• Title/Summary/Keyword: CO yield

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Synthesis of Trifoliate Orange Extract Having Anti inflammation Activities (항염증 활성을 갖는 탱자 추출물 합성)

  • Kim, Duck-Sool;Roh, Eon-Joo
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.196-202
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    • 2011
  • Coumarin derivatives were shown to possess valuable pharmacological properties such as anticancer/anti carcinogenic, anti-inflammatory, anti helicobacter, anti genotoxic, neuroprotective and dietary effect. In this study, novel coumarin derivatives structurally related to 7-geranyloxycoumarin were effectively synthesised in good yields by $Cs_2CO_3$/acetonitrile in mild condition. The synthesis of geranyloxycoumarin derivatives in weak base($Na_2CO_3$, $K_2CO_3$, $Cs_2CO_3$ etc)/$CH_3CN$ at room temperature obtained in good yield. On the other hand, the reaction of geranyloxycoumarin formation in strong base(NaOH, KOH, CsOH etc)/$CH_3CN$ at reflux condition obtained in low yield.

The characteristics of grown carbon nanotubes by controlled catalyst preparation at the catalytic chemical vapor deposition (촉매제어를 통한 촉매화학기상증착법으로 성장시킨 탄소나노튜브의 특성분석)

  • Kim, Jong-Sik;Kim, Gwan-Ha;Kim, Chang-Il
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1378-1379
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    • 2006
  • Carbon nanotubes (CNTs) with few defects and very small amount of amorphous carbon coating have been synthesized by catalytic decomposition of acetylene in $H_2$ over well-dispersed metal particles supported on MgO. The yield, quality and diameters of CNTs were obtained by control of catalyst metal compositions to be used. The optimization condition of carbon nanotubes with high yield is when Co and Mo are in a 1:1 ratio and Fe metal contents to Co is increased on magnesium oxide support. It is also found that the diameter of the as-prepared CNTs can be controlled mainly by adjusting the molar ratio of Fe-Mo, Co-Fe, and Co-Mo versus the MgO support. Our results indicated that desired diameter distribution of CNTs is obtained by choosing or combining the catalyst to be employed.

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Effect of Microstructure and Unit Cell's Geometry on the Compressive Mechanical Response of Additively Manufactured Co-Cr-Mo Sheet I-WP Lattice

  • So-Yeon Park;Kyu-Sik Kim;Bandar Almangour;Kee-Ahn Lee
    • Archives of Metallurgy and Materials
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    • v.67 no.4
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    • pp.1525-1529
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    • 2022
  • Co-Cr-Mo based sheet I-WP lattice was fabricated via laser powder bed fusion. The effect of microstructure and the I-WP shape on compressive mechanical response was investigated. Results of compression test showed that yield strength of the sheet I-WP was 176.3 MPa and that of bulk Co-Cr-Mo (reference material) was 810.4 MPa. By applying Gibson-Ashby analytical model, the yield strength of the lattice was reversely estimated from that of the bulk specimen. The calculated strength of the lattice obtained was 150.7 MPa. The shape of deformed lattice showed collective failure mode, and its microstructure showed that strain-induced martensitic transformation occurred in the overall lattice. The deformation behavior of additively manufactured sheet I-WP lattice was also discussed.

Model for Estimating CO2 Concentration in Package Headspace of Microbiologically Perishable Food

  • Lee, Dong-Sun;Kim, Hwan-Ki;An, Duck-Soon;Yam, Kit L.
    • Preventive Nutrition and Food Science
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    • v.16 no.4
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    • pp.364-369
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    • 2011
  • Levels of carbon dioxide gas, a metabolite of microbial growth, have been reported to parallel the onset of microbial spoilage and may be used as a convenient index for a packaged food's shelf life. This study aimed to establish a kinetic model of $CO_2$ production from perishable food for the potential use for shelf life control in the food supply chain. Aerobic bacterial count and package $CO_2$ concentration were measured during the storage of seasoned pork meat at four temperatures (0, 5, 10 and $15^{\circ}C$), and their interrelationship was investigated to establish a mathematical model. The microbial growth at constant temperature was described by using model of Baranyi and Roberts. $CO_2$ production from the stored food could be explained by taking care of its yield and maintenance factors linked to the microbial growth. By establishing the temperature dependence of the microbial growth and $CO_2$ yield factor, $CO_2$ partial pressure or concentration in package headspace could be estimated to a limited extent, which is helpful for controlling the shelf life under constant and dynamic temperature conditions. Application and efficacy of the model needs to be improved with further refinement in the model.

