment by superstructure size. Stability assessment was according to ISO 12217 (Small craft Stability and buoyancy assessment and categorization). A program was also developed based on stability assessment process due to rolling in beam waves and wind, and it was applied to the case study. The result of the case study showed that the windage area distribution tendency of the yachts whose hulls were made of the light-weight material CFRP was similar to that of the GFRP-yachts, but that the superstructure shapes of the CFRP-yachts were about 50% smaller than those of the GFRP-yachts. In addition, the stability assessment involving various superstructure areas of the CFRP-yachts showed that problems with stability occurred when their superstructure sizes were similar to, or larger by about 10% than, those of the GFRP-yachts.

Flexible Unit Floor Plan of Off-Site Construction Housing Considering Long-Lasting Housing Certification System (장수명주택 인증을 고려한 OSC공법 주택의 가변형 평면계획 연구)

  • Lee, Ji-Eun;Roh, Jeong-Yeol;Kwon, Soo-Hye;Kim, Seung-Mo
    • Land and Housing Review
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    • v.12 no.4
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    • pp.103-117
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    • 2021
  • With the current rapid changes in population and technology, the long-lastig housing certification system is a means of prolonging the physical and functional lifespan of a building. The certification requires differentiation between the structure and infill elements to allow for variability and ease of repairs. This works well with prefabricated houses so this study investigated the possibility of applying the long-lastig housing certification requirements to apartment construction using off-site construction (OSC) methods focused on the installation of bathrooms (plumbing and toilet) that differ from the traditional wet method. This study examined three different sized floor plans at 22 m2, 46 m2, and a combined one resulting in 69 m2. The larger 69 m2 plan utilized a removeable non-load bearing wall to increase flexibility in the layout of the floorplan. The apartments are constructed of steel reinforced concrete composite columns on a 9 m × 10.5 m grid with integrated slabs. The exterior and interior infill walls are all non-load bearing with some containing plumbing. This separation of the structure and infill walls can help meet some of the criteria in the long-lastig housing certification, particularly with the ease of repairs. Technologies that facilitate the replacement of infill elements that contain plumbing and other building services can benefit the nation by reducing carbon emissions and therefore tax incentives should be introduced to increase the adoption of the proposed construction methods.

Application of Porous Nanofibers Comprising Hollow α-Fe2O3 Nanospheres Prepared by Applying Both PS Template and Kirkendall Diffusion Effect for Anode Materials in Lithium-ion Batteries (커켄달 효과와 주형법을 통해 합성한 α-Fe2O3 중공입자로 구성된 다공성1차원 구조체의 리튬 이차전지 음극활물질 적용)

  • Lee, Young Kwang;Jeong, Sun Young;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.819-825
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    • 2018
  • Porous nanofibers comprising hollow ${\alpha}-Fe_2O_3$ nanospheres were prepared by applying both template method and Kirkendall diffusion effect to electrospinning process. During heat-treatment processes, the solid Fe nano-metals formed by initial heat-treatment in the carbon matrix were converted into the hollow structured ${\alpha}-Fe_2O_3$ nanospheres. In particular, PS nanobeads added in the spinning solution were decomposed and formed numerous channels in the composite, which served as a good pathway for Kirkendall diffusion gas. The resulting porous nanofibers comprising hollow ${\alpha}-Fe_2O_3$ nanospheres were applied as an anode material for lithium-ion batteries. The discharge capacities of the nanofibers for the 30th cycle at a high current density of $1.0A\;g^{-1}$ was $776mA\;h\;g^{-1}$. The good lithium ion storage property was attributed to the synergetic effects of the hollow ${\alpha}-Fe_2O_3$ nanospheres and the interstitial nanovoids between the nanospheres. The synthetic method proposed in this study could be applied to the preparation of porous nanofibers comprising hollow nanospheres with various composition for various applications, including energy storage.

Flexural Strengthening Effects of RC Beam Reinforced with Pre-stressing Plate (긴장을 가한 보강 플레이트로 보강된 RC 보의 휨보강 효과)

  • Ha, Sang-Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.171-178
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    • 2019
  • Fiber-reinforced polymer (FRP) composites have proved to be reliable as strengthening materials. Most of existing studies used single types of FRP composites. Therefore, in this experimental study, carbon FRP sheet, aramid FRP sheet, and hybrid FRP plate including glass fibers were fabricated, and the effect of pre-stressed FRP composites on flexural strengthening of reinforced concrete (RC) beams was investigated. In total, eight RC beam specimens were fabricated, including one control beam (specimen N) without FRP composites and seven FRP-strengthened beams. The main parameters were type of FRP composite, the number of anchors used for pre-stressing, and thickness of FRP plates. As a result, the beam strengthened with pre-stressed FRP plate showed superior performance to the non-strengthened one in terms of initial strength, strength and stiffness at yielding, and ultimate strength. As the number of anchors and thickness of FRP plate (i.e., amount of FRP plates) increased, the strengthening effect increased as well. When hybrid FRP plates were pre-stressed, the strengthening effect was higher in comparison with pre-stressed single type FRP plate.

