• Title/Summary/Keyword: CP2c

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Degradation of 2-chlorophenol by Ferrate(VI) (Ferrate(VI)를 이용한 2-chlorophenol의 분해특성 연구)

  • Choi, Hye-Min;Kwon, Jae-Hyun;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.1
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    • pp.63-74
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    • 2011
  • The degradation characteristics of 2-chlorophenol(2-CP) by Ferrate(VI) were studied. The degradation efficiency of 2-CP in aqueous solution was investigated at various values of pH, Fe(VI) dosage, initial concentration and aqueous solution temperature. The maximum degradation efficiencies of 2-CP were obtained at pH 7.0 and aqueous solution temperature of 25$^{\circ}C$. The degradation efficiency was proportional to dosage of Fe(VI). Also, the initial rate constant of 2-CP degradation increased with decreasing of the 2-CP initial concentration. In addition, the degradation pathway study for 2-CP was conducted with GC-MS analysis. Acetic acid, formic acid, benzaldehyde and benzoic acid were identified as reaction intermediates of the 2-CP degradation by Ferrate(VI).

Comparison of Morphological Characteristics of the Subaxial Cervical Spine between Athetoid Cerebral Palsy and Normal Control

  • Kim, Jun Young;Kwon, Jae Yeol;Kim, Moon Seok;Lee, Jeong Jae;Kim, Il Sup;Hong, Jae Taek
    • Journal of Korean Neurosurgical Society
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    • v.61 no.2
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    • pp.243-250
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    • 2018
  • Objective : To compare the morphometry of subaxial cervical spine between cerebral palsy (CP) and normal control. Methods : We retrospectively analyzed 72 patients with CP, as well as 72 patients from normal population. The two groups were matched for age, sex, and body mass index. Pedicle, lateral mass (LM), and vertebral foramen were evaluated using computed tomography (CT) imaging. Pedicle diameter, LM height, thickness, width and vertebral foramen asymmetry (VFA) were measured and compared between the two groups. Cervical dynamic motion, disc and facet joint degeneration were investigated. Additionally, we compared the morphology of LM between convex side and concave side with cervical scoliotic CP patients. Results : LM height was smaller in CP group. LM thickness and width were larger in CP group at mid-cervical level. In 40 CP patients with cervical scoliosis, there were no height and width differences between convex and concave side. Pedicle outer diameter was not statistically different between two groups. Pedicle inner diameter was significantly smaller in CP group. Pedicle sclerosis was more frequent in CP patients. VFA was larger in CP group at C3, C4, and C5. Disc/facet degeneration grade was higher in the CP group. Cervical motion of CP group was smaller than those of the control group. Conclusion : LM morphology of CP patients was different from normal population. Sclerotic pedicles and vertebral foramen asymmetry were more commonly identified in CP patients. CP patients were more likely to demonstrate progressive disc/facet degeneration. This data may provide useful information on cervical posterior instrumentation in CP patients.

Characteristics of Light Harvesting Chlorophyll-Protein Complex and Singlet Oxygen ($^1O_2$) Quenching in Leaf-burning Disease from Panax ginseng C. A. Meyer (인삼 Light Harvesting Chlorophyll Protein의 특성 및 엽소병에서 Singlet Oxygen($^1O_2$) Quenching)

  • 양덕조;이성택
    • Journal of Ginseng Research
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    • v.13 no.2
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    • pp.158-164
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    • 1989
  • In order to determine the relationships between the lea(-burning disease and the light harvesting chlorophyll-protein (LHCP) complex in Panax ginseng C. A. Meyer, we investigated the chlorophyll-protein (CP) complex of the thylakoid membrane and its characteristics. In P. ginseng four Cp-complex bands determined by non-denaturing SDS-PAGE were identified CP I'(containing reaction center of photosystem I and LHCP I antennae), CP I (reaction center of photosystem I) LHCP II** (oligoform of LHCP II), and LHCP II (photosystem II antennae, CP 26 and CP 29) by Bassis and Dunahay's procedures. Under our experimental condition, the CP I band was only observed in P. ginseng and the band intensity of LHCP II** in P ginseng was higher than in spinach and soybean. There were differences in the absorption and fluorescence spectra and chlorophyll a/b ratio of the CP-complex bands between P. ginseng and other Plants. The Polypeptidr content of P. ginseng thylakoid was lower than in spinach and soybean thylakoid, and the Polypeptide profiles of P. ginseng was low band intensity, especially about 29-35 kD, 55 kD, and 60 kD, compared to spinach and soybean. The inhibitory effects of 2,5-dimethylfuran, specific singlet oxygen ($^1O_2$) quencher, showed that singlet oxygen destroyed 60% of chl.a, 90% of chl.b and 70% of carotenoid in bleaching P. ginseng with leaf-burning disease.

