• KSBB Journal
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• v.19 no.5
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• pp.406-409
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• 2004

Matrix Assisted Laser Desorption ionization Time of Flight (MALDI-TOF) was used for enzymes identification related to B -1,3-glucan synthesis. Agrobacterium sp. ATCC31750 was cultivated with two stage Continuous Stirrer Tank Reactor (CSTR) and the cells were harvested and their protein profiles were analysed by two dimensional electrophoresis. The specific enzyme spot was treated with trypsin and ana lysed by MALDI-TOF to get peptide molecular weight. The peptide molecular weights were matched with Agrobacterium tumefacience's Data Base from the matrix science site, then could identify the avaliable key enzymes. In this study, we identified key metabolite of synthesis of beta-1,3-glucan, such as glucose-6-phosphate isomerase, phosphoglucomutase, B-1,3-glucan synthase and glucokinase, and we also identified uracil phosphoribocyl transferase and Ribosome recycling factor also.

• 제어로봇시스템학회:학술대회논문집
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• 1993.10b
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• pp.48-53
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• 1993

In this paper, it is shown that chaotic nonlinear chemical process can be controlled based on the Poincare map based control algorithm. An isothermal autocatalytic CSTR, which has chaotic dynamics, is successfully controlled and period 2 orbit is generated in a normal chaotic region with small perturbation of the control parameter.

• Journal of Institute of Control, Robotics and Systems
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• v.9 no.2
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• pp.159-167
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• 2003

This study suggests the hybrid fault diagnosis method of signed digraph (SDG) and partial least squares (PLS). SDG offers a simple and graphical representation for the causal relationships between process variables. The proposed method is based on SDG to utilize the advantage that the model building needs less information than other methods and can be performed automatically. PLS model is built on local cause-effect relationships of each variable in SDG. In addition to the current values of cause variables, the past values of cause and effect variables are inputted to PLS model to represent the Process armies. The measured value and predicted one by dynamic PLS are compared to diagnose the fault. The diagnosis example of CSTR shows the proposed method improves diagnosis resolution and facilitates diagnosis of masked multiple-fault.

• International Journal of Safety
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• v.2 no.1
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• pp.28-33
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• 2003

Thermal decomposition characteristics of ethyl methacrylate (EMA) and Styrene (St.) copolymer was investigated with synthesis at 8$0^{\circ}C$ in a continuous stirred tank reacto (CSTR) using toluene and benzoyl peroxide(BPO) as solvent and initiator, respectively. The thermal decomposition was considered to be side scission at below 30$0^{\circ}C$ and estimated 2nd-order reaction kinetics of EMA/St. copolymer. The activation energies of decomposition on this copolymers were in the ranges of 38-43 kcal/mol for EMA/St. and a good additivity rule was observed in each composition. The thermogravimetric trace curves agreed well with the theoretical calculation.

• Journal of the Korean Mathematical Society
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• v.49 no.3
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• pp.641-658
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• 2012

The goal of this paper is to develop a nonlinear observer-based control strategy for a multi-variables continuous stirred tank reactor (CSTR). A new robust nonlinear observer is constructed to estimate the whole process state variables. The observer is coupled with a nonlinear controller, designed based on the input-output linearization for controlling the concentration and reactor temperature. The closed loop system is shown to be globally asymptotically stable based on Lyapunov arguments. Finally, computer simulations are developed for showing the performance of the proposed controller.

• 제어로봇시스템학회:학술대회논문집
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• 1993.10a
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• pp.570-575
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• 1993

화학 공정에서의 이상 진단 시스템 개발 및 응용에 대한 연구는 지난 5년간 많은 발전이 이루어졌다. 화학 공정의 본질적인 특성으로 대형 시스템, 비선형 특성, 모델링 자체의 어려움, 공정 변수의 large dead time 및 복잡한 인과 관계등을 들수 있으며, 이러한 어려움에도 불구하고 적절한 이상 진단 시스템의 중요성을 인식하여, 초기에는 주로 rule-based approach가 도입되어 현장에서의 조업에 많은 도움을 주었었다. 그러나 개발 기간의 단축화, 개발 과정의 표준화 뿐 아니라 개발된 시스템 자체의 일관성 등을 위하여 체계적인 접근 방법이 필요하게 되었으며, 그중 지식 베이스 합성 문제는 그 동안 활발하게 연구되어 오고 있는 분야이다. 이에 본 연구에서는 기호화된 정성적인 정보를 얻기위한 기존의 실험 방법의 한계를 극복하고자 동적 모사를 이용하여 정량적인 정보로부터 정성적인 정보를 생성시키는 방법론에 대해 연구하였다. CSTR(Continuous Stirred Tank Reactor)에서 나타날수 있는 이상의 종류에 대한 동적 모사를 수행하여 이상 진단 시스템을 위한 지식이 생성되는 과정을 보였다.