Research Trends of Polybenzimidazole-based Polymer Electrolyte Membranes for High-temperature Polymer Electrolyte Membrane Fuel Cells (고온 구동형 고분자 전해질 막 연료전지용 폴리벤즈이미다졸계 고분자 전해질 막의 개발 동향)

  • HyeonGyeong, Lee;Gabin, Lee;Kihyun, Kim
    • Membrane Journal
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    • v.32 no.6
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    • pp.442-455
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    • 2022
  • High-temperature polymer electrolyte membrane fuel cell (HT-PEMFC) has been studied as an alternative to low-temperature PEMFC due to its fast activation of electrodes and high resistance to electrode poisoning by carbon monoxide. It is highly required to develop stable PEMs operating at high temperatures even doped by ion-conducting materials for the development of high-performance and durable HT-PEMFC systems. A number of studies have been conducted to develop polybenzimidazole (PBI)-based PEMs for applications in HT-PEMFC due to their high interaction with doped ion-conducting materials and outstanding thermomechanical stability under high-temperature operation. This review focused on the development of PBI-based PEMs showing high performance and durability. Firstly, the characteristic behavior of PBI-based PEMs doped with various ion-conducting materials including phosphoric acid was systematically investigated. And then, a comparison of the physicochemical properties of the PEMs according to the different membrane manufacturing processes was conducted. Secondly, the incorporation of porous polytetrafluoroethylene substrate and/or inorganic composites to PBI matrix to improve the membrane performances was studied. Finally, the construction of cross-linked structures into PBI-based PEM systems by polymer blending method was introduced to improve the PEM properties.

Synthesis of porous-structured (Ni,Co)Se2-CNT microsphere and its electrochemical properties as anode for sodium-ion batteries (다공성 구조를 갖는 (Ni,Co)Se2-CNT microsphere의 합성과 소듐 이차전지 음극활물질로서의 전기화학적 특성 연구)

  • Yeong Beom Kim;Gi Dae Park
    • Clean Technology
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    • v.29 no.3
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    • pp.178-184
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    • 2023
  • Transition metal chalcogenides have garnered significant attention as anode materials for sodium-ion batteries due to their high theoretical capacity. Nevertheless, their practical application is impeded by their limited lifespan resulting from substantial volume expansion during cycling and their low electrical conductivity. To tackle these issues, this study devised a solution by synthesizing a nanostructured anode material composed of porous CNT (carbon nanotube) spheres and (Ni,Co)Se2 nanocrystals. By employing spray pyrolysis and subsequent heat treatments, a porous-structured (Ni,Co)Se2-CNT composite microsphere was successfully synthesized, and its electrochemical properties as an anode for sodium-ion batteries were evaluated. The synthesized (Ni,Co)Se2-CNT microsphere possesses a porous structure due to the nanovoids that formed as a result of the decomposition of the polystyrene (PS) nanobeads during spray pyrolysis. This porous structure can effectively accommodate the volume expansion that occurs during repeated cycling, while the CNT scaffold enhances electronic conductivity. Consequently, the (Ni,Co)Se2-CNT anode exhibited an initial discharge capacity of 698 mA h g-1 and maintained a high discharge capacity of 400 mA h g-1 after 100 cycles at a current density of 0.2 A g-1.

New Method for Combined Quantitative Assessment of Air-Trapping and Emphysema on Chest Computed Tomography in Chronic Obstructive Pulmonary Disease: Comparison with Parametric Response Mapping

