• Title/Summary/Keyword: Cadmium selenide

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Detection of Hydrofluoric Acid Using Cadmium Selenide Nanoparticles (카드뮴 셀레나이드 나노입자를 이용한 HF의 감지)

  • Kim, Sungjin
    • Journal of Integrative Natural Science
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    • v.3 no.2
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    • pp.112-116
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    • 2010
  • Prepared CdSe nanoparticles were systems, one of the most studied and useful nanostructures. Semiconductor quantum dots (QDs) have been the subject of much interest for both fundamental reseach and technical applications in recent years, due mainly to their strong size dependent properties and excellent chemical processibility. CdSe nanocrystals were synthesized by using sol-gel process. Synthesized CdSe quantum dots were studied to evaluate the optical, electronic and structural properties using UV-absorption, and photoluminescence (PL) measurement. Prepared CdSe nanoparticles were subjected to sense hydrofluoric acid. Photoluminescence was quenched upon adding of hydrofluoric acid.

Effects of Ligand-exchanged Cadmium Selenide Nanoparticles on the Performance of P3HT:PCBM:CdSe Ternary System Solar Cells

  • Park, Eung-Kyu;Fu, Honghong;Choi, Mijung;Luan, Weiling;Kim, Yong-Sang
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2321-2324
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    • 2013
  • An improved hybrid solar cell was obtained by focusing on the effects of ligand for CdSe nanoparticles, in the active layers. The performance was compared by mixing nanoparticles capped with pyridine or oleic acid for the acceptor material into poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester based active layer. The solar cells with pyridine capped CdSe nanoparticles showed a power conversion efficiency of 2.96% while oleic acid capped CdSe nanoparticles showed 2.85%, under AM 1.5G illumination. Formation of percolation pathways for carrier transport and a reduction in the hopping event resulted in better performance of pyridine capped nanoparticles.

Preparation and Characteristics of Elongated CdSe nanoparticles (CdSe 나노 입자의 이방성 구조 제어 및 특성연구)

  • Kim, Shin-Ho;Park, Myoung-Guk;Kim, Yang-Do
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.210-213
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    • 2008
  • Elongated CdSe nanoparticles with a diameter of 3-7nm have been successfully synthesized using two surfactants of trioctylphospine (TOP) and hexadecylamine (HDA) at $160^{\circ}C$. The formation of elongated CdSe nanoparticles is possibly due to the cooperative effects from both the different binding capability of two surfactants (TOP and HDA) and intrinsically anisotropic crystal structure of the CdSe. The electron diffraction pattern of CdSe nanoparticles revealed the formation of wurzite phase. The CdSe samples showed red-shifted wavelength from 560 to 580nm with increasing the refluxing time due to the gradual growth of CdSe nanoparticles. The relatively broad absorption band can be attributed to the surface state of CdSe nanoparticles. The possible formation mechanism of elongated CdSe nanoparticles was proposed and the characteristics of CdSe have been discussed as well.

CdSe/$TiO_2$ electrode of photoelectrochemical[PEC] cell for hydrogen production from water using solar energy (태양광과 물로부터 수소생산을 위한 광전기화학전지의 CdSe/$TiO_2$ 전극)

  • Lee, Eun-Ho;Jung, Kwang-Deog;Joo, Oh-Shim
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.2
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    • pp.130-135
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    • 2005
  • Cadmium selenide is one of the group IIb-VI compounds, which is the promising semiconductor material due to its wide range of technological applications in optoelectronic devices such as photoelectrochemical cells, solid state solar cells, thin film photoconductors etc. CdSe has optical band gap of 1.7-1.8eV and proper conduction band edge for water splitting. CdSe films are coated with small thickness(20-50nm) nanocrystalline $TiO_2$ film by electrodeposition or chemical bath deposition methods and PEC properties of CdSe and CdSe/$TiO_2$ sandwich structure are studied. The photoactivity of CdSe and CdSe/$TiO_2$ films deposited on titanium substrate is studied in aqueous electrolyte of 1M NaOH solution. Photocurrent and photovoltage obtained were of the order of 2-4 mA/$cm^2$ and 0.5V, respectively, under the intensity of illumination of 100 mW/$cm^2$.

Fabrication and characterization of optoelectronic device using CdSe nanocrystal quantum dots/single-walled carbon nanotubes (카드뮴 셀레나이드 양자점과 단일벽 탄소나노튜브로 구성된 이종 나노 소재를 기반으로 한 광전소자의 제작 및 특성평가)

  • Shim, Hyung-Cheoul;Jeong, So-Hee;Han, Chang-Soo;Kim, Soo-Hyun
    • Journal of Sensor Science and Technology
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    • v.19 no.2
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    • pp.160-167
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    • 2010
  • In this paper, we fabricated the optoelectronic device based on Cadmium selenide(CdSe) nanocrystal quantum dots (NQDs)/single-walled carbon nanotubes(SWNTs) heterostructure using dieletrophoretic force. The efficient charge transfer phenomena from CdSe to SWNT make CdSe-Pyridine(py)-SWNT unique heterostructures for novel optoelectronic device. The conductivity of CdSe-py-SWNT was increased when it was exposed at ultra violet(UV) lamp, and varied as a function of wavelength of incident light.

Electrochemical Preparation of Indidum Sulfide Thin Film as a Buffer Layer of CIGS Solar Cell (CIGS 태양전지 버퍼층으로의 활용을 위한 인듐설파이드의 전기화학적 합성)

  • Kim, Hyeon-Jin;Kim, Kyu-Won
    • Journal of the Korean Electrochemical Society
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    • v.14 no.4
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    • pp.225-230
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    • 2011
  • CIGS solar cells are kind of thin film solar cells, which are studied several years. CdS buffer layer that makes heterojunction between window layer and absorbing layer was one of issue in the CIGS solar cell study. New types of buffer layer consisted of indium sulfide are being studied these days owing to high price and environmental harmful of CdS. In this study, we demonstrated electrochemical synthesis of indium sulfide film as a buffer layer, which is cheaper and faster than other methods. A uniform indium sulfide film was obtained by applying two different alternating potentials. The band gap of the film was optimized by controlling temperature during the electrochemical synthesis. Using x-ray photoelectron spectroscopy and diffraction method we confirmed that ${\beta}$-indium sulfide was formed on ITO electrode surface.