• 제목/요약/키워드: CO2 reduction

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초간편 H형강 기둥-보 약축접합부의 구조성능 및 CO2 저감량 평가 (Structural Performance and CO2 Reduction Evaluation of the Ultra simple Wide-shaped section Beam-to-Column Weak Axis Connection)

  • 김상섭;부윤섭
    • 한국강구조학회 논문집
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    • 제23권5호
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    • pp.615-627
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    • 2011
  • 강구조에서 약축에 대한 접합기술 및 연구는 소수의 연구자들에 의해 진행되고 있으며, 연구실적 및 접합부 기술발전의 성과가 많이 부족한 실정이다. 기존 브라켓타입의 약축접합부는 효율적인 시공성 및 $CO_2$배출량의 저감을 위하여 개선될 필요가 있으며, 구조성능이 우수하고 $CO_2$배출량이 적은 새로운 형태의 약축접합부로 대체되어야 할 것이다. 그러나 새로운 형태의 약축접합부는 구조성능의 검증 및 안전성에 대한 검토가 선행되어야 하며, $CO_2$저감에 관한 연구가 진행되어야 할 것으로 판단된다. 따라서 본 연구는 기존 브라켓타입의 약축접합부, 표준약축접합부 및 초간편 약축접합부를 대상으로 구조성능을 검토하였으며, 약축접합에 필요한 접합재료의 소요수량 및 $CO_2$배출량을 정량적으로 평가하였다. 그 결과, 초간편 약축접합부가 구조성능이 우수하고, $CO_2$배출량도 적으며, 접합재료의 소요수량이 적기 때문에 시공성이 우수하여 기존 브라켓타입의 약축접합부를 대체할 수 있을 것으로 판단된다.

우리나라 쇠고기 소비 행태 변화에 의한 이산화탄소 배출 변화량 예측 (Prediction of the Carbon Dioxide Emission Change Resulting from the Changes in Bovine Meat Consumption Behavior in Korea)

  • 여민주;김용표
    • 한국대기환경학회지
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    • 제31권4호
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    • pp.356-367
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    • 2015
  • A consumption based study on the carbon dioxide ($CO_2$) emission change due to the changes in the bovine meat consumption behavior in Korea was carried out. It was found that if the consumption of bovine meat be reduced by half, the reduction amount of $CO_2$ emissions be over 0.8 $MtCO_2e$ in all senarios in 2023. This amount is equivalent to over 50% of the greenhouse gases (GHGs) emission reduction target in agriculture and forestry, and fishery, a significant reduction. It was also found that the $CO_2$ emission reduction amount in consumption-based approach was the largest when the consumption of the imported bovine meat be reduced, though the difference was not that large.

분무건조법에 의해 제조된 Ti-Co-O계 산화물 분말의 고체 탄소에 의한 환원/침탄 (Carbothermal Reduction of Spray Dried Titanium-Cobalt-Oxygen Based Oxide Powder by Solid Carbon)

  • 이길근;문창민;김병기
    • 한국분말재료학회지
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    • 제11권1호
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    • pp.28-33
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    • 2004
  • In the present study, the focus is on the analysis of carbothermal reduction of the titanium-cobalt-oxygen based oxide powder by solid carbon for the optimizing synthesis process of ultra fined TiC/Co composite powder. The titanium-cobalt-oxygen based oxide powder was prepared by the combination of the spray drying and desalting processes using the titanium dioxide powder and cobalt nitrate as the raw materials. The titanium-cobalt-oxygen based oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and thermal gravity of the mixture during carbothermal reduction were analysed using XRD and TGA. The synthesized titanium-cobalt-oxygen based oxide powder has a mixture of $TiO_2$ and $CoTiO_3$. This oxide powder was transformed to a mixed state of titanium car-bide and cobalt by solid carbon through four steps of carbothermal reduction steps with increasing temperature; reduction of $CoTiO_3$ to $TiO_2$ and Co, reduction of $TiO_2$, to the magneli phase($Ti_nO_{2n-1}$, n>3), reduction of the mag-neli phase($Ti_nO_{2n-1}$, n>3) to the $Ti_nO_{2n-1}$(2$\leq$n$\leq$3) phases, and reduction and carburization of the $Ti_nO_{2n-1}$(2$\leq$n$\leq$3) phases to titanium carbide.

지열 시스템의 난방 경제성 및 $CO_2$ 절감 실증 연구 (An Experimental Study on the Ground Source Heat Pump System for Heating Economic Efficiency and Reduction Amount of $CO_2$)

  • 남임우;백기동
    • 한국지열·수열에너지학회논문집
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    • 제3권2호
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    • pp.25-30
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    • 2007
  • The final energy consumption in the building sector in Korea represents almost 20% of the total energy consumption. Besides, Space heating and hot water generation in Korea are based on fossil fuels, with a serious environmental impact. This study describes thermal performance of heating demonstration system using close-loop ground source heat pump installed at Korean minjok leadership academy. The results of the experimental study, it retrieve the investment cost for 3years 8months and reduction amount of $CO_2$are 293,900 $kgCO_2$.

