Browse > Article

Degradation of 2-chlorophenol by Ferrate(VI)  

Choi, Hye-Min (부경대학교 환경공학과)
Kwon, Jae-Hyun (인제대학교 환경공학부)
Kim, Il-Kyu (부경대학교 환경공학과)
Publication Information
Journal of Korean Society of Water and Wastewater / v.25, no.1, 2011 , pp. 63-74 More about this Journal
Abstract
The degradation characteristics of 2-chlorophenol(2-CP) by Ferrate(VI) were studied. The degradation efficiency of 2-CP in aqueous solution was investigated at various values of pH, Fe(VI) dosage, initial concentration and aqueous solution temperature. The maximum degradation efficiencies of 2-CP were obtained at pH 7.0 and aqueous solution temperature of 25$^{\circ}C$. The degradation efficiency was proportional to dosage of Fe(VI). Also, the initial rate constant of 2-CP degradation increased with decreasing of the 2-CP initial concentration. In addition, the degradation pathway study for 2-CP was conducted with GC-MS analysis. Acetic acid, formic acid, benzaldehyde and benzoic acid were identified as reaction intermediates of the 2-CP degradation by Ferrate(VI).
Keywords
2-chlorophenol; Ferrate(VI); Oxidation; Intermediate study;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Carr, J. D. ; Kelter, P. B. ; Tabatabai, A. ; Spichal, D. ; Erickson, J. ; McLaughin, C. W.(1985) "Properties of ferrate(VI) in aqueous solution : an alternative oxidant in wastewater treatmen," Proc. Conf. Water Chlorin. Chem. Environ. Impact Health Effects 5, 1285-1298.
2 Christelle Briois, Nicolas Visez, Christiane Baillet, Jean-Pierre Sawerysyn(2006) "Experimental study on the thermal oxidation of 2-chlorophenol in air over the temperaturerange 450-900$^{\circ}C$," Chemosphere 62, 1806-1816.   DOI   ScienceOn
3 C. Kim, Y. Lee, J. Yoon(2004) "kinetics of Bisphenol A Removal by Ferrate (Fe(VI)) Oxidation," Journal of Korean Society on Water Quality ․ Korean Society of Water and Wastewater.
4 EPA homepage, www.epa.gov
5 Galina Matafonova, Nick Christofi, Valeriy Batoev, Edward Sosnin(2008) "Degradation of chlorophenols in aqueous media using UV XeBr excilamp in a flow-through reactor," Chemosphere 70, 1124 - 1127.   DOI   ScienceOn
6 H. Kim, B. Kim, S. Lee, J. Yang, H. Kim, J. Kwan, H. Lm(2008) "Treatment of Wastewater Containing Cu(II)-EDTA Using Ferrate in Sequencing Batch Scale System," Journal of Korean Society of Environmental Engineers 30(7), 729-734.
7 Jiang J-Q., and Lloyd B.(2002) "Progress in the Development and Use of Ferrate(VI) Salt as an Oxidant and Coagulant for Water and Wastewater Treatment," Wat. Res., 36, 1397-1408.   DOI   ScienceOn
8 J. Kim, H. Ha, S. Lee, J. Lee, I. Kim(2004), "A study on the photodegradation of 2-Chlorophenol by $TiO_{2}$ with Cu/Fe, Journal of Korean Society on Water Quality ․ Korean Society of Water and Wastewater," pp.705-708.
9 J. W. Kang, H. S. Park and K. H. Choei(1995) "Photocatalytic degradation of organic pollutants over a $TiO_{2}$ semiconductor," J. of KSEE, 17(3), 283-294.
10 Kang, Yoon Suk(2002) "Separation of 2-chlorophenol from aqueous solution by liquid emulsion membrane employing ultrasonic homogenization," Sungkyunkwan University.
11 Karoly Mogyorosi, Andras Farkas, and Imre Dekany.(2002) "$TiO_{2}$-based photocatalytic degradation of 2-chlorophenol adsorbed on hydrophobic clay," Environ. Sci. Technol., 36(16), 3618-3624.   DOI   ScienceOn
12 K. Choiy(2004) "Photodecomposition of volatile organic compounds(VOCs) on $TiO_{2}$ catalysts," Chonbuk national universit.
