• Title/Summary/Keyword: CO2 reduction

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Structural Performance and CO2 Reduction Evaluation of the Ultra simple Wide-shaped section Beam-to-Column Weak Axis Connection (초간편 H형강 기둥-보 약축접합부의 구조성능 및 CO2 저감량 평가)

  • Kim, Sang-Seup;Boo, Yoon-Seob
    • Journal of Korean Society of Steel Construction
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    • v.23 no.5
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    • pp.615-627
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    • 2011
  • There have been few researches on the connection technology for steel structures, so the research outputs and the outcome of the technology development are still insufficient. The bracket-type connection should be improved for efficient constructability and $CO_2$ reduction. It should be replaced by a new type of weak-axis connection that has better structural performance and less $CO_2$ emission. Since the structural performance and safety of the new type of weak-axis connection must first be verified, however, a study on $CO_2$ reduction will be conducted. Therefore, this study looked into the structural performance of the bracket-type details, standard details, and ultra-simple details. It evaluated the requirements for connection materials and $CO_2$ emission. It was found that the ultra-simple weak-axis connection has thebest structural performance and the least $CO_2$ emissions, so it is deemed capable of replacing the bracket-type weak-axis connection.

Prediction of the Carbon Dioxide Emission Change Resulting from the Changes in Bovine Meat Consumption Behavior in Korea (우리나라 쇠고기 소비 행태 변화에 의한 이산화탄소 배출 변화량 예측)

  • Yeo, Min Ju;Kim, Yong Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.4
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    • pp.356-367
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    • 2015
  • A consumption based study on the carbon dioxide ($CO_2$) emission change due to the changes in the bovine meat consumption behavior in Korea was carried out. It was found that if the consumption of bovine meat be reduced by half, the reduction amount of $CO_2$ emissions be over 0.8 $MtCO_2e$ in all senarios in 2023. This amount is equivalent to over 50% of the greenhouse gases (GHGs) emission reduction target in agriculture and forestry, and fishery, a significant reduction. It was also found that the $CO_2$ emission reduction amount in consumption-based approach was the largest when the consumption of the imported bovine meat be reduced, though the difference was not that large.

Carbothermal Reduction of Spray Dried Titanium-Cobalt-Oxygen Based Oxide Powder by Solid Carbon (분무건조법에 의해 제조된 Ti-Co-O계 산화물 분말의 고체 탄소에 의한 환원/침탄)

  • 이길근;문창민;김병기
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.28-33
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    • 2004
  • In the present study, the focus is on the analysis of carbothermal reduction of the titanium-cobalt-oxygen based oxide powder by solid carbon for the optimizing synthesis process of ultra fined TiC/Co composite powder. The titanium-cobalt-oxygen based oxide powder was prepared by the combination of the spray drying and desalting processes using the titanium dioxide powder and cobalt nitrate as the raw materials. The titanium-cobalt-oxygen based oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and thermal gravity of the mixture during carbothermal reduction were analysed using XRD and TGA. The synthesized titanium-cobalt-oxygen based oxide powder has a mixture of $TiO_2$ and $CoTiO_3$. This oxide powder was transformed to a mixed state of titanium car-bide and cobalt by solid carbon through four steps of carbothermal reduction steps with increasing temperature; reduction of $CoTiO_3$ to $TiO_2$ and Co, reduction of $TiO_2$, to the magneli phase($Ti_nO_{2n-1}$, n>3), reduction of the mag-neli phase($Ti_nO_{2n-1}$, n>3) to the $Ti_nO_{2n-1}$(2$\leq$n$\leq$3) phases, and reduction and carburization of the $Ti_nO_{2n-1}$(2$\leq$n$\leq$3) phases to titanium carbide.

An Experimental Study on the Ground Source Heat Pump System for Heating Economic Efficiency and Reduction Amount of $CO_2$ (지열 시스템의 난방 경제성 및 $CO_2$ 절감 실증 연구)

  • Nam, Leem-Woo;Paek, Gi-Dong
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.3 no.2
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    • pp.25-30
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    • 2007
  • The final energy consumption in the building sector in Korea represents almost 20% of the total energy consumption. Besides, Space heating and hot water generation in Korea are based on fossil fuels, with a serious environmental impact. This study describes thermal performance of heating demonstration system using close-loop ground source heat pump installed at Korean minjok leadership academy. The results of the experimental study, it retrieve the investment cost for 3years 8months and reduction amount of $CO_2$are 293,900 $kgCO_2$.