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여러 가지 pH 수용액에서 Bis-Cobalt Phenylporphyrin 유도체들에 의한 산소의 전극 촉매적 환원 (The Electrocatalytic Reduction of Oxygen by Bis-Cobalt Phenylporphyrins in Various pH Solutions)

  • 최용국;조기형;박종기
    • 대한화학회지
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    • 제37권8호
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    • pp.735-743
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    • 1993
  • Cofacial bis-cobalt tetraphenylporphyrin(Co-TPP) 유도체 화합물들이 수식된 유리질 탄소 전극과 carbon microelectrode을 작업 전극으로 사용하여 여러가지 pH 용액에서 순환 전압전류법 및 시간 전류법에 의해 산소의 환원반응을 조사하였다. 산성용액에서 monomer인 cobalt tetraphenylporphyrin 화합물이 수식된 전극에서 산소의 환원반응경로는 중간 생성물인 H$_2$O$_2$로 가는 2전자 반응으로, dimer인 cofacial bis-cobalt tetraphenylporphyrin 유도체 화합물들이 수식된 전극에서는 최종 생성물인 H$_2$O로 가는 4전자 반응으로 진행되었다. 이와 같은 산소의 환원반응은 전체적으로 비가역적이며 확산지배적인 반응으로 주어졌다. pH 변화에 따른 산소의 환원전위는 pH 13에서 pH 4 까지는 직선관계가 성립하였으나 강한 산성용액에서는 이들 관계가 성립하지 않았다. 산성용액에서 산소의 환원전위는 알몸 유리질 탄소전극에서 보다 monomer Co-TPP 화합물이 수식된 유리질 탄소전극에서는 400 mV만큼, dimer Co-TPP 화합물이 수식된 전극에서는 750 mV 만큼 더 양전위 방향으로 이동되었다.

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SnO2/Cu(OH)2 Nanowires 전극을 이용한 전기화학적 이산화탄소 환원 특성 (Tin Oxide-modulated to Cu(OH)2 Nanowires for Efficient Electrochemical Reduction of CO2 to HCOOH and CO)

  • 성채원;배효정;조세아;허지원;한은미;하준석
    • 마이크로전자및패키징학회지
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    • 제30권4호
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    • pp.91-97
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    • 2023
  • 전기화학적 이산화탄소 (CO2) 환원은 CO2를 고부가가치의 탄소화합물로 전환하는 매우 유망한 방법이다. 본 논문에서는 양극 산화법과 원자층 증착법을 이용하여 전기화학적 CO2 환원용 SnO2/Cu(OH)2 나노와이어 (NWs) 전극을 합성하는 손쉬운 방법과 그 특성에 대해 보고한다. 제작된 SnO2/Cu(OH)2 NWs (-16 mA/cm2)는 -1.0 V (vs. RHE)에서 Cu(OH)2 NWs (-6 mA/cm2) 대비 더 우수한 전기화학적 성능을 보였다. CO2 환원 성능을 확인해 보았을 때도 일산화탄소(CO), 포름산염 (HCOOH) 생성물에 대해 각각 29.72 %, 58.01 %의 높은 페러데이 효율 (FE)을 보였다. 본 연구는 CO2 배출로 인한 기후 변화에 대응하는 경제적이며 지속 가능한 방법을 제공할 뿐만 아니라, 전기화학적 CO2 환원용 전극 개발에 크게 기여할 것으로 예상된다.

Econometric Estimation of the Climate Change Policy Effect in the U.S. Transportation Sector

  • Choi, Jaesung
    • 한국기후변화학회지
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    • 제8권1호
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    • pp.1-10
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    • 2017
  • Over the past centuries, industrialization in developed and developing countries has had a negative impact on global warming, releasing $CO_2$ emissions into the Earth's atmosphere. In recent years, the transportation sector, which emits one-third of total $CO_2$ emissions in the United States, has adapted by implementing a climate change action plan to reduce $CO_2$ emissions. Having an environmental policy might be an essential factor in mitigating the man-made global warming threats to protect public health and the coexistent needs of current and future generations; however, to my best knowledge, no research has been conducted in such a context with appropriate statistical validation process to evaluate the effects of climate change policy on $CO_2$ emission reduction in recent years in the U.S. transportation. The empirical findings using an entity fixed-effects model with valid statistical tests show the positive effects of climate change policy on $CO_2$ emission reduction in a state. With all the 49 states joining the climate change action plans, the U.S. transportation sector is expected to reduce its $CO_2$ emissions by 20.2 MMT per year, and for the next 10 years, the cumulated $CO_2$ emission reduction is projected to reach 202.3 MMT, which is almost equivalent to the $CO_2$ emissions from the transportation sector produced in 2012 by California, the largest $CO_2$ emission state in the nation.

