• Title/Summary/Keyword: Carbon Coating

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A Study of Tailored Blank Welding between Mild Steel and Zn-coated Steel Sheets by $CO_2$ Laser Beam ($CO_2$레이저빔에 의한 저탄소강판과 아연도금강판의 Tailored Blank 용접에 관한 연구)

  • 서종현;김도훈;유병길;이경돈
    • Laser Solutions
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    • v.1 no.1
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    • pp.4-10
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    • 1998
  • A basic research for tailored blank welding between mild steel and Zn-coated steel was carried out with $CO_2$ laser beam. The materials used in this work were low carbon steel sheet with a thickness of 1.2mm and Zn-coated steel sheet with the same thickness and 6.3$\mu$m Zn coating. Experiments were carried out by applying the Taguchi method in order to obtain optimized conditions for the application of tailored blank laser welding method in practical manufacturing process. Optical microscopy, XRD, SEM and TEM analysis were performed to observe microstructures and to determine the solidification mode of welded zone. Also mechanical properties were measured by microhardness test tensile test and Erichsen test in order to evaluate the formability of welded specimen. There was no trapped Zn in the fusion zone, and the phases in this region consisted of polygonal ferrite, quasi-polygonal ferrite, banitic ferrite and martensite. The elongation value of welded specimen was more than 80% of that value in the substrate and LDH value was more than 90% of that value in the substrate metal.

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Characterization of Fracture Toughness and Wear Behavior for Plasma Ceramic Coated Materials (플라즈마 코팅재료의 파괴인성과 마모 거동)

  • Ha, Sun-Ho;Lee, Dong-Woo;Rehman, Atta Ur;Wasy, Abdul;Song, Jung-Il
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.4
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    • pp.123-130
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    • 2013
  • Zirconia is well known in industrial applications for its mechanical characteristics. DLC (diamond-like carbon) have high elastic modulus, high electric resistivity, high dielectric constant, high wear resistance, low friction coefficient, bio compatibility, chemically inert and thermally stable. Because of all these physical and chemical properties these types of coatings have become key procedure for thin coating. Friction coefficient of DLC films is already evaluated and the current work is a further advancement by calculating the fracture toughness and wear resistance of these coatings. In the present study DLC thin film coatings are developed on $ZrO_2$ alloy surface using Plasma Enhanced Chemical Vapor Deposition (PECVD) method. Vicker hardness test is employed and it was concluded that, DLC coatings increase the Vickers hardness of ceramics.

Fabrication of Hydrocarbon Membrane based DMFC MEAs with Low Temperature Decal Method (탄화수소계 전해질막과 저온 전사법을 이용한 DMFC용 MEA 제조)

  • Krishnan, N. Nambi;Prabhuram, Joghee;Ha, Heung-Yong;Kim, Soo-Kil
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.415-417
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    • 2009
  • A low temperature decal (LTD) transfer method is tried to fabricated hydrocarbon (HC) membrane based MEA. Sandwiched structures of outer ionomer/catalyst/carbon coating/substrate, which had been developed for Nafion membrane, are used for transfer of catalyst to the HC membrane. Performances of the HC MEA before and after 500hr continuous operation are compared and it is found that a severe delamination occurs at the interface between the HC membrane and the catalyst layer, which is the main reason of the low performance and its degradation. The delamination is due probably to the different nature of HC membrane to the Nafion ionomer. A substitutional method, therefore, is suggested to overcome this. In such a way, the outer ionomer process is removed and the low transfer rate of catalyst by skipping the ionomer process is compensated with optimization of other process variables such as transfer time or temperature. The resulting performance is superior to the original LTD method, which can be explained in terms of low resistive components both in ohmic and kinetic.

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Degradation Efficiencies of Gas Phase Hydrocarbons for Photocatalysis Reactor With TiO2Thin Film (TiO2광촉매 반응기의 기체상 탄화수소의 분해효율)

  • 이진홍;박종숙;김진석;오상협;김동현
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.3
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    • pp.223-230
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    • 2002
  • Titania photocatalytic oxidation reactors were studied to investigate degradation efficiencies of hydrocarbons. In general, it is well known phenomena that thin layered titania oxidizes most of hydrocarbons to carbon dioxide and water under UV light. In this study, degradation efficiencies were measured due to changes in reactor structures, UV sources, the number of titania coatings, and various hydrocarbon chemicals. It was proven that gas degradation efficiencies are related to such factors as UV transmittance of coating substance, collision area of surface, and gas flow rate. For packing type annular reactor, about 98% degradation efficiency was achieved for achieved for propylene of 500 ppm level at a flow rate of 100 ml/min. Several gases were also tested for double-coated titania thin film under the condition of continuous flow of 100 ml/min and 365 nm UV source. It was shown that degradation efficiencies were decreasing in the order: $C_3$ $H_{6}$, n-C$_4$ $H_{10}$, $C_2$ $H_4$, $C_2$ $H_2$, $C_{6}$ $H_{6}$ and $C_2$ $H_{6}$./. 6/./.