Photocatalytic conversion of CO2 into hydrocarbon fuels with standard titania (Degussa P25) using newly installed experimental setup

  • Kim, Hye Rim;Razzaq, Abdul;Heo, Hyo Jung;In, Su-Il
    • Rapid Communication in Photoscience
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    • v.2 no.2
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    • pp.64-66
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    • 2013
  • Photoreduction of $CO_2$ into hydrocarbon fuels on the surface of photocatalyst is one of the breakthroughs in the field of photocatalysis. At present various approaches have been investigated with the aim of increasing the $CO_2$ conversion efficiency. The reactor for photoconversion of $CO_2$ plays a vital role in experimental setup. In this work an attempt was made to testify a newly designed the photoreactor for conversion of $CO_2$ into useful products. The photoreactor was specifically designed for simple operation bearing features of temperature and pressure control. The reactor has been tested successively with the standard titania, Degussa P25 yielding methane with moderate production rate of 30.8 $ppm{\cdot}g^{-1}{\cdot}h^{-1}$ under UV lamp with 365 nm wavelength. The methane yield obtained is comparable to the values reported in literature. Thus we anticipate that this experimental setup equipped with newly designed photoreactor can yield competitive amounts of fuels from $CO_2$ photoredcution via 365 nm UV light illumination on various photocatalysts.

A Effect of Reaction Conditions on Syngas Yield for the Preparation of Syngas from Landfill Gas (매립지가스(LFG)로부터 합성가스 제조시 반응조건에 따른 수율에 미치는 연구)

  • CHO, WOOKSANG;CHOI, KEONGDON;BAEK, YOUNGSOON
    • Journal of Hydrogen and New Energy
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    • v.26 no.5
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    • pp.477-483
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    • 2015
  • LFG (Land-Fill Gas) includes components of $CH_4$, $CO_2$, $O_2$, $N_2$, and water. The preparation of synthesis gas from LFG as a DME (Dimethyl Ether) feedstock was studied by methane reforming of $CO_2$, $O_2$ and steam over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Our experiments were performed to investigate the effects of methane conversion and syngas yield on the amount of LFG components over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Results were obtained through the methan reforming experiments at the temperature of $900^{\circ}C$ and GHSV of 8,800. The results were as following; it has generally shown that syngas yield increase with the increase of oxygen and steam amounts and then decrease. Highly methane conversion of above 98% and syngas yield of approximately 60% were obtained in the feed of gas composition flow-rate of 243ml/min of $CH_4$, 241ml/min of $CO_2$, 195ml/min of $O_2$, 48ml/min of $N_2$, and 450ml/min of steam, respectively, under reactor pressure of 1 bar for 200 hrs of reaction time. Also, it was shown that catalyst deactivation by coke formation was reduced by excessively adding oxygen and steam as an oxidizer of the methane reforming.

Comparisons of Protein-bound Polysaccharide Contents Obtained from Mycelial Cultured Broth and Fruit body of Coriolus versieolor (구름버섯의 균사배양액 및 자실체로부터 얻어진 단백다당체의 수율비교)

  • Park, Young-Do;Hong, Yong-Ki;Whang, Wan-Kyun;Huh, Jae-Doo;Park, Shin
    • The Korean Journal of Mycology
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    • v.17 no.4
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    • pp.223-228
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    • 1989
  • This study was performed to obtain higher yield rate of protein-bound polysac-charide extracted from cultured broth and fruit body of Coriolus versieolor, basidiomycetes. 16002 strain produced 0.58%, the highest yield rate among four strains, and there was no significantly different yield in other three strains. The optimal liquid media were CVT-III to obtain higher yield of protein-bound polysaccharide comparing with the various culture media. Compared with several materials for substitution of medium source, the residue extract media of Coriolus versieolor fruit-body were yield rate similar to control, and addition of the extracts of ginseng residues increased 11.4-48%. And also compared with fruit bodies that were artificially cultured on the oak longs, 16002 strain produced the highest yield similar to the result of cultured broth. Fruit body of the prematures stage was more effective to obtain high yield rate.

