• Title/Summary/Keyword: Carbon Nanotube, CNT

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Study of Surface Treatments on Field Emission Properties for Triode-Type Carbon Nanotube Cathodes (3극형 탄소나노튜브 캐소드의 전계방출 특성에 미치는 표면처리에 관한 연구)

  • Lee, Ji-Eon;An, Young-Je;Lee, Je-Hyun;Chung, Won-Sub;Cho, Young-Rae
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.173-178
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    • 2007
  • Carbon nanotube cathodes(CNT cathodes) with a trench structure similar to gated structure of triode-type cathode were fabricated by a screen printing method using multi-walled carbon nanotubes. The effects of surface treatments on CNT cathodes were investigated for high efficiency field emission displays(FEDs). A liquid method easily removed the organic residue and protruded the CNTs. Field emission properties were measured by using a diode-type mode. The liquid method produced a turn-on field of $1.4V/{\mu}m$. The emission current density was measured about $3.1mA/cm^{2}$ at the electric field of $3V/{\mu}m$. The liquid method showed a high potential applicable to the surface treatment for triode-type FEDs.

Fabrication of carbon nanotube gas sensor using a diaphragm structure (다이아프램 구조를 이용한 탄소나노튜브 가스 센서의 제작)

  • Kim, Sung-Woon;Han, Chun-Jae;Cho, Woo-Sung;Ju, Byeong-Kwon;Cho, Hyun-Seob;Kim, Young-Cho
    • Proceedings of the KAIS Fall Conference
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    • 2006.05a
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    • pp.223-226
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    • 2006
  • The micro-gas sensor based on carbon nanotubes (CNTs) was fabricated and its gas sensing characteristics on nitrogen dioxide ($NO_2$) have been investigated. The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_2$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

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Effect of Fe catalyst and growth temperature on growth of carbon nanotubes by thermal CVD (열 화학기상증착법을 이용한 탄소나노튜브 성장에 촉매 및 성장온도 영향)

  • Heo, Sung-Taek;Yoon, Seung-Il;Lee, Yang-Kyu;Kim, Sam-Soo;Chun, Hyun-Tea;Lee, Dong-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.418-419
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    • 2007
  • Effects of Fe catalyst film and carbon nanotube (CNT) growth temperature on the characteristics of carbon nanotube were investigated in thermal chemical vapor deposition (CVD) process. Fe catalyst was prepared by DC magnetron sputter with thickness of 5-40 nm and pre-treated with ammonia gas. CNTs were grown at $700-900^{\circ}C$. It was found that the island formation of catalyst is necessary for the CNT growth. The diameter of these CNTs shows a strong correlation with the catalyst film thickness and growth temperature.

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Opto-electrical properties of solution based carbon nanotube electrode (용액코팅된 탄소나노튜브 전극의 광전기적 성질)

  • Woo, Jong-Seok;Kim, Sun-Young;Han, Joong-Tark;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.394-394
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    • 2007
  • Transparent conductive films can serve as a critical component in displays, solar cells, lasers, optical communication devices, and solid state lighting. Carbon nanotube (CNT) based transparent conductive films are fabricated on glass and polymer substrates. CNTs typically exist in form of quasi-crystalline bundles or highly entangled bundles containing tens of individual nanotubes. To achieve full potential, CNTs must be dispersed in a solvent or other organic media. CNTs are acid treated with nitric acid then the stable dispersion of CNTs in polar solvent such as alcohols, DMF, etc. is achieved by sonication. The solubility of CNTs correlates well with the area ratio of the D and G bands from Raman spectrum. Thin films are formed from well dispersed CNT solutions using spray coating method. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders.