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The Electrocatalytic Reduction of Oxygen by Bis-Cobalt Phenylporphyrins in Various pH Solutions (여러 가지 pH 수용액에서 Bis-Cobalt Phenylporphyrin 유도체들에 의한 산소의 전극 촉매적 환원)

  • Yong-Kook Choi;Ki-Hyung Chjo;Jong-Ki Park
    • Journal of the Korean Chemical Society
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    • v.37 no.8
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    • pp.735-743
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    • 1993
  • The electrocatalytic reduction of oxygen is investigated by cyclic voltammetry and chronoamperometry at glassy carbon electrode and carbon microelectrode coated with a variety of cobalt phenylprophyrins in various pH solutions. Oxygen reduction catalyzed by the monomeric porphyrin Co(Ⅱ)-TPP mainly occurs through the 2e$^-$ reduction pathway resulting in the formation of hydrogen peroxide whereas electrocatalytic process carried out 4e$^-$ reduction pathway of oxygen to H$_2$O at the electrodes coated with cofacial bis-cobalt phenylporphyrins in acidic solution. The electrocatalytic reduction of oxygen is irreversible and diffusion controlled. The reduction potentials of oxygen in various pH solutions have a straight line from pH 4 to pH 13, but level off in strong acidic solution. The reduction potentials of oxygen shift to positive potential more 400 mV at the electrode coated with monomer Co-TPP compound than bare glassy carbon electrode while 750 mV at the electrode coated with dimer Co-TPP compound.

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Tin Oxide-modulated to Cu(OH)2 Nanowires for Efficient Electrochemical Reduction of CO2 to HCOOH and CO (SnO2/Cu(OH)2 Nanowires 전극을 이용한 전기화학적 이산화탄소 환원 특성)

  • Chaewon Seong;Hyojung Bae;Sea Cho;Jiwon Heo;Eun Mi Han;Jun-Seok Ha
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.4
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    • pp.91-97
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    • 2023
  • Electrochemical (EC) CO2 reduction is a promising method to convert CO2 into valuable hydrocarbon fuels and chemicals ecofriendly. Here, we report on a facile method to synthesize surface-controlled SnO2/Cu(OH)2 nanowires (NWs) and its EC reduction of CO2 to HCOOH and CO. The SnO2/Cu(OH)2 NWs (-16 mA/cm2) showed superior electrochemical performance compared to Cu(OH)2 NWs (-6 mA/cm2) at -1.0 V (vs. RHE). SnO2/Cu(OH)2 NWs showed the maximum Faradaic efficiency for conversion to HCOOH (58.01 %) and CO (29.72 %). The optimized catalyst exhibits a high C1 Faradaic efficiency stable electrolysis for 2 h in a KHCO3 electrolyte. This study facilitates the potential for the EC reduction of CO2 to chemical fuels.

Econometric Estimation of the Climate Change Policy Effect in the U.S. Transportation Sector

  • Choi, Jaesung
    • Journal of Climate Change Research
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    • v.8 no.1
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    • pp.1-10
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    • 2017
  • Over the past centuries, industrialization in developed and developing countries has had a negative impact on global warming, releasing $CO_2$ emissions into the Earth's atmosphere. In recent years, the transportation sector, which emits one-third of total $CO_2$ emissions in the United States, has adapted by implementing a climate change action plan to reduce $CO_2$ emissions. Having an environmental policy might be an essential factor in mitigating the man-made global warming threats to protect public health and the coexistent needs of current and future generations; however, to my best knowledge, no research has been conducted in such a context with appropriate statistical validation process to evaluate the effects of climate change policy on $CO_2$ emission reduction in recent years in the U.S. transportation. The empirical findings using an entity fixed-effects model with valid statistical tests show the positive effects of climate change policy on $CO_2$ emission reduction in a state. With all the 49 states joining the climate change action plans, the U.S. transportation sector is expected to reduce its $CO_2$ emissions by 20.2 MMT per year, and for the next 10 years, the cumulated $CO_2$ emission reduction is projected to reach 202.3 MMT, which is almost equivalent to the $CO_2$ emissions from the transportation sector produced in 2012 by California, the largest $CO_2$ emission state in the nation.