  • Hye Jeon Hwang;Joon Beom Seo;Sang Min Lee;Namkug Kim;Jaeyoun Yi;Jae Seung Lee;Sei Won Lee;Yeon-Mok Oh;Sang-Do Lee
    • Korean Journal of Radiology
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    • v.22 no.10
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    • pp.1719-1729
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    • 2021
  • Objective: Emphysema and small-airway disease are the two major components of chronic obstructive pulmonary disease (COPD). We propose a novel method of quantitative computed tomography (CT) emphysema air-trapping composite (EAtC) mapping to assess each COPD component. We analyzed the potential use of this method for assessing lung function in patients with COPD. Materials and Methods: A total of 584 patients with COPD underwent inspiration and expiration CTs. Using pairwise analysis of inspiration and expiration CTs with non-rigid registration, EAtC mapping classified lung parenchyma into three areas: Normal, functional air trapping (fAT), and emphysema (Emph). We defined fAT as the area with a density change of less than 60 Hounsfield units (HU) between inspiration and expiration CTs among areas with a density less than -856 HU on inspiration CT. The volume fraction of each area was compared with clinical parameters and pulmonary function tests (PFTs). The results were compared with those of parametric response mapping (PRM) analysis. Results: The relative volumes of the EAtC classes differed according to the Global Initiative for Chronic Obstructive Lung Disease stages (p < 0.001). Each class showed moderate correlations with forced expiratory volume in 1 second (FEV1) and FEV1/forced vital capacity (FVC) (r = -0.659-0.674, p < 0.001). Both fAT and Emph were significant predictors of FEV1 and FEV1/FVC (R2 = 0.352 and 0.488, respectively; p < 0.001). fAT was a significant predictor of mean forced expiratory flow between 25% and 75% and residual volume/total vital capacity (R2 = 0.264 and 0.233, respectively; p < 0.001), while Emph and age were significant predictors of carbon monoxide diffusing capacity (R2 = 0.303; p < 0.001). fAT showed better correlations with PFTs than with small-airway disease on PRM. Conclusion: The proposed quantitative CT EAtC mapping provides comprehensive lung functional information on each disease component of COPD, which may serve as an imaging biomarker of lung function.

A Strategy of a Gap Block Design in the CFRP Double Roller to Minimize Defects during the Product Conveyance (제품 이송 시 결함 최소화를 위한 CFRP 이중 롤러의 Gap block 설계 전략)

  • Seung-Ji Yang;Young-june Park;Sung-Eun Kim;Jun-Geol Ahn;Hyun-Ik Yang
    • Composites Research
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    • v.37 no.1
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    • pp.7-14
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    • 2024
  • Due to the structural characteristic of a double roller, the double roller can have various deformation behaviors depending on a gap block design, even if dimensions and loading conditions for the double roller are the same. Based on this feature, we propose a strategy for designing the gap block of the carbon-fiber reinforced plastic (CFRP) double roller to minimize defects (e.g., sagging and wrinkling), which can be raised during the product conveying process, with the pursue of the lightweight design. In the suggested strategy, analysis cases are first selected by considering main design parameters and engineering tolerances of the gap block, and then deformation behaviors of these selected cases are extracted using the finite element method (FEM). Here, to obtain the optimal gap block parameters that satisfy the purpose of this study, deformation deviations in the contact area are calculated and compared using the extracted deformation behaviors. Note that the contact area in this work is located between the product and the roller. As a result, through the design method of the gap block proposed in this work, it is possible to construct the CFRP double roller that can significantly decrease the defects without changing the overall sizes of the roller. A detailed method is suggested herein, and the results are evaluated in a numerical way.

Performance Analysis of CFRP Rear Spoiler according to Types of Inner Foam Core under High-speed Driving Condition (고속 주행 상황에서 CFRP 리어 스포일러의 내부 폼 코어 종류에 따른 성능 분석)

  • Sung-Eun Kim;Jun-Geol Ahn;Moon-Sung Kim;Seung-Ji Yang;Ki-Young Kim;Hyun-Ik Yang
    • Composites Research
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    • v.37 no.2
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    • pp.86-93
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    • 2024
  • The inner foam structure plays an important role in the performance of the carbon-fiber-reinforced plastic (CFRP) rear spoiler used in automobiles. However, there is still a lack of studies for the CFRP-based rear spoiler according to the type of inner foam, especially under the high-speed driving condition. With this motivation, we numerically analyze the performance of the CFRP rear spoiler using various cases of the inner foam under the highspeed driving condition. Here, polymethacrylimide (PMI), polyvinyl chloride (PVC), and styrene acrylonitrile (SAN) resins are employed as the inner foams in this work. The performances are evaluated using the deformation aspects and vibration characteristics when the driving condition is a high-speed condition (200 km/h). Furthermore, to specifically verify the importance of the inner foam in the high-speed condition, we additionally investigate the performance of the CFRP rear spoiler without the inner foam structure (i.e., hollow type). As a result, it is confirmed that among the types of inner foams utilized in this work, the PMI and PVC inner foams have the best deformation aspect and vibration characteristic, respectively. Note that the hollow-type inner foam has inferior performances compared to other inner foams invoked in this study. Consequently, through this study, it can be confirmed that the inner foam structure can significantly improve the performance of the CFRP spoiler under high-speed driving condition (200 km/h), and also that the strengths of the CFRP spoiler can manifest differently depending on the types of inner foam core.