Stoichiometry, Thermal Stability and Reducibility of Perovskite-Type Mixed Oxide LaBO$_3$ (B = Fe, Co, Ni)

  • Park, Il-Hyun;Lee, Hyung-Pyo
    • Bulletin of the Korean Chemical Society
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    • 제9권5호
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    • pp.283-288
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    • 1988
  • The titled properties on reduction of the perovskite $LaBO_3$ (B = Fe, Co, Ni) have been investigated by means of temperature-programmed reduction, isothermal reduction and X-ray diffraction methods. Nominal composition of $LaFeO_{3.18},\;LaCoO_{3.00}\;and\;LaNiO_{2.92}$ are determined. Reduction reaction of these mixed oxides differed according to B-site transition metal and thermal stability on reduction decreased as following order: $LaFeO_{3.18}$ > $LaCoO_{3.00}$ > $LaNiO_{2.92}$. From the results of isothermal reaction, kinetics on reduction of the perovskite has been discussed in detail.

Ni0.5Co0.5Fe2O4의 수소환원에 의한 나노구조 Fe-Ni-Co 합금의 제조 및 자성특성 (Synthesis and Magnetic Property of Nanocrystalline Fe-Ni-Co Alloys during Hydrogen Reduction of Ni0.5Co0.5Fe2O4)

  • 백민규;도경효;;박종진
    • 대한금속재료학회지
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    • 제49권2호
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    • pp.167-173
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    • 2011
  • Nickel cobalt ferrite($Ni_{0.5}Co_{0.5}Fe_2O_4$) powder was prepared through the ceramic route by the calcination of a stoichiometric mixture of NiO, CoO and $Fe_2O_3$ at $1100^{\circ}C$. The pressed pellets of $Ni_{0.5}Co_{0.5}Fe_2O_4$ were isothermally reduced in pure hydrogen at $800{\sim}1100^{\circ}C$. Based on the thermogravimetric analysis, the reduction behavior and the kinetic reaction mechanisms of the synthesized ferrite were studied. The initial ferrite powder and the various reduction products were characterized by X-ray diffraction, scanning electron microscopy, reflected light microscope and vibrating sample magnetometer to reveal the effect of hydrogen reduction on the composition, microstructure and magnetic properties of the produced Fe-Ni-Co alloy. The arrhenius equation with the approved mathematical formulations for the gas solid reaction was applied to calculate the activation energy($E_a$) and detect the controlling reaction mechanisms. In the initial stage of hydrogen reduction, the reduction rate was controlled by the gas diffusion and the interfacial chemical reaction. However, in later stages, the rate was controlled by the interfacial chemical reaction. The nature of the hydrogen reduction and the magnetic property changes for nickel cobalt ferrite were compared with the previous result for nickel ferrite. The microstructural development of the synthesized Fe-Ni-Co alloy with an increase in the reduction temperature improved its soft magnetic properties by increasing the saturation magnetization($M_s$) and by decreasing the coercivity($H_c$). The Fe-Ni-Co alloy showed higher saturation magnetization compared to Fe-Ni alloy.

토지이용변화에 따른 식생 및 토양의 이산화탄소 저감잠재량 분석 (The Analysis of Potential Reduction of CO2 Emission In Soil and Vegetation due to Land use Change)

  • 이동근;박찬
    • 한국환경복원기술학회지
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    • 제12권2호
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    • pp.95-105
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    • 2009
  • Land Use Changes (LUCs) have effects on greenhouse gas emissions and carbon stocks in soil and vegetation. Therefore, predictions for LUC are very important for achieving quantitative targets of $CO_2$ reduction rates. Some research exists on carbon fluxes and carbon cycles to estimate carbon stocks in terrestrial ecosystems in Korea. However, these researches have limitations in terms of helping us understand future potential reductions of $CO_2$ that reflect the influence of LUC. The aim of this study is to analyze the reduction levels of $CO_2$ emissions while considering LUC scenarios that effect carbon fluxes for LCS basic study in the year 2030. In this study, a common approach to model the effects of LUC on carbon stocks is the use of CA-Markov technical process with LUC patterns in the past. Potential reduction of $CO_2$ is calculated by change of land use that contains different soil organic carbon, each land use type, and biomass in vegetation. An IPCC analytical method of natural carbon sink and coefficient results from previous study in Korea is used as a calculation method for potential reduction of $CO_2$. As a result, 12,419 KtC will be reduced annually, which is 8.3% percent of 2005 $CO_2$ emissions in Korea. This will result in 3,226 hundred million won of economic efficiency. In conclusion, conservation of natural carbon sinks is necessary even if the amount of potential reduction change is little.