• 제어로봇시스템학회:학술대회논문집
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• 1993.10a
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• pp.589-594
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• 1993

This paper presents a fault detection strategy that discriminates the faulty sensor and that detects the component fault using a bank of observers for the system in which sensor fault and component fault can occur simultaneously. Observers as many as the number of measurements are designed, and each observer uses measurements excluding sequentially one measurement, to estimate the state variables. The faulty sensor can be found out by comparing each state variable from different observer. Next, component fault can be detected by using measurements from the sensors excluding the faulty sensor. The suggested strategy is applied to a nonisothermal, series reaction with unknown reaction kinetics in a CSTR. This strategy is found out to perform well even in the case that the sensor and component fault occur simultaneously. Since each observer is designed to be independent of reaction kinetics, this strategy is not affected by the model uncertainty and nonlinearity of the reaction kinetics.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.17 no.5
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• pp.88-93
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• 2003

This paper presents a controller design method of bilinear systems via iterative method. The iterative procedure with auxiliary sequences is defined in the process of constructing coupled linear time varying systems from bilinear systems. To design the feedback controller for bilinear systems with quadratic cost function, an optimization procedure is given by the representation closely related to the Riccati approach. In the simulation results, it is shown that the suggested method accomplishes the improved performance and good convergence.

• Proceedings of the Korea Society for Simulation Conference
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• 2000.11a
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• pp.67-72
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• 2000

PET는 합성섬유, 필름, 음료수병, 성형 플라스틱 등의 다양한 용도를 가지고 있으며 특히 섬유 원료부분에서는 전세계의 약 40%이상을 차지하고 있는 상업적 입장에서 아주 중요한 소재이다.［1］그러나, PET 제조공정은 긴 반응시간과 높은 반응온도, 대용량의 다단계 공정시설을 필요로 하는 대표적인 에너지 다소비 공정으로서 현대의 치열한 고분자 제품의 시장경쟁 상황에서 에너지 투입량 감축을 위한 공정의 해석 및 개발과 그로 인한 생산원가의 절감이 필수적이다. 본 연구에서는 실제 공장에서 사용되는 단일 연속식 직접 에스테르화 반응기(CSTR Direct Esterification Reactor)를 모델링하고 Van Krevelen［2］의 Group contribution method로 계산된 올리고머의 열용량값을 이용하여 에너지 소모량을 계산하였다. 모델링 결과는 모두 실제 공장의 자료와 비교되었으며 가장 제어하기 쉬운 변수에 따른 반응물의 물성과 에너지 소모량을 분석하였다. 또한 압력이 일정한 조건 하에서 입력변화에 따른 반응기의 동적 모델링을 동시에 수행하였으며 투입에너지량과 반응기의 운전지표와의 관계를 분석하였다. 이러한 연구는 실제 공정분석과 최적화에 있어서 소모 에너지량을 고려한 보다 정확한 지표를 제시하고 에너지 사용의 효율성을 높이는 데 기여할 수 있다.

• KSBB Journal
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• v.8 no.3
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• pp.243-255
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• 1993

In this study, it was observed that hydrogen Productivity varied with stirrer speed, bead radius, input glucose concentration and dilution rate in a continuous stirred tank reactor in which immobilized R. rubrum KS-301 was used as a hydrogen-producing bacterium The mass transfer resistance due to cell immobilization was also studied. In order to estimate an effectiveness factor, Des of glucose was first obtained, which was subsequently represented by the correlation equation between Dos and Xb, As a result external mass transfer resistance could be neglected for stirrer speeds greater than 400rpn With bead radius increasing, the hydrogen productivity and internal effectiveness factor decreased. With input 91ucose concentration increasing, the hydrogen productivity and interval and external effectiveness factor increased. Although an Internal effectiveness factor was not affected, hydrogen productivity Increased with dilution rate increasing. An overall effectiveness factor remained nearly constant for the dilution rates investigate4 but increased with input 91ucose concentration increasing.