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Effects of Brassiea campestris L. and Lactuca sativa L. Yield by Application of Organic Fertilizers and Microorganisms (유기질비료와 토양 미생물제제의 시용이 배추(Brassiea campestris L.)와 상추(Lactuca sativa L.)의 수량에 미치는 영향)

  • Jo, Sung-Hyun;Park, Tae-Hurn;Chang, Ki-Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.3
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    • pp.88-92
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    • 2001
  • This study was carried out to investigate about the effect of organic fertilizers(Pig manure fermentation compost; P, Organic fertilizer; B, F, Compost; D, and microorganism; M) on the growth and yield of the chinese cabbage and lactuca. At the standard applicated-amounts plot of organic fertilizer have appeared the best yield, but another the excess amount plot came into existence damage of fertilizer. However, according to the co-application of microorganism appeared certainly decreasing damage of fertilizers. Also at the same fertilizer and applicated-amounts plots were the higher than an-application of microorganism on the growth and yield. In conclusion, the excess application of organic fertilizer should be occurred fertilizer damages and increased on the growth and yield by use of microorganism.

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Hydrogen Supply to PEMFC for Unmanned Aero Vehicles Using Hydrolysis Reaction of NaBH4 (NaBH4 가수분해 반응에 의한 무인항공기용 PEMFC 수소공급)

  • Jung, Hyeon-Seong;Jo, Byung-Joo;Lee, Jung-Hoon;Lee, Han-Jong;Na, Il-Chai;Chu, Cheun-Ho;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.11-15
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    • 2016
  • Proton Exchange Membrane Fuel Cells (PEMFC) instead of batteries is appropriate for long time flight of unmanned aero vehicles (UAV). In this work, $NaBH_4$ hydrolysis system supplying hydrogen to PEMFC was studied. In order to decrease weight of $NaBH_4$ hydrolysis system, enhancement of hydrogen yield, recovery of condensing water and maintenance of stable hydrogen yield were studied. The hydrogen yield of 3.4% was increased by controlling of hydrogen pressure in hydrolysis reactor. Condensing water formed during air cooling of hydrogen was recovered into storage tank of $NaBH_4$ solution. In this process the condensing water dissolved $NaBH_4$ powder and then addition of $NaBH_4$ solution decreased system weight of 14%. $NaBH_4$ hydrolysis system was stably operated with hydrogen yield of 96% by 2.0g Co-P-B catalyst for 10 hours at 2.0L/min hydrogen evolution rate.

Effects of elevated CO2 concentration and increased temperature on the growth and crop yield of rice (Oryza sativa) cultivars in Korea -cv. Odaebyeo and cv. Saechucheongbyeo- (CO2농도와 온도 상승이 한국의 주요 재배 벼품종의 생육과 생산량에 미치는 영향 -오대벼와 새추청벼-)

  • Lee, Eung Pill;Jang, Rae Ha;Cho, Kyu Tae;You, Young Han
    • Journal of Wetlands Research
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    • v.16 no.4
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    • pp.363-370
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    • 2014
  • We grew seedlings of Saechucheongbyeo and Odaebyeo of rice cultivars that are cultivated dominantly in the northern and middle regions of Korea under control(ambient condition), ambient $CO_2$ concentration+elevated temperature, and elevated $CO_2$ concentration+elevated temperature in order to study how growth responses and crop yield of major rice of Korea change as the global warming proceeds and compared the results. Aboveground biomass, belowground biomass, total biomass, and panicles weight per individual and ripended grain rate of cv. Saechucheongbyeo were the highest under control, but those of cv. Odaebyeo were the highest under elevated $CO_2$ concentration+elevated temperature. There was no difference in the number of panicles per individual of cv. Saechucheongbyeo and cv. Odaebyeo in these experiments. There was no difference in the number of grains per panicle of cv. Saechucheongbyeo among three environmental gradients, but that of cv. Odaebyeo was the highest under elevated $CO_2$ concentration+elevated temperature. Weight of a grain of cv. Saechucheongbyeo was highest under elevated $CO_2$ concentration+elevated temperature, but that of cv. Odaebyeo was the higher under ambient $CO_2$ concentration+elevated temperature and elevated $CO_2$ concentration+elevated temperature. Thus, if global warming continues in Korea, selection of rice cultivation varieties must be chosen carefully for commendation.