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Effect of Post-Heat Treatment on Field Emission Properties for Carbon Nanotube Cathodes (탄소나노튜브 캐소드의 전계방출 특성에 미치는 재열처리의 영향)

  • Ha, Sang-Hoon;Kwon, Na-Hyun;Song, Pung-Keun;Chang, Jiho;Cho, Young-Rae
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.180-186
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    • 2010
  • For the application of field emission display (FED), it is essential to develop a carbon nanotube (CNT) cathode with high emission current density. In this study, we developed and demonstrated a post-heat treatment (PHT) process to improve field emission properties of CNT cathodes. Since the PHT is intended to burn out organic materials covering the CNTs, the PHT was carried out by heating samples at a high temperature in an atmosphere. The PHT process is applied for samples processed by surface treatment with an adhesive tape. Compared to samples prior to the PHT, samples after the PHT at $360^{\circ}C$ showed about 17% improvement in emission current density. The major reason for the increased current density is mainly the increased aspect ratio of the CNTs because of the removal of the adhesive organic residues covering the CNTs, which were attached on the CNT surfaces during the surface treatment using the adhesive taping method.

Characteristics of Transparent Conductive Films of Single-Walled Carbon Nanotubes with Treatment of Surfactants and Nitric Acid

  • Kim, Myeong-Su;Gwak, Jeong-Chun;Lee, Seung-Ho;Lee, Nae-Seong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.32.1-32.1
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    • 2009
  • 현재 ITO를 대체할 재료로 투명 전도성 탄소나노튜브(carbon nanotube, CNT) 필름에 대한 연구가 진행 되고 있다. 이러한 연구에서 특히 CNT 필름의 투과도에 따른 전기저항을 향상시키기 위한 연구가 활발히 진행되고 있다. 본 연구에서는 단일벽 CNT (single-walled CNT)를 여러 가지 계면활성제로 최적 분산시킨 수용액으로부터 제조한 CNT 필름의 투과도에 따른 면 저항 (sheet resistance) 변화를 관찰하였다. 우선 계면활성제로 분산시킨 CNT 수용액을 알루미나 재질의 필터에서 정량적으로 진공 필터링하여 CNT 필름을 제조하였다. 알루미나 필터를 sodium hydroxide (NaOH) 수용액으로 용해시켜 제거함으로써 얻은 CNT 필름을 유리기판 위에 부착시켰다. 필름의 전기저항을 낮추기 위해 유리기판 위에 부착된 CNT 필름을 질산 (HNO3) 용액으로 처리하였다. Scanning electron microscopy, UV-Vis spectroscopy를 이용하여 각각 필름의 형상과 광 투과도를 분석하였고, 4-point probe로 면 저항을 측정하였다. 계면활성제로 분산시킨 CNT 필름 대부분의 면 저항은 질산 처리에 의해 감소하였다. 이는 CNT 표면에 코팅되어 있던 계면활성제가 질산에 의해 제거되었기 때문인 것으로 예상된다. 여러 계면활성제 중 sodium dodecyl benzenesulfonate로 분산시킨 CNT 필름이 산 처리 후에 가장 낮은 면 저항을 보였다. 그리고 Polyvinyl pyrrolidone (PVP)과 cetyltrimethylammonium bromide (CTAB)를 사용하여 제조한 CNT 필름의 면 저항이 가장 뚜렷한 감소를 보였다.

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Fabrication of carbon nanotube fibers with nanoscale tips and their field emission properties

  • Shin, Dong-Hoon;Song, Ye-Nan;Sun, Yu-Ning;Shin, Ji-Hong;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.468-468
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    • 2011
  • Carbon nanotubes (CNTs) have been considered as one of the promising candidate for next-generation field emitters because of their unique properties, such as high field enhancement factor, good mechanical strength, and excellent chemical stability. So far, a lot of researchers have been interested in field emission properties of CNT itself. However, it is necessary to study proper field emitter shapes, as well as the fundamental properties of CNTs, to apply CNTs to real devices. For example, specific applications, such as x-ray sources, e-beam sources, and microwave amplifiers, need to get a focused electron beam from the field emitters. If we use planar-typed CNT emitters, it will need several focal lenses to reduce a size of electron beam. On the other hand, the point-typed CNT emitters can be an effective way to get a focused electron beam using a simple technique. Here, we introduce a fabrication of CNT fibers with nanoscale point tips which can be used as a point-typed emitter. The emitter made by the CNT fibers showed very low turn-on electric field, high current density, and large enhancement factor. In addition, it showed stable emission current during long operation period. The high performance of CNT point emitter indicated the potential e-beam source candidate for the applications requiring small electron beam size.

