• 한국분말재료학회지
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• 제25권5호
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• pp.435-440
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• 2018

In the present study, we develop a conductive copper/carbon nanomaterial additive and investigate the effects of the morphologies of the carbon nanomaterials on the conductivities of composites containing the additive. The conductive additive is prepared by mechanically milling copper powder with carbon nanomaterials, namely, multi-walled carbon nanotubes (MWCNTs) and/or few-layer graphene (FLG). During the milling process, the carbon nanomaterials are partially embedded in the surfaces of the copper powder, such that electrically conductive pathways are formed when the powder is used in an epoxy-based composite. The conductivities of the composites increase with the volume of the carbon nanomaterial. For a constant volume of carbon nanomaterial, the FLG is observed to provide more conducting pathways than the MWCNTs, although the optimum conductivity is obtained when a mixture of FLG and MWCNTs is used.

• Advances in nano research
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• 제16권1호
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• pp.53-69
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• 2024

Advancements in the technology of building materials has led to diverse applications of nanomaterials with the aim to monitor concrete structures. While there are myriad instances of the use of nanoparticles in building materials, the production of smart nano cement-composites is often expensive. Thereupon, this research aims to discover a sustainable nanomaterial from tyre waste using the pyrolysis process as part of the green manufacturing circle. Here, Nano Structure Tyre-Char (NSTC) is introduced as a zero-dimension carbon-based nanoparticle. The NSTC particles were characterized using various standard characterization techniques. Several salient results for the NSTC particles were obtained using microscopic and spectroscopic techniques. The size of the particles as well as that of the agglomerates were reduced significantly using the milling process and the results were validated through a scanning electron microscope. The crystallite size and crystallinity were found to be ~35nm and 10.42%, respectively. The direct bandgap value of 5.93eV and good optical conductivity at 786 nm were obtained from the ultra violet visible spectroscopy measurements. The thermal analysis reveals the presence of a substantial amount of carbon, the rate of maximum weight loss, and the two stages of phase transformation. The FT-Raman confirms the presence of carboxyl groups and a ID/IG ratio of 0.83. Water contact angle around 140° on the surface implies the highly hydrophobic nature of the material and its low surface energy. This characteristic process assists to obtain a sustainable nanomaterial from waste tyres, contributing to the development of a smart building material.

• Transactions on Electrical and Electronic Materials
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• 제13권4호
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• pp.165-170
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• 2012

One-dimensional, nanomaterial field effect transistors (FET) are promising sensors for bio-molecule detection applications. In this paper, we review fabrication and characteristics of 1-D nanomaterial FET type biosensors. Materials such as single wall carbon nanotubes, Si nanowires, metal oxide nanowires and nanotubes, and conducting polymer nanowires have been widely investigated for biosensors, because of their high sensitivity to bio-substances, with some capable of detecting a single biomolecule. In particular, we focus on three important aspects of biosensors: alignment of nanomaterials for biosensors, surface modification of the nanostructures, and electrical detection mechanism of the 1-D nanomaterial sensors.

• 한국표면공학회지
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• 제53권4호
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• pp.160-168
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• 2020

A polymer-based carbon nanomaterial composite was fabricated and characterized for the application of a thermal conductive adhesive. Low-dimensional carbon nanomaterials with excellent thermal conductivity such as carbon nanotube (CNT) and graphene were selected as a filler in the composite. Thermal, electrical and adhesive properties of the composite were investigated with respect to the morphology and content of the low-dimensional carbon nanomaterials. As a result, the composite-based adhesive fabricated by the loading of surface-treated MWCNTs of 0.4 wt% showed uniform dispersion, moderate adhesion and effective heat dissipation properties. Finally, it was confirmed through the thermal image analysis of LED module that the temperature reduction of 10℃ was achieved using the fabricated composite adhesive with MWCNT-6A. Expecially, heat dissipation performance of the optimized composite adhesive was evident at the hot spot in the module compared to other samples mixed with graphene or different MWCNT loading ratios.

• Elastomers and Composites
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• 제52권1호
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• pp.69-80
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• 2017

Conducting polymers and carbon nanomaterials offer a wide range of applications because of their unique soft conducting properties. Specifically, these conducting polymer-carbon nanocomposites have recently been utilized in bioengineering applications, partly because of their improved biocompatibility compared to conventional conducting materials such as metals and ceramics. Based on the assumption that these composites offer an important application potential as functional materials for biomedical devices or even as biomaterials, this review surveys the recent research trends on conducting polymers-carbon nanocomposites, focusing on bioengineering applications such as polyaniline (PANI), poly(3,4-ethylenedioxythiophene) or PEDOT, polypyrrole (Ppy), and carbon nanotubes and graphene.

