• Journal of the Korean Electrochemical Society
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• v.6 no.4
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• pp.229-235
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• 2003

A precursor of lithium manganese oxide was synthesized by mixing $(CH_3)_2CHOLi\;with\;Mn(CH_3COO)_2{\cdot}4H_2O$ in ethanol using a sol-gel method, then heat-treated at $400^{\circ}C\;and\;800^{\circ}C$ in air atmosphere. The condition of heat treatment was determined by thermogravimetric analysis/differential thermogravimetric analysis (TGA/DTA). The characterization of the lithium manganese oxide was done by X-ray diffraction (XRD) spectra and scanning electron microscopy (SEM). The electrochemical characteristics of lithium manganese oxide electrode for lithium ion battery were measured by cyclic voltammetry (CV), chronoamperometry and AC impedance method using constant charge/discharge process. The electrochemical behaviors of the electrode have been investigated in a 1.0M $LiClO_4/propylene$ carbonate electrolyte solution. The diffusivity of lithium ions, $D^+\;_{Li}\;^+$, as determined by AC impedance technique was $6.2\times10^{-10}cm^2s^{-1}$.

• Korean Journal of Environmental Agriculture
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• v.35 no.4
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• pp.247-255
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• 2016

BACKGROUND: Acrylamide (CAS No. 79-06-1) is known to be a carcinogenic compound, and is classified as a Group 2A compound by the International Agency for Research on Cancer (IARC, 1994). Acrylamide can be generated during the browning process via the non-enzymatic Maillard reaction of carbohydrates such as reducing sugars and of amino acids such as asparagine, both of which occur at a temperature above $120^{\circ}C$. Potato tubers contain reducing sugars, and thus, this will affect the safety of processed potato products such as potato chips and French fries. In order to reduce the level of acrylamide in potato processed products, it is therefore necessary to understand factors that affect the reducing sugar content of potatoes, such as environmental factors and potato storage conditions, as well as understanding factors affecting acrylamide formation during potato processing itself. METHODS AND RESULTS: Potatoes were cultivated in eight regions of Korea; For each of these different environments, soil physico-chemical characteristics such as pH, electrical conductivity, total nitrogen, available phosphate, and exchangeable cation content were measured and correlations with potato reducing sugar content and potato chip acrylamide levels were examined. The reducing sugar content in potato during storage for three months was determined and acrylamide level in potato chip was analyzed after processing. The storage temperature levels were $4^{\circ}C$, $8^{\circ}C$, or $10^{\circ}C$, respectively. The acrylamide content of chips prepared from potatoes stored at $10^{\circ}C$ or $20^{\circ}C$ for one month was analyzed and the different frying times were 2, 3, 5, and 7 min. CONCLUSION: This study showed that monitoring and controlling the phosphate content within a potato field should be sufficient to avoid producing brown or black potato chips. For potatoes stored at low temperatures, a reconditioning period ($20^{\circ}C$ for 20 days) is required in order to reduce the levels of reducing sugars in the potato and subsequently reduce the acrylamide and improve chip coloration and appearance.

• Horticultural Science & Technology
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• v.32 no.6
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• pp.917-921
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• 2014

'Hei-G' is a new tomato cultivar originating from the cross of two inbred lines, the maternal plant TKUI-3 separated from 'Kame' in 2007, and the paternal plant AL-1 developed by pedigree breeding. The new cultivar was registered as 'Hei-G' named 'JTB026 (Jeonnam-2)' based on characteristics and yield trials carried out in the spring of 3 years, from 2010 to 2012. 'Hei-G' is an indeterminate type with strong plant vigor. The fruit is round and the ripening fruit is blackish red. The average fruit weight of 'Hei-G' is about 43.4 g, and its marketable yield is $4,944kg{\cdot}10a^{-1}$. The lycopene content of 'Hei-G' ($11.8mg{\cdot}100g^{-1}$) is higher than that of other tomatoes (e.g., cv. Rapido, 3.1 mg). In addition, 'Hei-G' is suitable for environment-friendly protected cultivation because of its resistance to powdery mildew.

• Korean Journal of Agricultural and Forest Meteorology
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• v.8 no.3
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• pp.125-131
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• 2006

This survey was carried out to investigate the characteristics of low temperature injury in rice plants at a southwestern alpine area of Korea in 2003. During vegetative, reproductive, and ripening stage in a southwestern alpine area, mean air temperature was lower by 0.4, 3.1 and $1.7^{\circ}C$, respectively, as compared to those of a normal year, Minimum air temperature during the reproductive and ripening stage was lower by 2.6 and $1.7^{\circ}C$, respectively, as compared to those of a normal year, Sunshine hours during vegetative, reproductive, and ripening stage were lower by 40.6, 81.3 and 8.4 hours, respectively, than those of a normal year. Spikelet-sterility type cold injury occurred from the latter part of June to the middle of July, which is from panicle formation stage to meiosis stage, at temperatures less than $17^{\circ}C$. Spikelet sterility under normal transplanting (May 20) ranged from 16 to 58%, which was lower than that under early transplanting in the latter part of April (29 to 83%). The total area impacted by cold damage was 2,723ha in Namwon, 510ha in Sunchang, 300ha in Jinan, 250ha in Muju, and 210ha in Jangsu. Average spiklet sterility in these regions was 44%. Rice cultivars Odaebyeo, Unbongbyeo, and Jinbubyeo showed greater tolerance to low temperature than CV, Chugwangbyeo.