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Against the Asymmetric CP- V2 Analysis of Old English

  • Yoon, Hee-Cheol
    • Korean Journal of English Language and Linguistics
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    • v.4 no.2
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    • pp.117-149
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    • 2004
  • The paper is to argue against the asymmetric CP-V2 analysis of Old English, according to which finite verbs invariably undergo movement into a clause-final T within subordinate clauses and reach the functional head C within main clauses. The asymmetric CP-V2 analysis, first of all, faces difficulty in explaining a wide range of post-verbal elements within subordinate clauses. To resolve the problem, the analysis has to abandon the obligatoriness of V-to-T movement or introduce various types of extraposition whose status is dubious as a legitimate syntactic operation. Obligatory V-to-T movement in Old English lacks conceptual justification as well. Crosslinguistic evidence reveals that morphological richness in verbal inflection cannot entail overt verb movement. Moreover, the operation is always string-vacuous under the asymmetric CP- V2 analysis and has no effect at the interfaces, in violation of the principle of economy. The distribution of Old English finite verbs in main clauses also undermines the asymmetric CP-V2 analysis. Conceptually speaking, a proper syntactic trigger cannot be confirmed to motivate obligatory verb movement to C. The operation not only gets little support from nominative Case marking, the distribution of expletives, or complementizer agreement but also requires the unconvincing stipulation that expletives as well as sentence-initial subjects result from string-vacuous topicalization. Finally, textual evidence testifies that Old English sometimes permits non-V2 ordering patterns, many of which remain unexplained under the asymmetric CP-V2 analysis.

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The Effect of Electroacupuncture at the ST36 on the Electroencephalogram (족삼리(ST36) 전침 자극이 뇌파에 미치는 영향)

  • Gwon, Sun-Cheol;Youn, Dae-Sik;Lee, Sang-Ryong
    • Korean Journal of Acupuncture
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    • v.23 no.1
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    • pp.15-36
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    • 2006
  • Objectives . The aim of this study was to examine the effect of electroacupuncture(EA) at the ST36 on normal humans by using power spectral analysis. Methods : EEG(Electroencephalogram) power spectral exhibits site-specific and state-related differences in specific frequency bands. In this study, power spectrum was used as a measure of complexity. 32 channel EEG study was carried out in 12 subjects (10 males; age=26.7 years old, 2females; age=28 years old). Results ; In ${\alpha}$ (alpha) band, the power values at Fp2, F7, F3, Fz, FTC1, FTC2, T3, C3, Cz, C4, TT1, TCP1, CP1, CP2,T5, P3, Pz, P4, Po1, Po2, O1, Oz,O2 channels(p<0.05) during the ST36-acupoint treatment were significantly increased. In ${\beta}$ (beta) band, the power values at Fp2, F7, F3, Fz, F4, F8, FTC1, FTC2, T3, C3, Cz, C4, TT1, TCP1, CP1, CP2, T5, P3, Pz, P4, Po1, Po2, O1, Oz, O2 channels(p<0.05) during the ST36-acupoint treatment were significantly decreased. In ${\delta}$ (delta) band, the power values at F7, Fz, T3, C3, TT1, TCP1, CP1, CP2, T5, P3, Pz,T6, Po1, PO2,O1, Oz, O2 channels(p<0.05) during the ST36-acupoint treatment were significantly decreased. In ${\theta}$(theta) band, the power values at F7, Fz, FTC1, T3, TCP1, CP2, TCP2, Po1, Po2 channels(p<0.05) during the ST36-acupoint treatment were significantly decreased. ${\alpha}$/${\beta}$ values at Cz, T5, O1, Oz, O2 channels during the ST36-acupoint treatment were increased. ${\beta}$/${\theta}$ values at Fpl, F7, F3, Fz, F4, F8, FTC1, FTC2, T3, C3, C4, T4, TT1, TCP1, TCP2, TT2, P3, P4, T6, Pol channels during the ST36-acupoint treatment were increased. Conclusions : This results suggest that Electroacupuncture at the ST36 mostly affects the charge on alpha(23 channels), beta(25 channels) bands.

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Production of Polyethylene Wax via Metallocene Catalysts [(TMDS)$Cp_2$]$ZrCl_2$ and [$(n-Bu)_2Cp_2$]$ZrCl_2$ in the Presence of Hydrogen Gas as a Chain Transfer Reagent (메탈로센 화합물인 [(TMDS)$Cp_2$]$ZrCl_2$ 촉매와 [$(n-Bu)_2Cp_2$]$ZrCl_2$ 촉매를 이용한 고품질의 폴리에틸렌 왁스 제조)

  • Kim, Ji-Yoon;Yoon, Seok-Young;Yang, Young-Do;Noh, Seok-Kyun
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.566-572
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    • 2008
  • Polyethylene has been prepared via metallocene catalysts [(TMDS)$Cp_2$]$ZrCl_2$, 1, and [$(n-Bu)_2Cp_2$]$ZrCl_2$, 2, in the presence of hydrogen as a chain transfer reagent. Increase of hydrogen flow to the polymerization reactor resulted in the drop of catalytic activity, reduction of molecular weight of polyethylene, getting narrow of molecular weight distribution of polyethylene, and melting point of the polyethylene wax. It should be noticed that it was possible to control molecular weight down to 1500 and melting temperature to 60 $^\circ$C of polyethylene wax using the catalyst 1 that has been developed by authors as well as the catalyst 2 from Exxon.