Cooling Performance Analysis of Regeneratively Cooled Combustion Chamber (재생냉각 연소실의 냉각성능 해석)

  • Cho, Won-Kook;Seol, Woo-Seok;Cho, Gwang-Rae
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.4
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    • pp.67-72
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    • 2004
  • A regenerative cooling system has been designed through empirical 1-D analysis for a liquid rocket engine of 30-ton-level thrust. The hot-gas-side wall temperature from 1-D analysis shows 100K difference compared to 3D CFD analysis. Two variations of design with same cooling performance are suggested for different maximum channel widths i.e., 4mm and 2mm. The coolant pressure drop of the latter design is higher by 20%. The maximum liner temperature is about 700K when TBC and the thermal resistance of carbon deposit are considered. So film cooling is recommended to increase the cooling capacity as the present cooling capacity is insufficient

Regional Cathodic Protection Design of a Natural Gas Distribution Station

  • Yabo, Hu;Feng, Zhang;Jun, Zhao
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.235-240
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    • 2017
  • Regional cathodic protection has significant impact on pipeline integrity management. After risk analyses of a newly built gas distribution station constructed in an area with large dwelling density, risk score was high because of potential threat caused by galvanic corrosion. Except reinforced steel in concrete, there are four kinds of metal buried under earth: carbon steel, galvanized flat steel, zinc rod and graphite module. To protect buried pipeline from external corrosion, design and construction of regional cathodic protection was proposed. Current density was measured with potential using potential dynamic test and boundary element method (BEM) was used to calculate current requirement and optimize best anode placement during design. From our calculation on the potential, optimized conditions for this area were that an applied current was 3A and anode was placed at 40 meters deep from the soil surface. It results in potential range between $-1.128V_{CSE}$ and $-0.863V_{CSE}$, meeting the $-0.85V_{CSE}$ criterion and the $-1.2V_{CSE}$ criterion that no potential was more negative than $-1.2V_{CSE}$ to cause hydrogen evolution at defects in coating of the pipeline.

Fabrication of ceramic fibre composite and improvement of its property (세라믹 섬유 복합체의 제조 및 물성 향상)

  • 김법진;신재혁;신동우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.2
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    • pp.203-212
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    • 1996
  • Applicability of SiC coating through CVD process and PCS(polycarbosilane) impregnation for the oxidation resistance and mechanical properties of C/C composite was studied. The SiC layer coated by CVD was deposited uniformly on the C/C composite, whereas the SiC converted from PCS impregnation wetted around individual carbon fiber. The PCS-impregnated C/C composite exhibited a significant increase of bending strength in comparison with as received C/C composite. This increase in the mechanical property could be attributed to the high bonding strength between fibers due to an impregnated SiC phase. The PCS-impregnated C/C showed 25% improvement in density, 3.5 times higher MOR and 2.8 times higher oxidation resistance compared to the as-received C/C. The increments due to PCS impregnation were more effective than CVD process.

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Change in Molecular Weight Distribution of Diffusible Species on RTV Silicone Rubber Using Solvent Extraction and Recovery Rate of Hydrophobicity (용매추출에 의한 옥외용 RTV 실리콘고무의 분자량 변화와 발수성 회복속도)

  • Lee, Chang-R.;Kim, Dong-H.;Choi, Yong-C.;Kim, Jong-G.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1337-1339
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    • 2001
  • We have investigated the relation between the molecular weight distribution (MWD) of diffusible species and the recovery rate of hydrophobicity of room-temperature vulcanizing (RTV) silicone rubber (SIR) using solvent extraction at various temperatures. It was observed that the extract had a MWD ranging from a few hundreds g/mol to hundreds of thousands g/mol. By measuring the migration of siloxane to the extracted SIR surface through a thin carbon coating, the aspect of migration of diffusible species was observed as a real time plot, and the time constant of the migration was also calculated. According to the time dependence of IR-absorbance, the time constant was increased with the increase of MW of the extracts.

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Formation of β-phase PVDF by Introduction of CNTs in the CNT/PVDF Composite Film and Resulting Improvement of Piezoelectric Performance (CNT의 도입에 의한 β-phase PVDF의 형성과 CNT/PVDF 복합막에서의 압전성능 개선)

  • Lim, Young-Taek;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.11
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    • pp.712-715
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    • 2016
  • In this paper, we fabricated flexible CNT/PVDF piezoelectric composite device by introducing CNTs (carbon nanotubes) into PVDF (poly-vinylidene fluoride) solution using spray coating technique. Flexible PEDOT:PSS conducting polymer was used as electrodes. We tried to improve the piezoelectric performance from the CNT/PVDF composite film by increasing the portion of the ${\beta}$-phase PVDF in the film. We confirmed the structural conformation of the CNT/PVDF composite film as a function of CNT concentration by using FT-IR (fourier transform infra-red). As increasing CNT concentration, portion of the ${\beta}$-phase PVDF and resulting piezoelectric performance increased in the CNT/PVDF composite film. We found that CNTs introduced were played as seeds for formation of the ${\beta}$-phase PVDF in the CNT/PVDF composite film and resulting improvement of the piezoelectric performance.

Improvement of Piezoelectric Performance of the CNT/PVDF Composite Film by Enhancing Conductivity of the PEDOT:PSS Electrodes (PEDOT:PSS 전극의 전도도향상에 의한 CNT/PVDF 복합막의 압전성능 개선)

  • Lim, Young-Taek;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.11
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    • pp.716-719
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    • 2016
  • In this paper, we fabricated flexible CNT/PVDF (carbon nanotube / polyvinylidene fluoride) piezoelectric composite device with flexible poly(3,4-ethylenedioxythiophene) : polystyrene sulfonate (PEDOT:PSS) conducting polymer electrode using spray coating method. We tried to improve the piezoelectric performance from the CNT/PVDF composite film by enhancing electrical conductivity of the PEDOT:PSS electrodes. Electrical conductivity of the PEDOT:PSS electrode was enhanced by dipping it into the EG (ethylene glycol) solvent. Changes of chemical composition of the PEDOT:PSS electrode were analyzed with the dipping time by XPS (x-ray photoelectron spectroscopy) in terms of oxygen (O1s). Finally, Piezoelectric performances such as output voltage and current were measured with the dipping time. We found that enhanced electrical conductivity of the PEDOT:PSS electrodes resulted in improvement of the piezoelectric performance of the CNT/PVDF films.