• 제목/요약/키워드: Canonical form

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Effects of Microsolvation on the Stability of Zwitterionic Valine

  • Kim, Ju-Young;Won, Gang-Yeon;Lee, Sungyul
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3797-3804
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    • 2012
  • We present calculations for valine (Val) - $(H_2O)_n$ (n = 0-5) to examine the effects of microsolvating water on the relative stability of the zwitterionic vs. canonical forms of Val. We calculate the structures, energies and Gibbs free energies of the conformers at B3LYP/6-311++G(d,p), wB97XD/6-311++G(d,p) and MP2/aug-cc-pvdz level of theory. We find that five water molecules are needed to stabilize the zwitterionic form of Val. By calculating the barriers of the canonical ${\leftrightarrow}$ zwitterionic pathways of Val - $(H_2O)_5$ conformers, we suggest that both forms of Val - $(H_2O)_5$ may be observed in low temperature gas phase.

Kernel Poisson Regression for Longitudinal Data

  • Shim, Joo-Yong;Seok, Kyung-Ha
    • Journal of the Korean Data and Information Science Society
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    • 제19권4호
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    • pp.1353-1360
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    • 2008
  • An estimating procedure is introduced for the nonlinear mixed-effect Poisson regression, for longitudinal study, where data from different subjects are independent whereas data from same subject are correlated. The proposed procedure provides the estimates of the mean function of the response variables, where the canonical parameter is related to the input vector in a nonlinear form. The generalized cross validation function is introduced to choose optimal hyper-parameters in the procedure. Experimental results are then presented, which indicate the performance of the proposed estimating procedure.

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단체급식소 영양사의 종합적 품질경영(TQM) 수행과 조직문화와의 관계 규명에 관한 연구 (Relationship between TQM Performance and Organizational Culture of Dietitians in Institutional Foodservice)

  • 조기원;서의훈;윤지영
    • 한국식생활문화학회지
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    • 제22권2호
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    • pp.191-200
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    • 2007
  • This study was designed to investigate the correlation between perceived TQM performance and organizational culture of dietitians. The objective of the study is to help the management of foodservice by providing a direction which will elevate perceived TQM performance of dietitians and presenting plans which will ensure effective dietitians. Questionnaires handed out to 308 dietitians worked in institutional foodservice operation including elementary, middle and high schools, hospitals, business and industries. In terms of TQM importance and performance, the more important dietitians perceived, the higher their performance level rose. Data form the IPA, external and internal customer satisfaction, executive ability, communication system and technology, information technology and application ability, food process, strategy, and leadership were required further improvement by dietitians. Of present organizational culture model, human relations model and open systems model were more likely to be adopted by dietitians in middle and high schools. According to the type of foodservice management, the open systems model was more preferred by dietitians from self-operated operations rather than respondents from contracted operations. Canonical correlation analysis between TQM performance and organizational culture showed canonical correlation to be higher (canonical correlations coefficient: .66). In conclusion, TQM performance-organizational culture showed higher canonical correlation. In the organizational culture, foodservice operation is capable of improving the aims for the rational goal model and the open systems model. The results showed that TQM performance and organizational culture had significant relationship, especially positive organizational culture emphasizing on internal process and rational goal model would have influence on TQM performance of dietitians. Foodservice operation, however, should recognize importance of open and development culture to improve dietitians' TQM performance. To apply open system foodservice organization should encourage dietitian and foodservice employees to challenge and compete for the works, Moreover, organizational effort such as information exchange program and support system should be established.

갠트리 크레인의 입력 보상형 분산제어 (Decentralized Control with Input Compensation Form for Gantry Crane Systems)

  • 김환성;김명규;유삼상
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2000년도 제15차 학술회의논문집
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    • pp.283-283
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    • 2000
  • In this paper, we deals with a decentralized control scheme with input compensation form for gantry crane systems. By considering the gantry crane's characteristics, the system is decentralized into two subsystems such as the travelling and sway subsystem, and the hoisting subsystem. For decentralizing the system, a simple algorithm is proposed using observability canonical form. The decentralized subsystems include unknown input which coupled with other subsystems and actuator failures. These unknown input and actuator failures are estimated by using PI observation techniques and those estimated values are used to construct an input compensation form. Lastly, the proposed decentralized control scheme far the gantry crane systems is verified by crane simulation.