13 Kim Hyoung-Uk(2007) "Treatment of wastewater containing Cyanide and Cu(II)-EDTA with ferrate," Kwandong University.
14 K Park, E. Kim, H. Kim, S. Lee, M. Yoo(2006) "Comparison between ozone and ferrate in oxidizing nonylphenol," Journal of Korean Society of Environmental Engineers, 328-335.
15 Lee Froese, K. L. and Hutzinger, O.(1996) "Polychlorinated Benzene, Phenol, Dibenzofuran in Heterogeneous Combustion Reactions of Acetylene," Environ. Sic. Technol., 30(3), 998-1008.   DOI   ScienceOn
16 Lee, Y.H., Um, I.H. and Yoon, J.Y.(2003) "Arsenic(III) Oxidation by Iron(VI) (Ferrate) and Subsequent Removal of Arsenic(V) by Iron(III) Coagulation," Environ. Sci. Technol., 37, 5750-5756.   DOI   ScienceOn
17 Lee, Y.H., Yoon, J.Y., and Gunten, U.V.(2005) "Kinetics of the Oxidation of Phenols and Phenolic Endocrine Disruptors during Water Treatment with Ferrate(Fe(VI))," Environ. Sci. Technol., 39, 8978-8984.   DOI   ScienceOn
18 N.N. Rao, A.K. Dubey, S. Mohanty, P. Khare, R. Jain, S.N. Kaul(2003) "Photocatalytic degradation of 2-chlorophenol: a study of kinetics, intermediates and biodegradability," Journal of Hazardous Materials B101, 301-314.
19 Li, R., Savage, P. E., and Szmukler, D.(1993) "2-chlorophenol Oxidation in Supercrittcal Water: Global Kinetics and Reaction Products," AICHE J., 39, 178-187.   DOI
20 M. Lim, M. Kim(2007) "Removal of Natural Organic Matter using Potassium ferrate(VI)," Journal of Korean Society of Environmental Engineers 29(12), 1337-1344.
21 Nigel Graham, Cheng-chun Jiang, Xiang-Zhong Li, Jia-Qian Jiang, Jun Ma(2004) "The influence of pH on the degradation of phenol and chlorophenols by potassium ferrate," Chemosphere. 56. 949-956.   DOI   ScienceOn
22 Seong-Hoon Hong(2007) "Degradation of 2-chlorophenol by various Advanced Oxidation Processes," Pukyong National University.
23 Sharma, V. K., Kazma, F., Jiangyong, H., and Ray, A.K.(2005) "Ferrates(iron(VI) and iron(V)) : Environmentally Friendly Oxidants and Disinfectants," J. Water Health., 3, 45-58.
24 Sharma, V. K.(2004) "Use of Iron(VI) and Iron(V) in Water and Wastewater treatment," Water Sci. Technol., 49, 69-74.
25 S. Jo(2006) "$TiO_{2}$ A study on the photodegradation of Polycyclic Aromatic Sulfur Hydrocarbons(PASHs) and TCE by $TiO_{2}$ Photocatalysts," Pukyong National University.
26 Stuart Licht, and Xingwen Yu(2005), "Electrochemical Alkaline Fe(VI) Water Purification and Remediation," Environ. Sci. Technol., 39, 8071-8076.   DOI   ScienceOn
27 Virenderk, Sharma, Jeremyo, Smith and Frankj, Millero(1997) "Ferrate(VI) Oxidation of Hydrogen Sulfide," Environ. Sci. Technol., 31, 2486-2491.   DOI   ScienceOn
28 Virender K. Sharma(2002) "Potassium ferrate(VI): an environmentally friendly oxidant," Adances in Enironmental Research 6, 143-156.
29 Y. Lee, M. Cho, J. Yoon(2003) "Water treatment by ferrate, green oxidant and flocculant," Journal of environmental hi-technology, 2003.12., 52-60.
30 Yunho Lee, Jeyong Yoon, Urs von Gunten(2005) "Oxidation of Phenolic Contaminants during Water Treatment with Ferrate (Fe(VI)): A Kinetic Study," Applied Chemistry, 9(1), 205-208.
31 Zuzana Macova, Karel Bouzek, Jan Hives, Virender K. Sharma, Raymond J. Terryn, J. Clayton Baum.(2009) "Research progress in the electrochemical synthesis of ferrate(VI)," Electrochimica Acta., 54. 2673-2683.   DOI   ScienceOn