Stoichiometry, Thermal Stability and Reducibility of Perovskite-Type Mixed Oxide LaBO$_3$ (B = Fe, Co, Ni)

  • Park, Il-Hyun;Lee, Hyung-Pyo
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.283-288
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    • 1988
  • The titled properties on reduction of the perovskite $LaBO_3$ (B = Fe, Co, Ni) have been investigated by means of temperature-programmed reduction, isothermal reduction and X-ray diffraction methods. Nominal composition of $LaFeO_{3.18},\;LaCoO_{3.00}\;and\;LaNiO_{2.92}$ are determined. Reduction reaction of these mixed oxides differed according to B-site transition metal and thermal stability on reduction decreased as following order: $LaFeO_{3.18}$ > $LaCoO_{3.00}$ > $LaNiO_{2.92}$. From the results of isothermal reaction, kinetics on reduction of the perovskite has been discussed in detail.

Synthesis and Magnetic Property of Nanocrystalline Fe-Ni-Co Alloys during Hydrogen Reduction of Ni0.5Co0.5Fe2O4 (Ni0.5Co0.5Fe2O4의 수소환원에 의한 나노구조 Fe-Ni-Co 합금의 제조 및 자성특성)

  • Paek, Min Kyu;Do, Kyung Hyo;Bahgat, Mohamed;Pak, Jong Jin
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.167-173
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    • 2011
  • Nickel cobalt ferrite($Ni_{0.5}Co_{0.5}Fe_2O_4$) powder was prepared through the ceramic route by the calcination of a stoichiometric mixture of NiO, CoO and $Fe_2O_3$ at $1100^{\circ}C$. The pressed pellets of $Ni_{0.5}Co_{0.5}Fe_2O_4$ were isothermally reduced in pure hydrogen at $800{\sim}1100^{\circ}C$. Based on the thermogravimetric analysis, the reduction behavior and the kinetic reaction mechanisms of the synthesized ferrite were studied. The initial ferrite powder and the various reduction products were characterized by X-ray diffraction, scanning electron microscopy, reflected light microscope and vibrating sample magnetometer to reveal the effect of hydrogen reduction on the composition, microstructure and magnetic properties of the produced Fe-Ni-Co alloy. The arrhenius equation with the approved mathematical formulations for the gas solid reaction was applied to calculate the activation energy($E_a$) and detect the controlling reaction mechanisms. In the initial stage of hydrogen reduction, the reduction rate was controlled by the gas diffusion and the interfacial chemical reaction. However, in later stages, the rate was controlled by the interfacial chemical reaction. The nature of the hydrogen reduction and the magnetic property changes for nickel cobalt ferrite were compared with the previous result for nickel ferrite. The microstructural development of the synthesized Fe-Ni-Co alloy with an increase in the reduction temperature improved its soft magnetic properties by increasing the saturation magnetization($M_s$) and by decreasing the coercivity($H_c$). The Fe-Ni-Co alloy showed higher saturation magnetization compared to Fe-Ni alloy.

The Analysis of Potential Reduction of CO2 Emission In Soil and Vegetation due to Land use Change (토지이용변화에 따른 식생 및 토양의 이산화탄소 저감잠재량 분석)

  • Lee, Dong-Kun;Park, Chan
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.2
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    • pp.95-105
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    • 2009
  • Land Use Changes (LUCs) have effects on greenhouse gas emissions and carbon stocks in soil and vegetation. Therefore, predictions for LUC are very important for achieving quantitative targets of $CO_2$ reduction rates. Some research exists on carbon fluxes and carbon cycles to estimate carbon stocks in terrestrial ecosystems in Korea. However, these researches have limitations in terms of helping us understand future potential reductions of $CO_2$ that reflect the influence of LUC. The aim of this study is to analyze the reduction levels of $CO_2$ emissions while considering LUC scenarios that effect carbon fluxes for LCS basic study in the year 2030. In this study, a common approach to model the effects of LUC on carbon stocks is the use of CA-Markov technical process with LUC patterns in the past. Potential reduction of $CO_2$ is calculated by change of land use that contains different soil organic carbon, each land use type, and biomass in vegetation. An IPCC analytical method of natural carbon sink and coefficient results from previous study in Korea is used as a calculation method for potential reduction of $CO_2$. As a result, 12,419 KtC will be reduced annually, which is 8.3% percent of 2005 $CO_2$ emissions in Korea. This will result in 3,226 hundred million won of economic efficiency. In conclusion, conservation of natural carbon sinks is necessary even if the amount of potential reduction change is little.