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갠트리 크레인의 입력 보상형 분산제어 (Decentralized Control with Input Compensation Form for Gantry Crane Systems)

  • 김환성;김명규;유삼성
    • 제어로봇시스템학회논문지
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    • 제7권4호
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    • pp.281-287
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    • 2001
  • In this paper, we deal with a decentralized control scheme with input compensation form for gantry crane systems. By considering the gantry cranes characteristics, the system is decentralized into two subsystems, the travelling and swaying subsystem and the hoisting subsystem. For decentralizing the system, a simple algorithm is proposed using the observability canonical form. The decentralized subsystems include unknown inputs that one coupled with other subsystems and actuator failures. These unknown input and actuator failures are estimated by using PI observation techniques. And those estimated values are used to construct an input compensation form. Finally, the proposed decentralized control scheme for the gantry crane systems is verified by crane simulation.

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저효율 혈액투석 불이행 측정 도구 개발 (A Study of Low Flux Hemodialysis Noncompliance Indicators and Discriminant Standards, Development of Hemodialysis Noncompliance Measurement - Brief Form(HNCM-BF))

  • 허정
    • 간호행정학회지
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    • 제13권4호
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    • pp.462-472
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    • 2007
  • Purpose: Purpose of the this study is to define the hemodialysis noncompliance Indicators and discriminant standards levels for low Flux Hemodialysis patients and development of Hemodialysis noncompliance measurement - brief form. Method: Data was collected from 269 hemodialysis patients. To establish the hemodialysis noncompliance Indicators and to discriminate standards, 13 hemodialysis nurses and 2 nephrology doctors are participated in professional group. To verify the indicators and discriminant standards, data was ananlyzed by the canonical discriminant analysis method using by SAS 8.3 program. Result: 4 Indicators- interdialysis weight gain(IWG); average of recent 4weeks, serum phophate level, skipping of hemodialysis and hemodialysis time shortening without permission- of hemodialysis noncompliance are established and discriminant standards are developed. Discriminant ability of these 4 noncompliance indicators is 99.7%(p=.000). Hemodialysis noncompliance measurement - brief form has 96.3% discriminant accuracy. Conclusion: Hemodialysis noncompliant patients have high risks. It means that special intervention to noncompliance is needed. Also continuous and objective assessment and standards of noncompliance are needed.

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REGULAR VARIATION AND STABILITY OF RANDOM MEASURES

  • Quang, Nam Bui;Dang, Phuc Ho
    • 대한수학회지
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    • 제54권3호
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    • pp.1049-1061
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    • 2017
  • The paper presents a characterization of stable random measures, giving a canonical form of their Laplace transform. Domain of attraction of stable random measures is concerned in a theorem showing that a random measure belongs to domain of attraction of any stable random measures if and only if it varies regularly at infinity.

Orbital maneuvers by using feedback linearization method

  • Lee, Sanguk
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국제학술편); Seoul National University, Seoul; 20-22 Oct. 1993
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    • pp.480-485
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    • 1993
  • A method for obtaining optimal orbital maneuvers of a space vehicle has been developed by combining feedback linearization method with the elegance of the Lambert's theorem. To obtain solutions to nonlinear orbital maneuver problems. The full nonlinear equations of motion for space vehicle in polar coordinate system are transformed exactly into a controllable linear set in Brunovsky canonical form by using feedback linearization by choosing position vector as fully observable output vector. These equations are used to pose a linear optimal tracking problem with a solutions to Lambert's problem and a linear analytical solution of continuous low thrust problem as reference trajectories.

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A NEW ALGORITHM OF THE STATE-MINIMIZATION FOR THE NONDETERMINISTIC FINITE AUTOMATA

  • Melnikov, B.F.
    • Journal of applied mathematics & informatics
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    • 제6권2호
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    • pp.379-392
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    • 1999
  • The problem of the state-minimization for the nonde-terministic finite Rabin-Scott's automata is considered. A new algo-rithm for this problem is obtained. The obtained algorithm has the exponential effectiveness like the earlier-known algorithms for this problem. But each of previous algo-rithms amounts to the search of minimum generative system for local reaction of equal automaton of canonical form and unlike them we use in this paper two special function marking states of the given automaton.

THE E-EULER PROCESS FOR NONAUTONOMOUS SYSTEMS

  • Yu, Dong-Won
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제8권2호
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    • pp.87-93
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    • 2004
  • The E-Euler process has been proposed for autonomous dynamical systems in [7]. In this paper, the E-Euler process is extended to nonautonomous dynamical systems. When a discrete function is bounded or gradually decreases to ${\epsilon}\;<<\;1$ as $n\;{\rightarrow}\;{\infty}$, it is shown that the relative error converges to a constant or decreases.

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