Effects of Spacer Inserted Inside the Emission Layer on the Efficiency and Emission Characteristics of Phosphorescent Organic Light-emitting Diodes (발광층 내의 스페이서가 인광 OLED의 효율 및 발광 특성에 미치는 영향)

  • Seo, Yu-Seok;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.6
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    • pp.377-382
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    • 2014
  • We have investigated the effects of spacer layer inserted between blue and red doped emission layers on the emission and efficiency characteristics of phosphorescent OLEDs. N,N'-di-carbazolyl-3,5-benzene (mCP) was used as a host layer. Iridium(III)bis[(4,6-di-fluorophenyl)- pyridinato-N,$C^2$']picolinate (FIrpic) and tris(1-phenyl-isoquinolinato-$C^2$,N)iridium(III) [Ir(piq)3] were used as blue and red dopants, respectively. The emission layer structure was mCP (1-x) nm/mCP:$Ir(piq)_3$ (5 nm, 10%)/mCP (x nm)/mCP:FIrpic (5 nm, 10%). The thickness of mCP spacer layer was varied from 0 to 15 nm. The emission from $Ir(piq)_3$ and the efficiency of the device were dominated by energy transfer from mCP host and FIrpic molecules, and by diffusion of mCP host triplet excitons.

An In Vitro Method to Estimate Apparent Ileal Crude Protein Digestibility in Feed Ingredients Fed to Broiler Chickens (육계에서의 외관상 회장 조단백질 소화율 추정을 위한 In Vitro 실험방법)

  • Su Hyun, An;Changsu, Kong
    • Korean Journal of Poultry Science
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    • v.49 no.4
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    • pp.273-279
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    • 2022
  • The objective of this study was to evaluate an in vitro procedure to estimate the crude protein (CP) digestibility of feed ingredients and mixed diets in broiler chickens. The apparent ileal digestibility (AID) of the CP was measured using 23-d-old male broilers. Three experimental diets, containing three feed ingredients, namely soybean meal (SBM), canola meal (CM), and corn distiller's dried grains with solubles (DDGS), were used as the sole source of CP. A 2-step in vitro procedure was used to estimate in vivo CP digestibility; all the experiments were performed in triplicate. In step 1, the feed ingredient and mixed diet samples were incubated for 4 h at 40 °C with a pH 2.0 pepsin solution, and in step 2, the flasks were incubated for 12 h at 40 °C with a pH 6.8 pancreatin solution. Following incubation, all the samples were filtered; the undigested residues were collected and pooled together to analyze the undigested CP concentration. The in vitro CP digestibility of mixed diets and feed ingredients were 93.2% and 93.0% for SBM, 86.8% and 86.7% for CM, and 83.8% and 79.1% for DDGS, respectively. The coefficients of determination (R2) between the CP digestibility values for the feed ingredients and the in vitro CP digestibility values for the feed ingredients or respective mixed diets were 0.87 or 0.67. The results of the study demonstrated that the in vitro CP digestibility values obtained from the respective mixed diets were better estimates than the values obtained from the individual feed ingredients to predict the AID of CP in feed ingredients fed to broiler chickens.

Polymerization of Ethylene Initiated with Trisiloxane-bridged Heterometallic Dinuclear Metallocene

  • Lee, Dong-Ho;Lee, Hun-Bong;Kim, Woo-Sik;Min, Kyung-Eun;Park, Lee-Soon;Seo, Kwan-Ho;Kang, Inn-Kyu;Noh, Seok-Kyun;Song, Chang-Keun;Woo, Sang-Sun;Kim, Hyun-Joon
    • Macromolecular Research
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    • v.8 no.5
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    • pp.238-242
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    • 2000
  • The new trisiloxane-bridged heterometallic dinuclear metallocenes, hexamethyltrisiloxanediyl(cyclopentadienyltitanium trichloride) (cyclopentadienylindenyl zirconium dichloride) , $C_3ITi-Cp(CH_3)_2Si-O-Si(CH_3)_2-O-Si(CH_3)_2-Cp-ZrIndCI_2$ (1) and hexamethyltrisiloxanediyl (cyclopentadienylindenylhafnium dichloride) (cyclopentadienylindenyl zirconium dichloride), $C_2IndHf-Cp(CH_3)_2Si-O-Si(CH_3)_2-Cp-ZrIndCl_2$ 2) connecting two dissimilar metallocenes were synthesized and used for ethylene polymerization in the presence of modified methylaluminoxane (MMAO) cocatalyst. The catalytic activity of heterometallic dinuclear metallocenes, 1 and 2 was lower than that of corresponding mononuclear metal-locene as well as two physically mixed catalysts, $CpTiCl_2/Cp_2ZrCl_2 and Cp_2HfCl_2/Cp_2ZrCl_2$. On the tither hand, MWD of PE obtained with 1 and 2 was remarkably broader ($M_w/M_n$) became up to 9.4) than those of PEs prepared with the corresponding mononuclear metallocenes and mixed catalysts. With analysis by GPC and CFC, it was found that PE produced by the heterometallic dinuclear metallocenes exhibited the definite bimodal GPC curves that should cause the broadening of MWD.

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