• Journal of The Korean Society of Grassland and Forage Science
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• v.20 no.1
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• pp.49-54
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• 2000

A field experiment was carried out to determine the effects of seeding methods and rates on the growth characteristics, forage yield and nutritive value of sorghum X sudangrass hybrid (Sorghum bicolor (L.) Moench, cv. Pioneer 988) grown under application of animal manure in 1995. The application amount of animal manure were 40MT in cattle manure, 30MTha in swine and poultry manure. The methods and rates of seeding treated in this study were drill of 30kg, and broadcast of 30, 60 and 100kgha of seeding rates. The plant height was 180cm, 191cm and 204cm in cattle, swine and poultry manure, respectively. Plant height in the plot of drill was higher by about 15cm than those of broadcast plots. The dry matter(DM) yield was 7.73, 8.87 and 9.80MTha in cattle, swine and poultry manure, respectively. A significant higher forage yield was produced in the plot of drill, compared with broadcast(Pc0.05). DM yields in broadcast of 60kg and lOOkg of seeding rates were higher than that of 30kg of seeding rate of broadcast. However, no significant difference in forage yield was found between 60kg and IOOkg of seeding rates. The average DM yield was 11.16, 6.94, 8.26 and 8.83MTIha in drill(30kg), broadcast 30, 60 and 100kgIMT of seeding rates, respectively. The nutritive value of sorghum x sudangrass hybrid was very similar among treatments. The crude protein yields were 1,010kg in cattle manure, 1,180kg in swine manure, and 1,592kg in poultry manure. The protein yield was significantly high in the plot of drill. In conclusion, seeding by drill was recommended for forage production and protein yield of sorghumxsudangrass hybrid, and proper seeding rates were 30kg in drill and 60kg in broadcast. (Key words : Sorghumxsudangrass hybrid, Seeding rate, Seeding method, Forage yield, Nutritive value, Animal manure)

• Korean Journal of Food Science and Technology
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• v.46 no.2
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• pp.224-230
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• 2014

The characteristics and antioxidative activities of yellow and black soybean cheonggukjang prepared with the addition of purple sweet potato (Ipomoea batatas cv. Jami) were evaluated. In sensory evaluation experiments involving the addition of purple sweet potatoes to cheonggukjang at 0, 5, 10, 20, and 30% ratios (w/w), yellow (YCAP) and black (BCAP) soybean cheonggukjang with 20% purple sweet potato were most preferred. The total phenolics and flavonoid contents of YCAP and BCAP were higher than those of yellow (YC) and black (BC) cheonggukjang prepared without added purple sweet potato. YCAP and BCAP also showed higher DPPH radical-scavenging activities than other samples. Moreover, rat blood plasma samples taken 1 h after oral administration of YCAP and BCAP showed higher inhibitory effects against lipid peroxidation than did rats fed YC or BC. These results suggest that the long-term intake of cheonggukjang prepared with purple sweet potato may increase the antioxidative activity in the blood.

• Journal of The Korean Society of Grassland and Forage Science
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• v.13 no.1
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• pp.31-37
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• 1993

It is important to improve the germination of grass seeds because they are poor germination under water stress. This experiment was conducted to investigate the response of seeds pre-treated individually with Polyethylene glycol 6000 (PEG) and growth regulators(GA$_3$, Kinetin, NAA) on the germination characteristics when two levels of osmotic potential (0, -5 bar) were put to seeds of Orchardgrass. In the untreated seeds, the total germination rate was decreased under water stress, and the mean germination time was delayed. Priming of Orchardgrass seeds using PEG or GA$_3$ resulted in improved germination under water stress(-5 bar), whereas the opposite was true of kinetin or NAA. The response of seeds primed in solutions of either -15 bar PEG or 100 ppm GA$_3$ was particulary marked compared with the untreated seeds. It is suggested that PEG and GA$_3$ may have positive regulatory effects in triggering the system for water stress alleviation. But the inhibitory effect of the water stress was not completely removed by allowing the seeds to pre-treat in solution of PEG or GA$_3$.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.52-58
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• 2020

Electrochemical characterization and thermal stability were investigated for MgF₂ coated LiNi_0.8Co_0.15Al_0.05O₂ cathode. The ratio of MgF₂ was controlled by 0.5, 1, 3 wt%. Cyclic voltammetry, charge-discharge profiles, rate capability, cycle life were measured for electrochemical properties. DSC analysis was measured for thermal stability. The first discharge capacities of MgF₂ coated LiNi_0.8Co_0.15Al_0.05O₂ were decreased at 0.1C-rate compared to pristine LiNi_0.8Co_0.15Al_0.05O₂. But the rate capability and cycle life of MgF₂ coated LiNi_0.8Co_0.15Al_0.05O₂ were improved at 2C-rate. In DSC analysis result, the exothermic temperature of MgF₂ coated LiNi_0.8Co_0.15Al_0.05O₂ was increased and peak height was decreased.