• Carbon letters
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• 제15권4호
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• pp.268-276
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• 2014

Recently, methods that usea carbon-based filler, a conductive nanomaterial, have been investigated to develop composite fillers containing dielectric materials. In this study, we added geometric changes to a carbon fiber, a typical carbon-based filler material, by differentiating the orientation angle and the number of plies of the fiber. We also studied the electrical and electromagnetic shield characteristics. Based on the orientation angle of $0^{\circ}$, the orientation angle of the carbon fiber was changed between 0, 15, 30, 45, and $90^{\circ}$, and 2, 4, and 6 plies were stacked for each orientation angle. The maximum effect was found when the orientation angle was $90^{\circ}$, which was perpendicular to the electromagnetic wave flow, as compared to $0^{\circ}$, in which case the electrical resistance was small. Therefore, it is verified that the orientation angle has more of an effect on the electromagnetic interference shield performance than the number of plies.

• Transactions on Electrical and Electronic Materials
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• 제16권4호
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• pp.198-200
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• 2015

The microwave plasma enhanced chemical vapor deposition (PECVD) system was used to grow a carbon nanowall (CNW) on a silicon (Si) substrate with hydrogen (H₂) and methane (CH₄) gases. To find the growth mechanism of CNW, we increased the growth time of CNW from 5 to 30 min. The vertical and surficial conditions of the grown CNWs according to growth time were characterized by field emission scanning electron microscopy (FE-SEM). Energy dispersive spectroscopy (EDS) measurements showed that the CNWs consisted solely of carbon.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.185-186
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• 2023

Recently, a lot of nano-scale material technology development and research have been conducted in construction fields to improve the compressive strength and durability of cement-based Composites. There are some studies that have confirmed the properties and application effects of cement-based complex using each nanomaterial, but development and research using both materials are relatively limited. This study sought to confirm the effect of multi-wall carbon nanotubes (MWCNT) and nanosilica, which are representative construction nanomaterials, on the compressive strength, voids, and microstructure formation of cement. The purpose was to produce a cement composite by changing the mixing rate of the two nanomaterials, and to find the optimal mixing amount considering its mechanical and rheological properties.

• 공업화학
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• 제35권3호
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• pp.155-181
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• 2024

최근, 기존 분리막의 성능을 향상시켜 CO₂ 분리를 효율적으로 수행하기 위한 중요한 연구가 진행되고 있다. 이는 탄소포집 공정에서의 활용을 확대하는 것을 목표로 하고 있다. 분리막 기술은 비용 및 에너지 효율성, 연속 운전, 작은 공정 크기 등의 장점으로 인해 탄소제로 이슈에 대처하는 유망한 탄소 포집 기술로 부상하고 있다. 연구된 여러 종류의 분리막 중 혼합기질막(mixed-matrix membrane, MMM)이 전반적인 가스 분리 공정의 효율을 향상시킬 수 있는 전통적인 분리막의 대안으로 제안되었다. 2D 나노소재는 쉬운 개질과 기능화, 다른 재료와의 결합 등 특징적인 성질로 인해 다양한 일반적인 2D 나노소재들이 가스 분리를 위한 효율적인 MMMs 제작에 사용되고 있다. 본 논문은 2D 나노소재를 사용한 MMMs 분야의 최근 발전을 검토하였다. 또한, CO₂ 분리 및 포집을 위한 2D 나노소재 기반 분리막의 현재 도전과 전망을 논의하였다.

• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.175-186
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• 2018

Carbon nanomaterials (CNMs), particularly carbon nanotube and graphene-based materials, are rapidly emerging as one of the most effective adsorbents for wastewater treatment. CNMs hold great potential as new generation adsorbents due to their high surface to volume ratio, as well as extraordinary chemical, mechanical and thermal stabilities. However, implementation of pristine CNMs in real world applications are still hindered due to their poor solubility in most solvents. Hence, surface modification of CNMs is essential for wastewater treatment application in order to improve its solubility, chemical stability, fouling resistance and efficiency. Numerous studies have reported the applications of functionalized CNMs as very promising adsorbents for treating organic and inorganic wastewater pollutants. In this paper, the removal of organic dye and phenol contaminants from wastewater using various type of functionalized CNMs are highlighted and summarized. Challenges and future opportunities for application of these CNMs as adsorbents in sustainable wastewater treatment are also addressed in this paper.