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Preparation of Enzyme Electrodes for Biofuel Cells Based on the Immobilization of Glucose Oxidase in Polyion Complex (폴리이온복합체를 이용하여 글루코스 산화효소를 고정화한 바이오전지용 효소전극 제조)

  • Nguyen, Linh Thi My;Li, Nan;Yoon, Hyon Hee
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.99-103
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    • 2013
  • An emzymatic bioanode for a glucose/oxygen biofuel cell was prepared by the sequential coating of carbon nanotube (CNT), charge transfer complex (CTC) based on tetracyanoquinodimethane (TCNQ) and tetrathiafulvalene (TTF), glucose oxidase (GOx), and polyion complex (mixture of poly-L-lysine hydrobromide and poly (sodium 4-styrenesulfonate)) on a glassy carbon electrode. A biocathode was also prepared by the sequential coating of CNT, bilirubin oxidase (BOD), 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS), and polyion complex. The effect of CNT and CTC on the electrochemical performance was investigated. The biofuel cell exhibited a promising performance with maximum power densities of 3.6, 10.1, and $46.5{\mu}W/cm^2$ at 5, 20, and 200 mM of glucose concentration, respectively. The result indicates that the biofuel cell architecture prepared in this study can be used in the development of biofuel cells and biosensors.

Plasma Treatment of Carbon Nanotubes and Interfacial Evaluation of CNT-Phenolic Composites by Acoustic Emission and Dual Matrix Techniques (음향 방출과 이중 기지 기술을 이용한 탄소나노튜브의 플라즈마 처리 효과에 따른 탄소나노튜브-페놀 복합재료의 계면특성 평가)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Gu, Ga-Young;Lee, Woo-Il;Park, Jong-Kyoo;Park, Joung-Man
    • Composites Research
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    • v.25 no.3
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    • pp.76-81
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    • 2012
  • Atmospheric pressure plasma treatment on carbon nanotube (CNT) surfaces was performed to modify reinforcement effect and interfacial adhesion of carbon fiber reinforced CNT-phenolic composites. The surface changes occurring on CNT treated with plasma were analyzed by using Fourier transform infrared spectroscope (FT-IR). The significant improvement of wettability on CNT was confirmed by static contact angle test after plasma treatment. Such plasma treatment resulted in a decrease in the advancing contact angle from $118^{\circ}$ to $60^{\circ}$. The interfacial adhesion between carbon fiber and CNT-phenolic composites increased by plasma treatment based on apparent modulus test results during quasi-static tensile strength. Furthermore, the proposed database offers valuable knowledge for evaluating interfacial shear strength (IFSS).

Capacitance Enhancement and Evaluation of Gold-Deposited Carbon Nanotube Film Ion-Selective Electrode (금 입자 증착된 탄소나노튜브의 커패시턴스 증가 및 박막형 이온 선택성 전극으로서의 특성 평가)

  • Do Youn Kim;Hanbyeol Son;Hyo-Ryoung Lim
    • Journal of Powder Materials
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    • v.30 no.4
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    • pp.310-317
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    • 2023
  • Small-film-type ion sensors are garnering considerable interest in the fields of wearable healthcare and home-based monitoring systems. The performance of these sensors primarily relies on electrode capacitance, often employing nanocomposite materials composed of nano- and sub-micrometer particles. Traditional techniques for enhancing capacitance involve the creation of nanoparticles on film electrodes, which require cost-intensive and complex chemical synthesis processes, followed by additional coating optimization. In this study, we introduce a simple one-step electrochemical method for fabricating gold nanoparticles on a carbon nanotube (Au NP-CNT) electrode surface through cyclic voltammetry deposition. Furthermore, we assess the improvement in capacitance by distinguishing between the electrical double-layer capacitance and diffusion-controlled capacitance, thereby clarifying the principles underpinning the material design. The Au NP-CNT electrode maintains its stability and sensitivity for up to 50 d, signifying its potential for advanced ion sensing. Additionally, integration with a mobile wireless data system highlights the versatility of the sensor for health applications.