• Polymer(Korea)
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• v.35 no.1
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• pp.35-39
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• 2011

In this work, mesoporous carbons (CMK-3) were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in polymer electrolyte membrane fuel cells (PEMFCs). The CMK-3 were chemically activated to obtain high surface area and small pore diameter with different potassium hydroxide (KOH) amounts, i.e., 0, 1, 3, and 4 g as an activating agent. And then Pt-Ru was deposited onto activated CMK-3 (K-CMK-3) by a chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto K-CMK-3 were determined by surface area and pore size analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and inductive coupled plasma-mass spectrometry (ICP-MS). The electrochemical properties of Pt-Ru/K-CMK-3 catalysts were also analyzed by cyclic voltammetry (CV). From the results, the K3g-CMK-3 carbon supports activated with 3 g KOH showed the highest specific surface areas. In addition, the K3g-CMK-3 led to uniform dispersion of Pt-Ru onto K-CMK-3, resulted in the enhancement of elelctro-catalystic activity of Pt-Ru catalysts.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.157-157
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• 2016

최근 많은 산업의 발전으로 인해 환경오염을 유발시키는 폐수가 다량으로 배출되고 있으며, 이러한 폐수 속에는 유기용매, 고분자 물질 및 각종 염 등의 난분해성 물질들이 다량으로 함유되어 있다. 이런 물질들을 분해시키기 위해 물리적, 생물학적 수처리 방법이 많이 이용되고 있지만 이 방법들은 각각 운전비용과 처리비용이 고가인 단점이 있다. 따라서 비용과 효율 측면에서 효과적인 폐수처리를 위해서 전기화학적 폐수처리 방법이 많이 사용되고 있다. 물리적, 생물학적 처리 방법에 비해 비용이 적게 들고, 처리 후 잔류물이 남지 않으며. 독성을 띄는 산화제의 첨가 없이도 높은 폐수처리 능력을 보이기 때문에 친환경적이므로, 전기화학적 폐수산화 처리에 사용되는 불용성 전극에 대한 연구가 많이 진행되어져 오고 있다. 그 중 BDD(Boron-doped diamond) 전극은 표면에서 강력한 산화제인 수산화 라디칼의 높은 발생량으로 인해 뛰어난 폐수처리 능력을 보이므로 불용성 전극 분야에서 활발한 연구가 진행 중이다. 그러나 기존에 BDD 전극의 기판 모재로 이용되던 Si, W, Pb등은 모두 기계적 강도. 폐수처리 능력 및 독성 문제로 인해 한계가 있었고, 특히 Nb기판 위에 형성시킨 BDD 전극은 뛰어난 폐수처리 능력에도 불구하고 비싼 모재 원가로 인해 상용화가 힘든 실정이다. 이런 문제점을 해결하기 위해 높은 기계적 강도와 전기화학적 안정성을 가진 Ti 기판을 사용한 BDD 전극에 대한 연구가 보고되고 있다. 그러나 BDD와 Ti 간의 lattice mismatch, BDD층 형성을 위한 고온 공정 시 탄소의 확산으로 인한 기판 표면에서의 TiC층 형성으로 인해 접착력이 감소하여 박리가 생기는 문제점이 있다. BDD와 Ti의 접착력을 향상시키기 위해 융점이 높고, 전기전도성이 우수한 TiN을 diffusion barrier layer로 삽입하면 탄소 확산에 의한 TiC층의 생성을 억제하여, 내부응력에 기인한 접착력 감소를 방지할 수 있다. 또 하나의 방법으로 Ti 기판의 전처리를 통해 BDD층의 접착력을 향상 시킬 수 있다. Sanding과 etching을 통해 기판 표면의 물리, 화학적인 표면조도를 부여하고, seeding을 통해 diamond 결정 성장에 도움을 주는 seed 입자를 분포시킴으로써, 중간층과 BDD층의 접착력을 향상시키고, BDD 결정핵 성장을 촉진시켜 고품질의 BDD박막 증착이 가능하다. 본 연구에서는 기존 Si, Nb 등의 기판 모재를 Ti로 대체함으로써 제조원가를 절감시키고, TiN 중간층을 삽입하여 접착력을 향상시킴으로써 기존의 BDD 전극과 동등한 수준의 물성 및 수처리 특성을 가진 BDD전극 제작을 목표로 하였다. $25{\times}25mm$의 Ti 기판위에 TiN 중간층을 DC magnetron sputtering을 이용하여 증착 후, BDD 전극 층을 HFCVD로 증착하였다. 전처리를 진행한 기판과 중간층 및 BDD층의 미세구조를 XRD로 분석하였고, 표면 형상을 SEM으로 확인하였다. BDD전극의 접착력 분석을 통해 TiN 중간층의 최적 조성을 도출하고, 최종적으로 BDD/TiN/Ti 전극의 CV특성과 가폐수의 COD분해능력 및 축산폐수, 선박평형수 등의 실제 폐수 처리 능력을 BDD/Si, BDD/Nb 전극과 비교 검토할 것이다.